When water is placed in a buret it forms a concave meniscus at the surface. In contrast, mercury (in a manometer for example) forms a convex meniscus (Figure 11.17). Explain why this phenomenon occurs, and why the two liquids give different results. Predict the meniscus shape if the buret is filled with ethylene glycol (HOCH2CH2OH).
Meniscus
Water in glass tubes (right) is attracted to the polar ‒OH groups on the surface of glass and so water forms a downward facing or concave meniscus. Mercury, however, is not attracted to the glass surface, and so forms a convex meniscus (left).
Trending nowThis is a popular solution!
Chapter 11 Solutions
Chemistry & Chemical Reactivity
Additional Science Textbook Solutions
Fundamentals of Heat and Mass Transfer
Organic Chemistry - Standalone book
Inorganic Chemistry
EBK INTRODUCTION TO CHEMISTRY
- 5-106 The normal boiling point of hexane, C6H14, is 69°C, and that of pentane, C5H12, is 36°C. Predict which of these compounds has a higher vapor pressure at 20°C.arrow_forwardWhat are intermolecular forces? How do they differ from intramolecular forces? What are dipole-dipole forces? How do typical dipole-dipole forces differ from hydrogen bonding interactions? In what ways are they similar? What are London dispersion forces? How do typical London dispersion forces differ from dipole-dipole forces? In what ways are they similar? Describe the relationship between molecular size and strength of London dispersion forces. Place the major types of intermolecular forces in order of increasing strength. Is there some overlap? That is, can the strongest London dispersion forces be greater than some dipole-dipole forces? Give an example of such an instance.arrow_forwardDefine the following and give an example of each: (a) dispersion force (b) dipole-dipole attraction (c) hydrogen bondarrow_forward
- In terms of the kinetic molecular theory, in what ways are liquids similar to solids? In what ways are liquids different from solids?arrow_forwardIn an experiment, 20.00 L of dry nitrogen gas, N2, at 20.0C and 750.0 mmHg is slowly bubbled into water in a flask to determine its vapor pressure (see the figure on next page). The liquid water is weighed before and after the experiment, from which the experimenter determines that it loses 353.6 mg in mass. Answer the following questions. a How many moles of nitrogen were bubbled into the water? b The liquid water diminished by how many moles? What happened to the liquid? c How many moles of gas exit the flask during the experiment? What is the partial pressure of nitrogen gas exiting? The total gas pressure is 750.0 mmHg. d From these data, calculate the vapor pressure of water at 20C. Does this agree with what you expect?arrow_forwardWhy do liquids have a vapor pressure? Do all liquids have vapor pressures? Explain. Do solids exhibit vapor pressure? Explain. How does vapor pressure change with changing temperature? Explain.arrow_forward
- Describe the behavior of a liquid and its vapor in a closed vessel as the temperature increases.arrow_forwardWhat are the strongest attractive forces that must be overcome to (a) boil silicon hydride, SiH4? (b) vaporize calcium chloride? (c) dissolve Cl2 in carbon tetrachloride, CCl4? (d) melt iodine?arrow_forwardook at Fig. 14.2. Why doesn't temperature increase continuously ever time? That is, why does the temperature stay constanl for periods of time?arrow_forward
- Diethyl ether (CH3CH2OCH2CH3) was one of the first chemicals used as an anesthetic. At 34.6C, diethyl ether has a vapor pressure of 760. torr, and at 17.9C, it has a vapor pressure of 400. torr. What is the H of vaporization for diethyl ether?arrow_forwardWhich would you expect to have the higher fusion enthalpy, N2 or I2? Explain your choice.arrow_forwardYou and a friend each synthesize a compound with the formula XeCI2F2. Your compound is a liquid and your friend's compound is a gas (at the same conditions of temperature and pressure). Explain how the two compounds with the same formulas can exist in different phases at the same conditions of pressure and temperature.arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning