Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 1.13, Problem 28P
(a)
Interpretation Introduction
Interpretation:
The longer bond should be determined for the given set of bonds.
Concept Introduction:
The hydrogen-halogen bond becomes longer and weaker as the size of the halogen increases.
Bond strength decreases with increase in bond length.
(b)
Interpretation Introduction
Interpretation:
The stronger bond should be determined for given set of bonds.
Concept Introduction:
The hydrogen-halogen bond becomes longer and weaker as the size of the halogen increases.
Bond strength decreases with increase in bond length.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
For each pair, circle the more polar bond
N—H or O—H
Br—F or Cl—F
Cl—H or B—H
H—F or H—C
S—Br or F—Br
Which molecule has the shortest bond? N2 N2+ N22- N23-
Which molecule has the highest bond enthalpy? N2 N2+ N22- N23-
Which molecule has the weakest bond? N2 N2+ N22- N23-
Which of the following molecules or ions are likely to be free radicals: N2O, OCl-, and ClO2?
a) N2O onlyb) OCl- onlyc) ClO2 only
d) N2O and ClO2
e) OCl- and ClO2
Chapter 1 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 1.1 - Oxygen has three isotopes, 16O, 17O, and 18O. The...Ch. 1.2 - Prob. 2PCh. 1.2 - How many valence electrons do chlorine, bromine,...Ch. 1.2 - Look at the relative positions of each pair of...Ch. 1.3 - a. Find potassium (K) in the periodic table and...Ch. 1.3 - Which bond is more polar?Ch. 1.3 - Which of the following has a. the most polar bond?...Ch. 1.3 - Use the symbols + and to show the direction of...Ch. 1.3 - After examining the potential maps for LiH, HF,...Ch. 1.4 - An atom with a formal charge does not necessarily...
Ch. 1.4 - Prob. 12PCh. 1.4 - a. Draw two Lewis structures for C2H6O. b. Draw...Ch. 1.4 - Draw the lone-pair electrons that are not shown in...Ch. 1.4 - Prob. 16PCh. 1.4 - Which of the atoms in the molecular models in...Ch. 1.4 - Prob. 18PCh. 1.7 - What orbitals are used to form the 10 sigma bonds...Ch. 1.9 - Put a number in each of the blanks: a. ___ s...Ch. 1.11 - Predict the approximate bond angles in a. the...Ch. 1.11 - According to the potential map for the ammonium...Ch. 1.12 - Prob. 25PCh. 1.13 - a. Predict the relative lengths and strengths of...Ch. 1.13 - Prob. 28PCh. 1.14 - Which of the bonds in a carbonoxygen double bond...Ch. 1.14 - Caffeine is a natural insecticide, found in the...Ch. 1.14 - a. What is the hybridization of each of the carbon...Ch. 1.14 - Prob. 33PCh. 1.14 - Describe the orbitals used in bonding and the bond...Ch. 1.15 - Account for the difference in the shape and color...Ch. 1.15 - Which of the following molecules would you expect...Ch. 1 - Draw a Lewis structure for each of the following...Ch. 1 - Prob. 38PCh. 1 - What is the hybridization of all the atoms (other...Ch. 1 - Prob. 40PCh. 1 - Draw the condensed structure of a compound that...Ch. 1 - Prob. 42PCh. 1 - Prob. 43PCh. 1 - Draw a Lewis structure for each of the following...Ch. 1 - Prob. 45PCh. 1 - List the bonds in order from most polar to least...Ch. 1 - What is the hybridization of the indicated atom in...Ch. 1 - Write the Kekul structure for each of the...Ch. 1 - Assign the missing formal charges.Ch. 1 - Predict the approximate bond angles for the...Ch. 1 - Prob. 51PCh. 1 - a. Which of the indicated bonds in each compound...Ch. 1 - In which orbitals are the lone pairs in nicotine?...Ch. 1 - Draw the missing lone-pair electrons and assign...Ch. 1 - Rank the following compounds from highest dipole...Ch. 1 - Prob. 56PCh. 1 - a. Which of the species have bond angles of 109.5?...Ch. 1 - Prob. 58PCh. 1 - Sodium methoxide (CH3ONa) has both ionic and...Ch. 1 - a. Why is a H 8 H bond (0.74 ) shorter than a C 8...Ch. 1 - Which compound has a larger dipole moment, CHCl3...Ch. 1 - Which compound has a longer C 8 Cl bond?Ch. 1 - Prob. 63PCh. 1 - The following compound has two isomers. One isomer...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 7.35 Which one of the following contains botb ionic and covalent bonds? (a) BaCO3 , (b) MgCl2 , (c) BaO , (d) H2S , (e) So42arrow_forwardWhich is the most polar bond? (a) CC (b) CH (c) NH (d) OH (e) Se-Harrow_forwardOn the left side of Figure 3.6, label the areas shown with a dotted line where... one bond can form. one bond can form.arrow_forward
- Consider the carbon-oxygen bond in formaldehyde (CH2O) and carbon monoxide (CO). In which molecule is the CO bond shorter? In which molecule is the CO bond stronger?arrow_forwardDraw all possible resonance structures for each of these compounds. Determine the formal charge on each atom in each of the resonance structures: (a) O3 (b) SO2 (c) NO2 , (d) NO3arrow_forwarda. Which bond would be longer? b. Which bond would be stronger? 1. C - Cl or C - I 2 C - C or C - Cl 3 H - Cl or H - Farrow_forward
- More energy is required to break a bond with an order of3/2than is required to break a bond of order 2 . True False. Please type answer no write by hend.arrow_forwardWhich of the bonds A, B or C in Figure 7 is the easiest to break? * 1- A 2- B 3- C 4- These bonds are equally strong.arrow_forward- What orbital(s) are the lone pairs of electrons on the O atom placed? - What orbital is the lone pair of electrons on the N atom placed? - What type of bond(s) are formed between Ca1 – C? - What type of bond(s) are formed between C = O? - What type of bond(s) are formed between C – N? - What type of bond(s) are formed between N – Ca2? - What type of bond(s) are formed between N – H? - What is the angle between Ca1 – C = O? - What is the angle between Ca1 – C – N? - What is the angle between O = C – N? - What is the angle between C – N – Ca2?arrow_forward
- Draw the Lewis structure for HCN.a.What is the electron domain geometry of C?b.What is the molecular geometry of C?c.What is the approximate bond angle of the H-C-N?d.Is this molecule polar?arrow_forwardMake a model of propane (C3H8), and draw this model using dashed lines and wedges to represent bonds going back and coming forwardarrow_forward25.) How many sigma and how many pi bonds are there in HCN? Write your answer as _____ sigma and _____ pi. For example, 6 sigma and 7 pi (no period at end).arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning