INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN
INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN
8th Edition
ISBN: 9780134580289
Author: CORWIN
Publisher: PEARSON
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Chapter 12, Problem 39E
Interpretation Introduction

(a)

Interpretation:

The electron dot formula and structural formula of IO is to be drawn.

Concept introduction:

An electron dot formula is a way of representing the molecular structure in which electrons are represented by a dot. Structural formula is a way in which atoms are linked together through a solid line. This solid line represents the covalent bond. An electron dot structure is known as Lewis structure. Electron dot structure indicates the valence electrons of an atom which are involved in bonding.

Expert Solution
Check Mark

Answer to Problem 39E

Electron dot structure of IO is shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  1

The structural formula of IO is shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  2

Explanation of Solution

In molecule IO iodine and oxygen are present as the bonding atoms. Iodine has 7 valence electrons and oxygen has 6 valence electrons. Negative charge is present on the molecule indicates that one electron is gained by the any atom of the molecule. Total number of electron pairs is calculated by adding the valence electrons and the negative charge present on the molecule. So, number of electrons is (6+7+1) which is 14. This shows that total electrons must be 14. Iodine is a halogen atom. Therefore, total electrons present in bond pair is 2. Rest of the electrons are present as the lone pairs on iodine and oxygen atom. An electron dot structure and structural formula of IO is shown below in Figure 1 and 2 respectively.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  3

Figure 1

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  4

Figure 2

Solid line, in Figure 2, between the iodine and oxygen atom is the covalent bond which is made up of two electrons. This bond is formed by sharing of electrons between the atoms present in that bond.

Conclusion

An electron dot structure and structural formula of IO is shown above in Figure 1 and Figure 2.

Interpretation Introduction

(b)

Interpretation:

The electron dot formula and structural formula of IO2 is to be drawn.

Concept introduction:

An electron dot formula is a way of representing the molecular structure in which electrons are represented by a dot. Structural formula is a way in which atoms are linked together through a solid line. This solid line represents the covalent bond. An electron dot structure is known as Lewis structure. Electron dot structure indicates the valence electrons of an atom which are involved in bonding.

Expert Solution
Check Mark

Answer to Problem 39E

Electron dot structure of IO2 is shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  5

The structural formula of IO2 is shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  6

Explanation of Solution

In molecule IO2, iodine is the central atom and and oxygen is present as the surrounding atoms. Iodine has 7 valence electrons and oxygen has 6 valence electrons. Negative charge is present on the molecule indicates that one electron is gained by the atom of the molecule. Total number of electron pairs is calculated by adding the valence electrons and the negative charge present on the molecule. So, number of electrons is (6+6+7+1) which is 20. This shows that total electrons must be 20 or 10 pair of electrons. Iodine is a halogen. Therefore, total electrons present in each bond pair is 2. Rest of the electrons are present as the lone pair on iodine and oxygen atoms. An electron dot structure and structural formula of IO2 is shown below in Figure 3 and 4 respectively.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  7

Figure 3

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  8

Figure 4

Each solid line, in Figure 4, between the iodine and oxygen atom is the covalent bond which is made up of two electrons. This bond is formed by sharing of electrons between the central atom iodine and the surrounding oxygen atom.

Conclusion

An electron dot structure and structural formula of IO2 is shown above in Figure 3 and Figure 4.

Interpretation Introduction

(c)

Interpretation:

The electron dot formula and structural formula of IO3 is to be drawn.

Concept introduction:

An electron dot formula is a way of representing the molecular structure in which electrons are represented by a dot. Structural formula is a way in which atoms are linked together through a solid line. This solid line represents the covalent bond. An electron dot structure is known as Lewis structure. Electron dot structure indicates the valence electrons of an atom which are involved in bonding.

Expert Solution
Check Mark

Answer to Problem 39E

Electron dot structure of IO3 is shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  9

The structural formula of IO3 is shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  10

Explanation of Solution

In molecule IO3, iodine is the central atom and and oxygen is present as the surrounding atoms. Iodine has 7 valence electrons and oxygen has 6 valence electrons. Negative charge is present on the molecule indicates that one electron is gained by the atom of the molecule. Total number of electron pairs is calculated by adding the valence electrons and the negative charge present on the molecule. So, number of electrons is (6+6+6+7+1) which is 26. This shows that total electrons must be 26 or 13 pair of electrons. Iodine is a halogen. Therefore, total electrons present in each bond pair is 2. Rest of the electrons are present as the lone pair on iodine and oxygen atoms. An electron dot structure and structural formula of IO3 is shown below in Figure 5 and 6 respectively.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  11

Figure 5

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  12

Figure 6

Each solid line, in Figure 6, between the iodine and oxygen atom is the covalent bond which is made up of two electrons. This bond is formed by sharing of electrons between the central atom iodine and the surrounding oxygen atom.

Conclusion

An electron dot structure and structural formula of IO3 is shown above in Figure 5 and Figure 6.

Interpretation Introduction

(d)

Interpretation:

The electron dot formula and structural formula of IO4 is to be drawn.

Concept introduction:

An electron dot formula is a way of representing the molecular structure in which electrons are represented by a dot. Structural formula is a way in which atoms are linked together through a solid line. This solid line represents the covalent bond. An electron dot structure is known as Lewis structure. Electron dot structure indicates the valence electrons of an atom which are involved in bonding.

Expert Solution
Check Mark

Answer to Problem 39E

Electron dot structure of IO4 is shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  13

The structural formula of IO4 is shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  14

Explanation of Solution

In molecule IO4, iodine is the central atom and and oxygen is present as the surrounding atoms. Iodine has 7 valence electrons and oxygen has 6 valence electrons. Negative charge is present on the molecule indicates that one electron is gained by the atom of the molecule. Total number of electron pairs is calculated by adding the valence electrons and the negative charge present on the molecule. So, number of electrons is (6+6+6+6+7+1) which is 32. This shows that total electrons must be 32 or 16 pair of electrons. Iodine is a halogen. Therefore, total electrons present in each bond pair is 2. Rest of the electrons are present as the lone pair on iodine and oxygen atoms. An electron dot structure and structural formula of IO4 is shown below in Figure 7 and 8 respectively.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  15

Figure 7

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 39E , additional homework tip  16

Figure 8

Each solid line, in Figure 8, between the iodine and oxygen atom is the covalent bond which is made up of two electrons. This bond is formed by sharing of electrons between the central atom iodine and the surrounding oxygen atoms.

Conclusion

An electron dot structure and structural formula of IO4 is shown above in Figure 7 and Figure 8.

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Chapter 12 Solutions

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN

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