INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN
INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN
8th Edition
ISBN: 9780134580289
Author: CORWIN
Publisher: PEARSON
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Chapter 12, Problem 41E
Interpretation Introduction

(a)

Interpretation:

The electron dot formula and structural formula of SO42 are to be drawn.

Concept introduction:

An electron dot formula is a way of representing the molecular structure in which electrons are represented by a dot. Structural formula is a way in which atoms are linked together through a solid line. This solid line represents the covalent bond. An electron dot structure is known as Lewis structure. Electron dot structure indicates the valence electrons of an atom which are involved in bonding.

Expert Solution
Check Mark

Answer to Problem 41E

Electron dot structure and structural formula of SO42 are shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  1

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  2

Explanation of Solution

In molecule, SO42, sulfur is present as the central atom and oxygen is present as the surrounding atom of sulfur. Sulfur has and oxygen, both have 6 valence electrons. Negative charge present on the molecule indicates that two electrons are gained by the atom of the molecule. Total number of electron pairs is calculated by adding the valence electrons and the negative charge present on the molecule. So, number of electrons is (6+6+6+6+6+2) which is 32. Total electrons present in each bond pair is 2. Rest of the electrons are present as the lone pairs on oxygen and sulfur atom. An electron dot structure and structural formula of SO42 is shown below in Figure 1 and 2 respectively.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  3

Figure 1

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  4

Figure 2

Solid line, in Figure 2, between the atoms is the covalent bond which is made up of two electrons. This bond is formed by sharing of electrons between the atoms present in that bond.

Conclusion

An electron dot structure and structural formula of SO42 are shown above in Figure 1 and Figure 2.

Interpretation Introduction

(b)

Interpretation:

The electron dot formula and structural formula of HSO4 are to be drawn.

Concept introduction:

An electron dot formula is a way of representing the molecular structure in which electrons are represented by a dot. Structural formula is a way in which atoms are linked together through a solid line. This solid line represents the covalent bond. An electron dot structure is known as Lewis structure. Electron dot structure indicates the valence electrons of an atom which are involved in bonding.

Expert Solution
Check Mark

Answer to Problem 41E

Electron dot structure and structural formula of HSO4 are shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  5

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  6

Explanation of Solution

In molecule HSO4, sulfur is the central atom and the surrounding atom of sulfur is oxygen. Sulfur and oxygen, both have 6 valence electrons. Negative charge present on the molecule indicates that one electron is gained by the molecule. Total number of electron pairs is calculated by adding the valence electrons and the negative charge present on the molecule. So, number of electrons is (6+6+6+6+6+1+1) which is 32. This shows that total electrons must be 32 or 16 pair of electrons. Total electrons present in each bond pair is 2. Rest of the electrons are present as the lone pair on sulfur and oxygen atoms. An electron dot structure and structural formula of HSO4 is shown below in Figure 3 and 4 respectively.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  7

Figure 3

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  8

Figure 4

Each solid line, in Figure 4, between the atoms is the covalent bond which is made up of two electrons. This bond is formed by sharing of electrons between the atoms present in that bond.

Conclusion

An electron dot structure and structural formula of HSO4 are shown above in Figure 3 and Figure 4.

Interpretation Introduction

(c)

Interpretation:

The electron dot formula and structural formula of SO32 are to be drawn.

Concept introduction:

An electron dot formula is a way of representing the molecular structure in which electrons are represented by a dot. Structural formula is a way in which atoms are linked together through a solid line. This solid line represents the covalent bond. An electron dot structure is known as Lewis structure. Electron dot structure indicates the valence electrons of an atom which are involved in bonding.

Expert Solution
Check Mark

Answer to Problem 41E

Electron dot structure and structural formula of SO32 are shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  9

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  10

Explanation of Solution

In molecule SO32, sulfur is the central atom and the surrounding atom of sulfur is oxygen. Sulfur and oxygen, both have 6 valence electrons. Negative charge present on the molecule indicates that two electrons are gained by the the molecule. Total number of electron pairs is calculated by adding the valence electrons and the negative charge present on the molecule. So, number of electrons is (6+6+6+6+2) which is 26. This shows that total electrons must be 26 or 13 pair of electrons. Total electrons present in each bond pair is 2. Rest of the electrons are present as the lone pair on sulfur and oxygen atoms. An electron dot structure and structural formula of SO32 is shown below in Figure 5 and 6 respectively.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  11

Figure 5

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  12

Figure 6

Each solid line, in Figure 6, between the atoms is the covalent bond which is made up of two electrons. This bond is formed by sharing of electrons between the atoms present in that bond.

Conclusion

An electron dot structure and structural formula of SO32 are shown above in Figure 5 and Figure 6.

Interpretation Introduction

(d)

Interpretation:

The electron dot formula and structural formula of HSO3 is to be drawn.

Concept introduction:

An electron dot formula is a way of representing the molecular structure in which electrons are represented by a dot. Structural formula is a way in which atoms are linked together through a solid line. This solid line represents the covalent bond. An electron dot structure is known as Lewis structure. Electron dot structure indicates the valence electrons of an atom which are involved in bonding.

Expert Solution
Check Mark

Answer to Problem 41E

Electron dot structure and structural formula of HSO3 are shown below.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  13

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  14

Explanation of Solution

In molecule HSO3, sulfur is the central atom and the surrounding atom of sulfur is oxygen. Sulfur and oxygen, both have 6 valence electrons. Negative charge present on the molecule indicates that one electron is gained by the molecule. Total number of electron pairs is calculated by adding the valence electrons and the negative charge present on the molecule. So, number of electrons is (6+6+6+6+1+1) which is 26. This shows that total electrons must be 26 or 13 pair of electrons. Total electrons present in each bond pair is 2. Rest of the electrons are present as the lone pair on sulfur and oxygen atoms. An electron dot structure and structural formula of HSO3 is shown below in Figure 7 and 8 respectively.

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  15

Figure 7

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN, Chapter 12, Problem 41E , additional homework tip  16

Figure 8

Each solid line, in Figure 8, between the atoms is the covalent bond which is made up of two electrons. This bond is formed by sharing of electrons between the atoms present in that bond.

Conclusion

An electron dot structure and structural formula of HSO3 are shown above in Figure 7 and Figure 8.

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Chapter 12 Solutions

INTRODUCTORY CHEMISTRY-STD.GDE.+SOL.MAN

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