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Concept explainers
a)
Interpretation:
The products of the reaction and its name to be predicted for the hydrogenation of given
Concept Introduction:
- Name the parent compound: Find the longest chain containing the double bond or triple bond and add the suffix ‘-ene’ or ‘-yne’ to the end of the main chain name.
- Number the carbon atoms in the main chain so that those with multiple bonds have the lowest index numbers possible:
- Write the full name: List the substituents in alphabetical order. Use commas to separate the numbers and the hyphen to separate number from words. Indicate the position of double or triple bond in chain by giving the number of the first multiple-bond carbon.
Addition reaction: A general reaction type in which a substance X-Y adds to the multiple bond of an unsaturated reactant to yield a saturated product that has only single bonds.
Hydrogenation (Addition of
b)
Interpretation:
The products of the reaction and its name to be predicted for the hydrogenation of given Alkyne
Concept Introduction:
Addition reaction: A general reaction type in which a substance X-Y adds to the multiple bond of an unsaturated reactant to yield a saturated product that has only single bonds.
Hydrogenation (Addition of
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Chapter 13 Solutions
EBK FUNDAMENTALS OF GENERAL, ORGANIC, A
- Following are Fischer projections for a group of five-carbon sugars, all of which are aldopentoses. Identify the pairs that are enantiomers and the pairs that are epimers. (The sugars shown here are not all of the possible five-carbon sugars.) 1 СНО 2 СНО СНО Н-С—ОН Н-С—ОН Н—С—ОН Н-С—ОН НО —С—Н Н-С—ОН Н- С—ОН НО—С— Н НО—С—Н CH̟OH CH̟OH ČH̟OH в iоchemistry |61 STATE ATION Republic of the Philippines Romblon State University Romblan, Philippines 4 СНО 5 СНО 6 СНО НО—С—Н Н-С—ОН НО -С—Н Н—С—ОН НО -С—Н НО -С—Н H-C–OH Н-С—ОН НО—С—Н CH,OH ČH,OH CH,OHarrow_forwardFollowing are Fischer projection for a group of five carbon sugars,all of which are aldopentoses. Identify the pairs that are enantiomers and the pairs that are epimers.(The sugar shown herebare not all of the possible five carbon sugars.)arrow_forwardThe explosive trinitrotoluene (TNT) is made by carrying out three successive nitration reactions on toluene. If these nitrations only occur in the ortho and para positions relative to the methyl group, what is the structure of TNT?arrow_forward
- draw a fischer projection formula for the enantiomer of each of the following monosaccharides.arrow_forwardIn the monosaccharide derivatives known as sugar alcohols, the carbonyl oxygen is reduced to a hydroxyl group. For example, D-glyceraldehyde can be reduced to glycerol. However, this sugar alcohol is no longer designated D or L. Why?arrow_forwardDraw the structures of the following compounds. (Includes both new and old names.) 3-cyclopentylhexan-3-olarrow_forward
- Drawn are four isomeric dimethylcyclopropanes. How are the compounds in each pair related (enantiomers, diastereomers, constitutional isomers): A and B; A and C; B and C; C and D?arrow_forwardIf Taxol (see Problem ) has a specific rotation of -49°, then what is the specific rotation of its enantiomer?arrow_forwardGive one specific sample structure (Fischer Projection or Haworth) of the following carbohydrate derivatives: - Alditols - Deoxy-sugararrow_forward
- (a) (S)-2-chlorobutane, draw a three-dimensional representation.arrow_forwardGlutathione is a commonly occurring tripeptide; it has considerable physiological importance because it is a scavenger for oxidizing agents. gamma-glutamyl-L-cysteinylglycine. Draw the structure of Glutathione and explain why the systematic name of Glutathione is such.arrow_forwardThe reaction of methoxy benzene with hydrogen iodide will yield a phenol and an alkyl halide. Which of following choices is the correct combination of the products?arrow_forward
- BiochemistryBiochemistryISBN:9781319114671Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.Publisher:W. H. FreemanLehninger Principles of BiochemistryBiochemistryISBN:9781464126116Author:David L. Nelson, Michael M. CoxPublisher:W. H. FreemanFundamentals of Biochemistry: Life at the Molecul...BiochemistryISBN:9781118918401Author:Donald Voet, Judith G. Voet, Charlotte W. PrattPublisher:WILEY
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