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(a)
Interpretation:
The reaction equation for the reaction of p-dichlorobenzene with
Concept Introduction:
Reaction of
Halogenation: The substitution of a halogen group for hydrogen on an aromatic ring.
(b)
Interpretation:
The reaction equation for the reaction of p-dichlorobenzene with
Concept Introduction:
Reaction of aromatic compounds: Unlike alkene, aromatic compound undergoes a electrophilic aromatic substitution reaction where a H atom get replaced by group of atoms.
Nitration: The substitution of a nitro group for hydrogen on an aromatic ring.
(c)
Interpretation:
The reaction equation for the reaction of p-dichlorobenzene with
Concept Introduction:
Reaction of aromatic compounds: Unlike alkene, aromatic compound undergoes a electrophilic aromatic substitution reaction where a H atom get replaced by group of atoms.
Sulfonation: The substitution of a sulfonic acid group for a hydrogen atom on an aromatic ring.
(d)
Interpretation:
The reaction equation for the reaction of p-dichlorobenzene with
Concept Introduction:
Reaction of aromatic compounds: Unlike alkene, aromatic compound undergoes a electrophilic aromatic substitution reaction where a H atom get replaced by group of atoms.
Halogenation: The substitution of a halogen group for hydrogen on an aromatic ring.
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Chapter 13 Solutions
EBK FUNDAMENTALS OF GENERAL, ORGANIC, A
- In the electrolysis of aqueous sodium bromide, there are two possible anodic reactions: *2H2O(l) ——-> 02(g) + 4H+(aq) + 4e–, E° = 1.23V2Br–(aq) ——–> Br2(g) + 2e-2, E° = 1.08 VWhich reaction occurs at anode and why?arrow_forwardConsider the reaction A + 2B ----> C. If the molar mass of C is twice the molar mass of A, what mass of C is produced by the complete reaction of 10.0 g A?(a) 10.0 g(b) 30.0 g(c) 60.0 garrow_forwarddraw the alkane strucutre based off the IR spectrum, 1H NMR spectrum, and 13C NMR spectrum for this compound.arrow_forward
- Draw a structure for the compound, C3H5Br, that fits the following 1H NMR data: δ 2.32 (3H, singlet) δ 5.35 (1H, broad singlet) δ 5.54 (1H, broad singlet)arrow_forwardPropose a reasonable mechanism, using curved arrow notation, for the reaction performed in this experiment. Your answer should include the following:(1) Decomposition of the 3-sulfolene(2) cycloaddition of 1,3-butadiene with maleic anhydride including the HOMO-LUMO interactions(3) hydrolysis of the anhydride under BASE hydrolysis with NaOH in H2O (consider how this differs from what was done in the experiment)Check attached image.arrow_forwardBalance the chemical equation for the oxidation of α-linolenic acid to ATP, CO2, and water. (Use the lowest possible ratio of reactants and products.) +arrow_forward
- I Write a balanced equation for each of the following two reactions that you will use in this activity. In the boxes provided, draw a diagram showing this reaction at the molecular level. Be sure that the drawing shows conservation of mass (see Figure 1.7A and B). a Calcium chloride reacting with sodium phosphate (double replacement) CaCl2 (aq) + NazPO4 (aq) → (_) + Reactants Products b Zinc reacting with hydrochloric acid (single replacement) Zn (s) + HCI (aq) → (_) + Reactants Productsarrow_forwardFor the following reaction: HNO3 H2SO4 NO2 NO2 NO2 10% 8% 82% 1. Write a reasonable mechanism, using curved arrow notation to show the flow of electrons, for the formation of all three products. Your answer should include all important resonance structures. 2. Using the mechanism and resonance structures, provide an explanation for the product ratios shown.arrow_forwardin which of the following alternatives is the greatest amount of energy released from the hydrogenation of:a) 1 mole propeneb) 1 mole of butadiene 1.3c) 1 mole pentyn-2d) 3 moles of ethenearrow_forward
- Write the formulas of the four singly chlorinated isomers formed when 2-methylbutane reacts with Cl2 in the presence of light.arrow_forwardThe reaction quotient is Q=1.6×10-26 Part B What pH is needed to produce this value of Q if the concentration and pressure values are [Br2]=2.50×10−4M , [Br−]=11.65M, [SO42−]=9.50M, and PSO2=3.50×10−5atm ? Express your answer numerically to two decimal places.arrow_forwardThe main constituents in vinegar are water and ethanoic acid (CH3COOH). In order to determine the concentration of acid in homemade vinegar, a student titrated 25 cm3 of 001 M NaOH against the vinegar. The equation for the reaction is: CH3COOH(aq) + NaOH(aq) ® CH3COONa(aq) + H2O(l) The following titration results were obtained: Burette readings (cm3) Rough 1 2 Final burette reading 20.10 38.90 31.40 Initial burette reading 0.10 20.00 12.50 Volume of vinegar used 20.00 18.90 18.90 (a) What volume of vinegar should be used in the calculation? (b) What is the mole ratio of NaOH:CH3COOH? (c) Calculate the number of moles of alkali in 25 cm3 of NaOH solution used. (d) How many moles of acid were used in the titration? (e) Calculate the…arrow_forward
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