What products would result from the following processes?
Write an equation for each reaction.
a.
b.
c.
d.
e.
(a)
Interpretation:
The product formed when
Concept introduction:
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
Answer to Problem 13.29E
The product formed when
Explanation of Solution
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
Alcohols on heating at
Figure 1
The product formed when
(b)
Interpretation:
The product formed by the excess oxidation of
Concept introduction:
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
Answer to Problem 13.29E
The product formed by the excess oxidation of
Explanation of Solution
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
The primary alcohol,
Figure 2
The product formed by the excess oxidation of
(c)
Interpretation:
The product formed by the controlled oxidation of
Concept introduction:
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
Answer to Problem 13.29E
The product formed when
Explanation of Solution
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
The compound
Figure 3
The product formed when
(d)
Interpretation:
The product formed when
Concept introduction:
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
Answer to Problem 13.29E
The product formed when
Explanation of Solution
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
Alcohols on heating at temperature
Figure 4
Interpretation:
The product formed when
(e)
Interpretation:
The product formed by the controlled oxidation of
Concept introduction:
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
Answer to Problem 13.29E
No product is formed by the controlled oxidation of
Explanation of Solution
Ketones can be prepared by the oxidation reaction of secondary alcohol. On the other hand, primary alcohols on oxidation with weak oxidant give aldehyde and with strong oxidant give carboxylic acid. No product is obtained by the oxidation of tertiary alcohol.
The controlled oxidation of
No product is formed by the controlled oxidation of
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Chapter 13 Solutions
Chemistry for Today: General, Organic, and Biochemistry
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