Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 13, Problem 13.8QAP

At 580 nm, which is the wavelength of its maximum absorption, the complex Fe(SCN)2+ has a molar absorptivity of 7.00 × I03L cm-1 mol-1.Calculate
(a) the absorbance of a 4.47 × 10-5 M solution of the complex at 580 nm in a 1.00-cm cell.
(b) the absorbance of a solution in a 2.50-cm cell in which the concentration of the complex is one half that in(a).
(c) the percent transmittance of the solutions described in (a) and (b).
(d) the absorbance of a solution that has half the transmittance of that described in (a).

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