Concept explainers
(a)
Interpretation: To justify if the given statements are true or false.
Concept introduction: The buffer solution is a solution contains weak acid and conjugate base or weak base and conjugated acid. It resists the change in
To determine: The authenticity of the given statement, “A solution consisting of
(b)
Interpretation: To justify if the given statements are true or false.
Concept introduction: The buffer solution is a solution contains weak acid and conjugate base or weak base and conjugated acid. It resists the change in
To determine: The authenticity of the given statement, “If
(c)
Interpretation: To justify if the given statements are true or false.
Concept introduction: The buffer solution is a solution contains weak acid and conjugate base or weak base and conjugated acid. It resists the change in pH.
To determine: The authenticity of the given statement, “Adding more
(d)
Interpretation: To justify if the given statements are true or false.
Concept introduction: The buffer solution is a solution contains weak acid and conjugate base or weak base and conjugated acid. It resists the change in pH.
To determine: The authenticity of the given statement, “If
(e)
Interpretation: To justify if the given statements are true or false.
Concept introduction: The buffer solution is a solution contains weak acid and conjugate base or weak base and conjugated acid. It resists the change in pH.
To determine: The authenticity of the given statement, “If
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Chapter 14 Solutions
Chemistry: An Atoms First Approach
- Calculate the pH after 0.010 mole of gaseous HCl is added to 250.0 mL of each of the following buffered solutions. a. 0.050 M NH3/0.15 M NH4Cl b. 0.50 M NH3/1.50 M NH4Cl Do the two original buffered solutions differ in their pH or their capacity? What advantage is there in having a buffer with a greater capacity?arrow_forwardConsider 1000. mL of a 1.00 104-M solution of a certain acid HA that has a Ka value equal to 1.00 104. How much water was added or removed (by evaporation) so that a solution remains in which 25.0% of HA is dissociated at equilibrium? Assume that HA is nonvolatile.arrow_forwardA sodium hydrogen carbonate-sodium carbonate buffer is to be prepared with a pH of 9.40. (a) What must the [ HCO3 ]/[ CO32 ]ratio be? (b) How many moles of sodium hydrogen carbonate must be added to a liter of 0.225 M Na2CO3 to give this pH? (c) How many grams of sodium carbonate must be added to 475 mL of 0.336 M NaHCO3 to give this pH? (Assume no volume change.) (d) What volume of 0.200 M NaHCO3 must be added to 735 mL of a 0.139 M solution of Na2CO3 to give this pH? (Assume that volumes are additive.)arrow_forward
- Select from Table 15.1 a conjugate acid-base pair that is suitable for preparing a buffer solution whose concentration of hydronium ions is (a) 4.5 103 M. (b) 5.2 108 M. (c) 8.3 106M. (d) 9.7 1011 M. Explain your choices.arrow_forwardKa for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.arrow_forward2. If an acetic acid/sodium acetate buffer solution is prepared from 100. mL of 0.10 M acetic acid what volume of 0.10 M sodium acetate must be added to have a pH of 4.00? 100. mL 50. mL 36 mL 18 mLarrow_forward
- Determine the dominant acid-base equilibrium that results when each of the following pairs of solutions is mixed. Indicate the equilibrium by writing 1 for a strong acid, 3 for a weak acid, 4 for an acidic buffer, 7 for a neutral solution, 10 for a basic buffer, 11 for a weak base, and 13 for a strong base. (a) 10.0 mL of 0.15 M NaOH + 15.0 mL of 0.10 M HNO3 (b) 25.0 mL of 0.10 M HCl + 10.0 mL of 0.25 M NH3 (c) 50.0 mL of 0.050 M NaOH + 50.0 mL of 0.10 M NH3 (d) 50.0 mL of 0.10 M NH3 + 50.0 mL of 0.05 M HClarrow_forwardWater is accidentally added to 350.00 mL of a stock solution of 6.00 M HCI. A 75.00-mL sample of the diluted solution is titrated to pH 7.00 with 78.8 mL of 4.85 M NaOH. How much water was accidentally added? (Assume that volumes are additive.)arrow_forward
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning