Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+)
8th Edition
ISBN: 9780135213759
Author: John McMurry, David Ballantine
Publisher: PEARSON+
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Textbook Question
Chapter 14, Problem 14.46AP
The following
(a)
(b)
(c) 2-Phenyl-2-hexene
(d)
(e) 1,4-Pentadiene
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2-butanol can be formed as the only product of the Markovnikov addition of H2O to two different alkenes. In contrast, 2-pentanol can be formed as the only
product of the Markovnikov addition of H2O to just one alkene. To examine the difference, draw the alkene starting materials of each alcohol.
:
Draw the bond-line (skeletal) structures of the two alkene starting materials that can be used to synthesize 2-butanol via Markovnikov hydration.
Part 1 of 2
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structure.
☑
2-butanol can be formed as the only product of the Markovnikov addition of H2O to two different alkenes. In contrast, 2-nonanol can be formed as the only
product of the Markovnikov addition of H2O to just one alkene. To examine the difference, draw the alkene starting materials of each alcohol.
Part 1 of 2
Draw the bond-line (skeletal) structures of the two alkene starting materials that can be used to synthesize 2-butanol via Markovnikov hydration.
Click and drag to start drawing a
structure.
0*
Part 2 of 2
Draw the bond-line (skeletal) structure of the alkene starting material that can be used to synthesize 2-nonanol selectively via Markovnikov hydration.
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Draw the structures of the following acids:(a) 2-Ethyl-3-hydroxyhexanoic acid (b) m-Nitrobenzoic acid
Chapter 14 Solutions
Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+)
Ch. 14.1 - Identify each of the following compounds as an...Ch. 14.1 - Prob. 14.2PCh. 14.2 - Prob. 14.3PCh. 14.2 - Prob. 14.4PCh. 14.2 - Prob. 14.5PCh. 14.3 - Prob. 14.6PCh. 14.3 - For each of the following molecules, (i) redraw...Ch. 14.4 - Prob. 14.1MRPCh. 14.4 - Provide the mechanism for the dehydration of...Ch. 14.4 - Prob. 14.3MRP
Ch. 14.4 - Prob. 14.8PCh. 14.4 - What alcohols yield the following alkenes as the...Ch. 14.4 - Prob. 14.10KCPCh. 14.4 - What products would you expect from oxidation of...Ch. 14.4 - Prob. 14.12PCh. 14.4 - Prob. 14.13KCPCh. 14.5 - Prob. 14.14PCh. 14.5 - Prob. 14.15PCh. 14.7 - Prob. 14.1CIAPCh. 14.7 - Prob. 14.2CIAPCh. 14.7 - Prob. 14.3CIAPCh. 14.7 - Prob. 14.16PCh. 14.8 - What disulfides would you obtain from oxidation of...Ch. 14.9 - Prob. 14.18PCh. 14.10 - Prob. 14.19PCh. 14.10 - Prob. 14.20PCh. 14.10 - Prob. 14.4CIAPCh. 14.10 - Prob. 14.5CIAPCh. 14.10 - Prob. 14.6CIAPCh. 14.10 - Prob. 14.7CIAPCh. 14 - Prob. 14.21UKCCh. 14 - Prob. 14.22UKCCh. 14 - Prob. 14.23UKCCh. 14 - Prob. 14.24UKCCh. 14 - Prob. 14.25UKCCh. 14 - How do alcohols, ethers, and phenols differ...Ch. 14 - What is the structural difference between primary,...Ch. 14 - Prob. 14.28APCh. 14 - Prob. 14.29APCh. 14 - The Taxane nucleus is shown here; it is the basis...Ch. 14 - Vitamin E has the structure shown. Identify the...Ch. 14 - Give systematic names for the following alcohols:...Ch. 14 - Give systematic names for the following compound...Ch. 14 - Draw structures corresponding to the following...Ch. 14 - Draw structures corresponding to the following...Ch. 14 - Prob. 14.36APCh. 14 - Locate the alcohol functional groups in the taxane...Ch. 14 - Prob. 14.38APCh. 14 - Prob. 14.39APCh. 14 - Prob. 14.40APCh. 14 - Prob. 14.41APCh. 14 - Prob. 14.42APCh. 14 - Prob. 14.43APCh. 14 - Assume that you have samples of the following two...Ch. 14 - Which of the following alcohols can undergo...Ch. 14 - The following alkenes can be prepared by...Ch. 14 - Prob. 14.47APCh. 14 - Prob. 14.48APCh. 14 - What alcohols would you oxidize to obtain the...Ch. 14 - Prob. 14.50APCh. 14 - What is the structural relationship between a...Ch. 14 - Prob. 14.52APCh. 14 - Prob. 14.53APCh. 14 - Prob. 14.54APCh. 14 - Prob. 14.55APCh. 14 - Prob. 14.56APCh. 14 - Prob. 14.57APCh. 14 - Identify the chiral center(s) in each of the...Ch. 14 - Are the following molecules chiral or achiral? If...Ch. 14 - Prob. 14.60CPCh. 14 - Prob. 14.61CPCh. 14 - 1-Propanol is freely soluble in water, 1-butanol...Ch. 14 - Prob. 14.63CPCh. 14 - Prob. 14.64CPCh. 14 - Prob. 14.65CPCh. 14 - Prob. 14.66CPCh. 14 - Prob. 14.67CPCh. 14 - Prob. 14.68CPCh. 14 - Prob. 14.69CPCh. 14 - Prob. 14.70CPCh. 14 - Prob. 14.71CPCh. 14 - Prob. 14.72CPCh. 14 - (a)Draw all possible cyclic C7H14O alcohol isomers...Ch. 14 - Prob. 14.74GPCh. 14 - Prob. 14.75GP
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- The reaction of methoxy benzene with hydrogen iodide will yield a phenol and an alkyl halide. Which of following choices is the correct combination of the products?arrow_forwardDraw structural formulas for all of the following. Q.) Alcohols with the molecular formula C4H10Oarrow_forwardDrawn are four isomeric dimethylcyclopropanes. How are the compounds in each pair related (enantiomers, diastereomers, constitutional isomers): A and B; A and C; B and C; C and D?arrow_forward
- Consider the alkene 5,5-dimethyl-3-octene for the following problems. Part 1 of 2 Draw a skeletal structure for the cis isomer of 5,5-dimethyl-3-octene. Click and drag to start drawing a structure. ☑ :୮arrow_forwardProvide compounds that fit the following descriptions:(a) Two amines that are gases at room temperature(b) A heterocyclic amine(c) A compound with an amine group on an aromatic ringarrow_forwardWhen pentane is exposed to Br2 in the presence of light, a halogenation reaction occurs. Write the formulas of:(a) All possible products containing only one bromine(b) All possible products containing two bromines that are not on the same carbonarrow_forward
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