Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Chapter 14, Problem 14.94EP

(a)

Interpretation Introduction

Interpretation:

The following intermediate compound generated in the first or second cycle of the lipogenesis pathway is produced by (1) a dehydration reaction, (2) a hydrogenation reaction, or (3) a condensation reaction has to be identified.

Organic And Biological Chemistry, Chapter 14, Problem 14.94EP , additional homework tip  1

Concept introduction:

Lipogenesis is the process employed for the synthesis of fatty acid. The starting precursor for the synthesis is acetyl CoA. The enzyme employed for the process is fatty acid synthase. It is a multienzyme complex that ties the reaction responsible for the synthesis of fatty acid. The fatty acid is synthesized in two parts. In the first part, there is citrate-malate shuttle system and in the second part, there is a cyclic process to synthesize saturated fatty acid.

The different reactions that are involved in the cyclic process are:

Organic And Biological Chemistry, Chapter 14, Problem 14.94EP , additional homework tip  2

In hydrogenation reaction, a hydrogen molecule (H2) is added to an organic substance; in hydration reaction, a water molecule (H2O) is added to an unsaturated substrate; in the condensation reaction, two molecules combine to form a single product.

The first turn of the cyclic process produces four-carbon acyl group and the further turns add two carbon unit to the four-carbon acyl group. Therefore, the first turn has four carbon units and the second turn has six carbon unit in their intermediate compound.

(b)

Interpretation Introduction

Interpretation:

The following intermediate compound generated in the first or second cycle of the lipogenesis pathway is produced by (1) a dehydration reaction, (2) a hydrogenation reaction, or (3) a condensation reaction has to be identified.

Organic And Biological Chemistry, Chapter 14, Problem 14.94EP , additional homework tip  3

Concept introduction:

Lipogenesis is the process employed for the synthesis of fatty acid. The starting precursor for the synthesis is acetyl CoA. The enzyme employed for the process is fatty acid synthase. It is a multienzyme complex that ties the reaction responsible for the synthesis of fatty acid. The fatty acid is synthesized in two parts. In the first part, there is citrate-malate shuttle system and in the second part, there is a cyclic process to synthesize saturated fatty acid.

The different reactions that are involved in the cyclic process are:

Organic And Biological Chemistry, Chapter 14, Problem 14.94EP , additional homework tip  4

In hydrogenation reaction, a hydrogen molecule (H2) is added to an organic substance; in hydration reaction, a water molecule (H2O) is added to an unsaturated substrate; in the condensation reaction, two molecules combine to form a single product.

The first turn of the cyclic process produces four-carbon acyl group and the further turns add two carbon unit to the four-carbon acyl group. Therefore, the first turn has four carbon units and the second turn has six carbon unit in their intermediate compound.

(c)

Interpretation Introduction

Interpretation:

The following intermediate compound generated in the first or second cycle of the lipogenesis pathway is produced by (1) a dehydration reaction, (2) a hydrogenation reaction, or (3) a condensation reaction has to be identified.

Organic And Biological Chemistry, Chapter 14, Problem 14.94EP , additional homework tip  5

Concept introduction:

Lipogenesis is the process employed for the synthesis of fatty acid. The starting precursor for the synthesis is acetyl CoA. The enzyme employed for the process is fatty acid synthase. It is a multienzyme complex that ties the reaction responsible for the synthesis of fatty acid. The fatty acid is synthesized in two parts. In the first part, there is citrate-malate shuttle system and in the second part, there is a cyclic process to synthesize saturated fatty acid.

The different reactions that are involved in the cyclic process are:

Organic And Biological Chemistry, Chapter 14, Problem 14.94EP , additional homework tip  6

In hydrogenation reaction, a hydrogen molecule (H2) is added to an organic substance; in hydration reaction, a water molecule (H2O) is added to an unsaturated substrate; in the condensation reaction, two molecules combine to form a single product.

The first turn of the cyclic process produces four-carbon acyl group and the further turns add two carbon unit to the four-carbon acyl group. Therefore, the first turn has four carbon units and the second turn has six carbon unit in their intermediate compound.

(d)

Interpretation Introduction

Interpretation:

The following intermediate compound generated in the first or second cycle of the lipogenesis pathway is produced by (1) a dehydration reaction, (2) a hydrogenation reaction, or (3) a condensation reaction has to be identified.

Organic And Biological Chemistry, Chapter 14, Problem 14.94EP , additional homework tip  7

Concept introduction:

Lipogenesis is the process employed for the synthesis of fatty acid. The starting precursor for the synthesis is acetyl CoA. The enzyme employed for the process is fatty acid synthase. It is a multienzyme complex that ties the reaction responsible for the synthesis of fatty acid. The fatty acid is synthesized in two parts. In the first part, there is citrate-malate shuttle system and in the second part, there is a cyclic process to synthesize saturated fatty acid.

The different reactions that are involved in the cyclic process are:

Organic And Biological Chemistry, Chapter 14, Problem 14.94EP , additional homework tip  8

In hydrogenation reaction, a hydrogen molecule (H2) is added to an organic substance; in hydration reaction, a water molecule (H2O) is added to an unsaturated substrate; in the condensation reaction, two molecules combine to form a single product.

The first turn of the cyclic process produces four-carbon acyl group and the further turns add two carbon unit to the four-carbon acyl group. Therefore, the first turn has four carbon units and the second turn has six carbon unit in their intermediate compound.

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Chapter 14 Solutions

Organic And Biological Chemistry

Ch. 14.3 - Prob. 3QQCh. 14.4 - In the oxidation of fatty acids, what two...Ch. 14.4 - Prob. 2QQCh. 14.4 - Prob. 3QQCh. 14.4 - Prob. 4QQCh. 14.4 - Prob. 5QQCh. 14.4 - Prob. 6QQCh. 14.5 - Prob. 1QQCh. 14.5 - Prob. 2QQCh. 14.5 - Prob. 3QQCh. 14.6 - Prob. 1QQCh. 14.6 - Prob. 2QQCh. 14.6 - Prob. 3QQCh. 14.6 - Prob. 4QQCh. 14.6 - Prob. 5QQCh. 14.6 - Prob. 6QQCh. 14.7 - The process of lipogenesis occurs in the a....Ch. 14.7 - Prob. 2QQCh. 14.7 - Prob. 3QQCh. 14.7 - Prob. 4QQCh. 14.7 - The reducing agent needed in the process of...Ch. 14.7 - Prob. 6QQCh. 14.8 - Prob. 1QQCh. 14.8 - Prob. 2QQCh. 14.9 - Prob. 1QQCh. 14.9 - Prob. 2QQCh. 14.9 - Prob. 3QQCh. 14.9 - Prob. 4QQCh. 14.10 - Which of the following substances cannot be...Ch. 14.10 - Prob. 2QQCh. 14.10 - Prob. 3QQCh. 14.11 - Prob. 1QQCh. 14.11 - Which of the following B-vitamin-containing...Ch. 14.11 - Prob. 3QQCh. 14 - Indicate whether each of the following aspects of...Ch. 14 - Indicate whether each of the following aspects of...Ch. 14 - Prob. 14.3EPCh. 14 - Prob. 14.4EPCh. 14 - Indicate whether each of the following statements...Ch. 14 - Prob. 14.6EPCh. 14 - Prob. 14.7EPCh. 14 - Prob. 14.8EPCh. 14 - Prob. 14.9EPCh. 14 - Prob. 14.10EPCh. 14 - At what location are free fatty acids and...Ch. 14 - Prob. 14.12EPCh. 14 - Prob. 14.13EPCh. 14 - What is the major metabolic function of adipose...Ch. 14 - What is triacylglycerol mobilization?Ch. 14 - Prob. 14.16EPCh. 14 - Prob. 14.17EPCh. 14 - Triacylglycerols in adipose tissue do not enter...Ch. 14 - In which step of glycerol metabolism does each of...Ch. 14 - Prob. 14.20EPCh. 14 - Prob. 14.21EPCh. 14 - How does the structure of dihydroxyacetone...Ch. 14 - Prob. 14.23EPCh. 14 - Prob. 14.24EPCh. 14 - Prob. 14.25EPCh. 14 - Prob. 14.26EPCh. 14 - Prob. 14.27EPCh. 14 - Identify the oxidizing agent needed in Step 3 of a...Ch. 14 - Prob. 14.29EPCh. 14 - Prob. 14.30EPCh. 14 - Prob. 14.31EPCh. 14 - Prob. 14.32EPCh. 14 - Prob. 14.33EPCh. 14 - Prob. 14.34EPCh. 14 - Prob. 14.35EPCh. 14 - Prob. 14.36EPCh. 14 - Prob. 14.37EPCh. 14 - Prob. 14.38EPCh. 14 - Prob. 14.39EPCh. 14 - Prob. 14.40EPCh. 14 - Prob. 14.41EPCh. 14 - Prob. 14.42EPCh. 14 - How many turns of the -oxidation pathway would be...Ch. 14 - How many turns of the -oxidation pathway would be...Ch. 14 - Prob. 14.45EPCh. 14 - Prob. 14.46EPCh. 14 - Prob. 14.47EPCh. 14 - Prob. 14.48EPCh. 14 - Prob. 14.49EPCh. 14 - Prob. 14.50EPCh. 14 - Prob. 14.51EPCh. 14 - Prob. 14.52EPCh. 14 - Prob. 14.53EPCh. 14 - Prob. 14.54EPCh. 14 - Prob. 14.55EPCh. 14 - Prob. 14.56EPCh. 14 - Prob. 14.57EPCh. 14 - Which yield more NADH, saturated or unsaturated...Ch. 14 - Prob. 14.59EPCh. 14 - Prob. 14.60EPCh. 14 - Prob. 14.61EPCh. 14 - Why does a deficiency of carbohydrates in the diet...Ch. 14 - Prob. 14.63EPCh. 14 - Prob. 14.64EPCh. 14 - Prob. 14.65EPCh. 14 - Prob. 14.66EPCh. 14 - Prob. 14.67EPCh. 14 - Prob. 14.68EPCh. 14 - Prob. 14.69EPCh. 14 - Prob. 14.70EPCh. 14 - Prob. 14.71EPCh. 14 - Prob. 14.72EPCh. 14 - Prob. 14.73EPCh. 14 - Prob. 14.74EPCh. 14 - Prob. 14.75EPCh. 14 - Severe ketosis situations produce acidosis....Ch. 14 - Prob. 14.77EPCh. 14 - Prob. 14.78EPCh. 14 - Prob. 14.79EPCh. 14 - Prob. 14.80EPCh. 14 - Prob. 14.81EPCh. 14 - Prob. 14.82EPCh. 14 - Prob. 14.83EPCh. 14 - Prob. 14.84EPCh. 14 - Prob. 14.85EPCh. 14 - Prob. 14.86EPCh. 14 - Prob. 14.87EPCh. 14 - Prob. 14.88EPCh. 14 - Prob. 14.89EPCh. 14 - Prob. 14.90EPCh. 14 - Prob. 14.91EPCh. 14 - Prob. 14.92EPCh. 14 - Prob. 14.93EPCh. 14 - Prob. 14.94EPCh. 14 - What role does molecular oxygen, O2, play in fatty...Ch. 14 - Prob. 14.96EPCh. 14 - Prob. 14.97EPCh. 14 - Prob. 14.98EPCh. 14 - Prob. 14.99EPCh. 14 - Prob. 14.100EPCh. 14 - Prob. 14.101EPCh. 14 - Prob. 14.102EPCh. 14 - Prob. 14.103EPCh. 14 - Prob. 14.104EPCh. 14 - Prob. 14.105EPCh. 14 - Prob. 14.106EPCh. 14 - Prob. 14.107EPCh. 14 - Prob. 14.108EPCh. 14 - Prob. 14.109EPCh. 14 - Prob. 14.110EPCh. 14 - Prob. 14.111EPCh. 14 - Prob. 14.112EPCh. 14 - Prob. 14.113EPCh. 14 - Prob. 14.114EP
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