Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 14, Problem 14.9P
Interpretation Introduction

(a)

Interpretation:

The alkyne from which the pentan-2-one can be prepared by acid-catalyzed reaction is to be stated.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

Interpretation Introduction

(b)

Interpretation:

The alkyne from which the 3, 3-dimethylbutan-2-one can be prepared by acid-catalyzed reaction is to be stated.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

Interpretation Introduction

(c)

Interpretation:

The alkyne from which the decan-5-one can be prepared by acid-catalyzed reaction is to be stated.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

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