Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 14, Problem 14.11P
Interpretation Introduction

Interpretation:

The enols among the compounds (A) to (D) are to be identified. Also, the enols are to be converted into ketones.

Concept introduction:

An alkyne can be converted into aldehyde and ketone by hydration reaction. In hydration reaction, mercuric ion with a dilute acid is used to carry out the reaction. Mercuric ion is used as a catalyst. After the protonation of the alkynyl carbon, the water attacks as the nucleophile and an enol is formed. Enol is unstable and converts into a stable aldehyde or ketone.

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