Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 14.2D, Problem 14.2P
Interpretation Introduction
Interpretation:
The structure of the resulting aluminum chloride etherate complex is to be shown when aluminum trichloride reacts with ether.
Concept introduction:
Lewis bases are defined as those species which can donate its lone pair of electron to other species to form a new bond. Examples: ether and
Lewis acids are defined as those species which can accept the lone pair of electron from other species to form a new bond. Examples:
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Consider the following reaction:Al + 3KOH + 3H2C2O4 ∙ 2H2O → K3Al(C2O4)3 ∙ 3H2O + 6HO + (3/2)H21.00 g 20.0 mL 14.0 g6.00 M
What is the theoretical yield of the complex formed in the reaction?
Which of the following statements about 10Dq is false?
A. [VCl6]2- has a greater 10Dq than [VCl4] complex.B.[MnF6]2- has a higher 10Dq value than [TcF6]2-.A. [V(H2O)6]3+ has a higher 10Dq value than [V(H2O)6]2+.D. In the [CoX(NH3)5]n+ complex, the color changes from dark violet to yellow when X is replaced by I-, Br-, Cl-, H2O, and NH3, respectively.
1. Write the oxidation and reduction half equations of this reaction.
Co(NO3)2.6H2O + 4NH3(aq) + (NH4)2CO3 + ½ H2O2 →
[Co(NH3)4CO3]NO3 + NH4NO3 + 6H2O + NH4OH
2. Ali synthesized an octahedral complex with the formula, [Co(NH3)4CO3]Cl.
- Draw the structure of this complex. Name it.
Chapter 14 Solutions
Organic Chemistry (9th Edition)
Ch. 14.2C - Rank the given solvents in decreasing order of...Ch. 14.2D - Prob. 14.2PCh. 14.2D - In the presence of 18-crown-6, potassium...Ch. 14.3B - Give a common name (when possible) and a...Ch. 14.3C - Prob. 14.5PCh. 14.3C - Name the following heterocyclic ethers.Ch. 14.4 - Propose a fragmentation to account for each...Ch. 14.5 - Prob. 14.8PCh. 14.5 - Prob. 14.9PCh. 14.6 - Prob. 14.10P
Ch. 14.7 - Explain why bimolecular condensation is a poor...Ch. 14.7 - Prob. 14.12PCh. 14.7 - Prob. 14.13PCh. 14.8 - Prob. 14.14PCh. 14.8 - Prob. 14.15PCh. 14.8 - Prob. 14.16PCh. 14.10A - Prob. 14.17PCh. 14.10A - Prob. 14.18PCh. 14.10B - Prob. 14.19PCh. 14.11B - Show how you would accomplish the following...Ch. 14.11B - Prob. 14.21PCh. 14.12 - Prob. 14.22PCh. 14.12 - Prob. 14.23PCh. 14.12 - Prob. 14.24PCh. 14.13 - Prob. 14.25PCh. 14.13 - Prob. 14.26PCh. 14.14 - Prob. 14.27PCh. 14.15 - Give the expected products of the following...Ch. 14 - Write structural formulas for the following...Ch. 14 - Give common names for the following compounds. a....Ch. 14 - Give IUPAC names for the following compounds. a....Ch. 14 - Glycerol (propane-1,2,3-triol) is a viscous syrup...Ch. 14 - Prob. 14.33SPCh. 14 - Show how you would make the following ethers,...Ch. 14 - (A true story.) An inexperienced graduate student...Ch. 14 - Prob. 14.36SPCh. 14 - a. Show how you would synthesize the pure (R)...Ch. 14 - a. Predict the values of m/z and the structures of...Ch. 14 - The following reaction resembles the...Ch. 14 - Prob. 14.40SPCh. 14 - Prob. 14.41SPCh. 14 - Prob. 14.42SPCh. 14 - Give the structures of the intermediates...Ch. 14 - Prob. 14.44SPCh. 14 - Show how you would synthesize the following ethers...Ch. 14 - Prob. 14.46SPCh. 14 - Prob. 14.47SPCh. 14 - Prob. 14.48SPCh. 14 - An acid-catalyzed reaction was carried out using...Ch. 14 - Propylene oxide is a chiral molecule. Hydrolysis...Ch. 14 - Prob. 14.51SPCh. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - In 2012, a group led by Professor Masayuki Satake...
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