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(a)
Interpretation:
The structural formula of 3-chloro-2-methylhexane should be determined.
Concept Introduction:
Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as
The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as
Rules of drawing structures of organic compounds are:
- First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
- After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).
(b)
Interpretation:
The structural formula of 4-ethyl-5-iodo-2,2-dimethyloctane should be determined.
Concept Introduction:
Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula
The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.
Rules of drawing structures of organic compounds are:
- First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
- After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).
(c)
Interpretation:
The structural formula of 1,1,3-tribromocyclohexane should be determined.
Concept Introduction:
Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula
The compounds in which hydrogen atoms of an alkane is replaced by halogen is known as alkyl halide.
The compounds in which series of atoms are connected to form a ring is known as cyclic compound whereas the compounds which are open chain compounds and their atoms doesn't form a ring is known as acyclic compounds. The general molecular formula of cyclic alkane is
Rules of drawing structures of organic compounds are:
- First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
- After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).
(d)
Interpretation:
The structural formula of propyl chloride should be determined.
Concept Introduction:
Compounds consist of carbon and hydrogen is known as hydrocarbons. Saturated hydrocarbon is known as alkane having general molecular formula
Rules of drawing structures of organic compounds are:
- First identify the base name, and then draw the straight chain of carbon atoms according to the base name.
- After that according to the given position of the substituents, locate them on carbon atoms (replacement of hydrogen atom occurs).
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Chapter 14 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
- A student was given the structural formulas of several compounds and was asked to give them systematic names. How many did the student name correctly? Correct those that are misnamed. a. 4-bromo-3-pentanol b. 2,2-dimethyl-4-ethylheptane c. 5-methylcyclohexanol d. 1,1-dimethyl-2-cyclohexanol e. 5-(2,2-dimethylethyl)nonane f. isopentylbromide g. 3,3-dichlorooctane h. 5-ethyl-2-methylhexane i. 1-bromo-4-pentanol j. 3-isopropyloctane k. 2-methyl-2-isopropylheptane l. 2-methyl-N,N-dimethyl-4-hexanaminearrow_forwardDraw skeletal structures for the following: a. 5-ethyl-2-methyloctane b. 1,3-dimethylcyclohexane c. 2,3,3,4-tetramethylheptane d. propylcyclopentane e. 2-methyl-4-(1-methylethyl)octane f. 2,6-dimethyl-4-(2-methylpropyl)decanearrow_forward2. Draw the following molecules 2-methyl-4-propyloctane a. b. 2-heptanone c. Methylbutyletherarrow_forward
- Draw the structure corresponding to each name: a. isobutylbenzene b. o-dichlorobenzene d. m-bromoaniline e. 4-chloro-1,2-diethylbenzene f. 3-tert-butyl-2-ethyltoluene c. cis-1,2-diphenylcyclohexanearrow_forward26. Which of the folow ing compounds contains 10 carbon atoms? c. 2-methyklecane d. 2,3-dimethylheptane a. 2,2,3-trimethy lheptane b. octane ha falluine eomnounds?arrow_forwardDraw the structure corresponding to each name: a.isobutylbenzene b.o-dichlorobenzene c.cis-1,2-diphenylcyclohexane d.m-bromoaniline e.4-chloro-1,2-diethylbenzene f.3-tert-butyl-2-ethyltoluenearrow_forward
- Show how to convert 1- Butene into these compounds. a. Butane b. 2- Butanol c. 2- Bromobutane d. 1,2- Dibromobutanearrow_forwardDraw a structure a. 3,4-dimethylpent-1-yneb.3-methyl-3-ethyl-1-butenec. 3,3-dimethyl-4-decened.1,1-dimethyl-4-ethyl-2,5-cyclohexadienee. 4-ethyl-2,3-dimethyl-2-heptenef. 1-chlorocyclopropeneg. 2,6-dimethyl-2,5-octadieneh. 1-cyclobutyl-3-methyl-1-butynei. 5-bromo-2-chlorotoluenearrow_forwardHow many different alkenes can be hydrogenated to form a. butane? b. 3-methylpentane? c. hexane?arrow_forward
- 2. Draw structures corresponding to the following IUPAC names. a. 2-Methyl-1,5-hexadiene b. 3-Ethyl-2,2-dimethyl-3-heptene c. 2,3,3-Trimethyl-1,4,6-octatriene d. 3,4-Diisopropyl-2,5-dimethyl-3-hexene e. 3-methyl-1-pentyne f. (Z)-3-methylhex-2-en-4-ynearrow_forwardWhich compound has the highest melting point? A. Decane B. 2,2,3,3-tetramethylbutane C. 2,3,3-trimethylpentane D. 4-methylnonanearrow_forwardConsider the structure of cyclohexyne, if it undergoes acetylide reaction with NaNH2 and 2 moles of CH3Br, which of the following final product is formed? a. 1,2-methylcyclohexyne HBr b. 1-methylcyclohexyne c. Cyclooctyne d. No reactionarrow_forward
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