EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
bartleby

Concept explainers

Question
Book Icon
Chapter 15, Problem 15.72P
Interpretation Introduction

(a)

Interpretation:

The chiral center of the clopidogrel needs to be labeled.

Concept introduction:

The molecules with a chiral center can form a superimposable mirror image and are known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(b)

Interpretation:

The enantiomers of clopidogrel needs to be drawn.

Concept introduction:

The chiral molecules which are mirror images of each other are known as enantiomers. They are non-superimposable mirror images, or they cannot be placed on top of each other.

Interpretation Introduction

(c)

Interpretation:

The Fischer projections forClopidogrel needs to be drawn.

Concept introduction:

For a molecule with a chiral center, the Fischer projection formula is written to describe the stereo arrangement of atoms in two dimensions. For large molecules with more than 1 stereocenters are also represent their stereochemistry using the Fischer Projection. The carbon chain of the molecule containing the chiral carbon center is represented as a vertical line with chiral carbon at the center. Two other groups are then horizontally arranged around the chiral carbon atom.

Blurred answer
Students have asked these similar questions
a) HO OH Molecule 5 is achiral has an enantiomer has at least one chiral diastereomer contains at least one R chiral center has a meso diastereomer b) Molecule 6 is achiral has an enantiomer has at least one chiral diastereomer contains at least one R chiral center has a meso diastereomer Ph Molecule 7 is achiral has an enantiomer has at least one chiral diastereomer contains at least one R chiral center has a meso diastereomer
6. Each of the following pairs of compounds contains one chirality center. Determine whether they are the same compound or enantiomers. If they are superimposable, they are the same. If they are nonsuperimposable, they are mirror images, they are enantiomers. Br C1 I_CC1 I— H Ме- Me-C Br Et H Br Cl H C-I Me-C Et Br H I-C Br Me BrC-I H H Et-C Br Me Me H H-C Br Me Et 1 2 Sk 954~ Rost 45 r Si
Translate the ball-and-stick model to a shorthand structure, and label the two chirality centers in vitamin K. Vitamin K is essential to blood clot formation. A defi ciency of this vitamin may lead to excessive and often fatal bleeding.

Chapter 15 Solutions

EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM

Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Organic Chemistry
Chemistry
ISBN:9781305080485
Author:John E. McMurry
Publisher:Cengage Learning
Text book image
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning