EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Chapter 15.3, Problem 15.5P
Interpretation Introduction

(a)

Interpretation:

The chiral center in the following compound should be located.

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 15.3, Problem 15.5P , additional homework tip  1

Concept Introduction:

Compounds in which an atom is attached to four different groups of atoms are known as chiral center and the compound is known as a chiral compound.

Interpretation Introduction

(b)

Interpretation:

The chiral center in the following compound should be located.

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 15.3, Problem 15.5P , additional homework tip  2

Concept Introduction:

Compounds in which an atom is attached to four different groups of atoms are known as chiral center and the compound is known as a chiral compound.

Interpretation Introduction

(c)

Interpretation:

The chiral center in the following compound should be located.

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 15.3, Problem 15.5P , additional homework tip  3

Concept Introduction:

Compounds in which an atom is attached to four different groups of atoms are known as chiral center and compound is known as a chiral compound.

Interpretation Introduction

(d)

Interpretation:

The chiral center in the following compound should be located.

  EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM, Chapter 15.3, Problem 15.5P , additional homework tip  4

Concept Introduction:

Compounds in which an atom is attached to four different groups of atoms are known as chiral center and compound is known as a chiral compound.

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1. Locate/Label the chirality center of the given molecules. a. OH H2N C H CH3 CH3 SH b. OH HO CH2NHC(CH3)3 HOCH2
8. Assign each chiral carbon as R or S in compound-A. Draw the mirror image of compound-A and assign configuration to each chiral carbon. (note that the dotted line represents the mirror). H₂N S OH Compound A CH3 CH3 mirror CH3 CH 3 Mmok NHZ
Ephedrine, a stimulant and illegal drug is an optically active compound with two chiral centers. OH NHCH3 CH3 Ephedrine a. In the structure of ephedrine on the answer sheet, mark each chiral center with an asterisk. b. How many stereoisomer/s does ephedrine have? Show necessary solutions on the answer sheet. c. Compound EPS is a stereoisomer of ephedrine. Determine the absolute configuration (R or S) at carbons A and B of compound EPS.

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