EBK NUMERICAL METHODS FOR ENGINEERS
EBK NUMERICAL METHODS FOR ENGINEERS
7th Edition
ISBN: 9780100254145
Author: Chapra
Publisher: YUZU
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Chapter 16, Problem 10P

For the reaction:

2 A + B C

equilibrium can be expressed as:

K = [ C ] [ A ] 2 [ B ] = [ C ] [ A 0 2 C ] 2 [ B 0 C ]

If   K = 2 M 1 , the initial concentration of A ( A 0 ) can be varied. The initial concentration of B is fixed by the process, B 0 = 100 . A costs $1/M and C sells for $10/M. What would be the optimum initial concentration of A to use such that the profits would be maximized?

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For the reaction H2(g) + Br2(g)  2HBr(g), Kc = 81.4 at 385ºC. If [H2] = [Br2] = [HBr] = 1.6 × 10–2 M at 385ºC, which one of the following is correct? Group of answer choices The reaction is at equilibrium already. The reaction will proceed in the forward direction because K > 1. The reaction will proceed in the reverse direction to reach equilibrium because Q < K. The reaction will proceed in the forward direction to reach equilibrium.
3) An ideal gas consisting of one mole of molecules of type A is in contact with the surroundings at T=300 K, and under a constant pressure of 1 atm. The gas undergoes a spontaneous isomeric chemical reaction, wherein some fraction x of molecules of type A change shape, become isomers of type B. This results in an equilibrium mixture of 1-x moles of A and x moles of B. The enthalpy of B is lower than the enthalpy of A by 3 kJ/mole, such that AH = -xɛ; & = 3kJ/mole . The change in entropy is given by AS ==R(xln x+ (1–x)ln(1– x)). Use the computer to graph the change in Gibbs free energy as a function of x. Determine, by inspection of your graph, or otherwise, the concentration of A and the concentration of B when equilibrium is obtained. What is the maximum work that could be extracted from this process (aside from PV work)? P= latm (consternt) T: 300k

Chapter 16 Solutions

EBK NUMERICAL METHODS FOR ENGINEERS

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