The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn. Concept introduction: The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as, The hydrolysis reaction of alkyl nitrile in presence of acid is written as, The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

Question

Write the structure of the Maleic Anhydride compound and label each non-equivalent carbon with a letter, A,B,C...

Answer 1

Question

Chapter 18, Problem 18.24P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(b)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(c)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Amide hydrolysis in aqueous base:

A carboxylate anion and ammonia or an amine will be the product of nitrile hydrolysis in aqueous base.

The formed carboxylate anion can be converted into carboxylic acid by the acidification of the reaction mixture.

(d)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

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Answer 2

Question

Chapter 18, Problem 18.24P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(b)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(c)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Amide hydrolysis in aqueous base:

A carboxylate anion and ammonia or an amine will be the product of nitrile hydrolysis in aqueous base.

The formed carboxylate anion can be converted into carboxylic acid by the acidification of the reaction mixture.

(d)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

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Answer 3

Question

Chapter 18, Problem 18.24P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(b)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(c)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Amide hydrolysis in aqueous base:

A carboxylate anion and ammonia or an amine will be the product of nitrile hydrolysis in aqueous base.

The formed carboxylate anion can be converted into carboxylic acid by the acidification of the reaction mixture.

(d)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

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Answer 4

Question

Chapter 18, Problem 18.24P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(b)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(c)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Amide hydrolysis in aqueous base:

A carboxylate anion and ammonia or an amine will be the product of nitrile hydrolysis in aqueous base.

The formed carboxylate anion can be converted into carboxylic acid by the acidification of the reaction mixture.

(d)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

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Answer 5

Chapter 18, Problem 18.24P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(b)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

(c)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Amide hydrolysis in aqueous base:

A carboxylate anion and ammonia or an amine will be the product of nitrile hydrolysis in aqueous base.

The formed carboxylate anion can be converted into carboxylic acid by the acidification of the reaction mixture.

(d)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

Answer 6

Chapter 18, Problem 18.24P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

Answer 7

Chapter 18, Problem 18.24P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

Answer 8

(b)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

Answer 9

(b)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

The reaction of alkyl halides with sodium cyanide gives alkyl cyanides or nitriles. After the reaction there is increase incarbon atoms of the alkyl chain of alkyl halide. The nitriles obtained undergo hydrolysis reaction in presence of acid gives carboxylic acid. The general reaction of alkyl halides and sodum cyanide is written as,

The hydrolysis reaction of alkyl nitrile in presence of acid is written as,

The amide is first formed when the cyano group is hydrolysed in excess of water and if there is only one mole of water per mole of nitrile, the reaction can be stopped by the formation of amide.

Answer 10

(c)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Amide hydrolysis in aqueous base:

A carboxylate anion and ammonia or an amine will be the product of nitrile hydrolysis in aqueous base.

The formed carboxylate anion can be converted into carboxylic acid by the acidification of the reaction mixture.

Answer 11

(c)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Amide hydrolysis in aqueous base:

A carboxylate anion and ammonia or an amine will be the product of nitrile hydrolysis in aqueous base.

The formed carboxylate anion can be converted into carboxylic acid by the acidification of the reaction mixture.

Answer 12

(d)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

Answer 13

(d)

Interpretation Introduction

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

Answer 14

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Answer 25

Ch. 18.1 - Prob. 18.1P Ch. 18.2 - Prob. 18.2P Ch. 18.4 - Prob. 18.3P Ch. 18.4 - Prob. 18.4P Ch. 18.4 - Synthesis of nitriles by nucleophilic displacement...Ch. 18.5 - Complete the following transesterification...Ch. 18.6 - Complete and balance equations for the following...Ch. 18.8 - Prob. AQ Ch. 18.8 - Several compounds have been found to inhibit...Ch. 18.8 - Prob. CQ

Concept explainers

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

Chapter 18 Solutions

Concept explainers

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn. Concept introduction: Concept introduction: LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.

Chapter 18 Solutions

The structural formula for the principal product formed when benzonitrile is treated with the given reagent has to be drawn.

Concept introduction:

Concept introduction:

LiAlH4 is a powerful reducing agent which reduces the cyano group of a nitrile to a primary amino group.