University Physics with Modern Physics (14th Edition)
14th Edition
ISBN: 9780321973610
Author: Hugh D. Young, Roger A. Freedman
Publisher: PEARSON
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Chapter 18, Problem 18.69P
(a)
To determine
Plot the graph of
(b)
To determine
Show the locations of points on graph of
(c)
To determine
The values of
(d)
To determine
The work that has to be done to pull the molecules at
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Let's consider the three atoms composing the molecule now have different masses and coordinate, while the axis of rotation is still z axis that is perpendicular to the xy plane. The first atom has a mass of 142.54 kg, with x coordinate at 3 m and y coordinate at 6 m. The second atom has a mass of 82.55 kg, with x coordinate at 1 m and y coordinate at 6 m. The third atom has a mass of 8 kg, with x coordinate at 5 m and y coordinate at 9 m. What is the moment of inertia in unit of kg m2 with respect to the x axis?
One description of the potential energy of a diatomic molecule is given by the Lennard–Jones potential, U = (A)/(r12) - (B)/(r6)where A and B are constants and r is the separation distance between the atoms. Find, in terms of A and B, (a) the value r0 at which the energy is a minimum and (b) the energy E required to break up a diatomic molecule.
A molecule has states with the following energies: 0, 1ε, 2ε, where ε = 1.0 x 10-20 J.
Calculate the average energy of this molecule in thermal equilibrium at T = 300 K.
Provide your answer in units of ε. In other words, your solution should have the form of
(number)ε, such as 2.137ε,
but the answer that you enter is just 2.137, a number in normal form with 3 decimal places (X.XXX).
It is a good idea to keep 4 decimal places during your calculation, then round to 3 decimal places for your submitted answer.
Chapter 18 Solutions
University Physics with Modern Physics (14th Edition)
Ch. 18.1 - Rank the following ideal gases in order from...Ch. 18.2 - Prob. 18.2TYUCh. 18.3 - Rank the following gases in order from (a) highest...Ch. 18.4 - A cylinder with a fixed volume contains hydrogen...Ch. 18.5 - A quantity of gas containing N molecules has a...Ch. 18.6 - The average atmospheric pressure on Mars is 6.0 ...Ch. 18 - Section 18.1 states that ordinarily, pressure,...Ch. 18 - In the ideal-gas equation, could an equivalent...Ch. 18 - When a car is driven some distance, the air...Ch. 18 - The coolant in an automobile radiator is kept at a...
Ch. 18 - Unwrapped food placed in a freezer experiences...Ch. 18 - A group of students drove from their university...Ch. 18 - The derivation of the ideal-gas equation included...Ch. 18 - A rigid, perfectly insulated container has a...Ch. 18 - (a) Which has more atoms: a kilogram of hydrogen...Ch. 18 - Use the concepts of the kinetic-molecular model to...Ch. 18 - The proportions of various gases in the earths...Ch. 18 - Comment on the following statement: When two gases...Ch. 18 - Prob. 18.13DQCh. 18 - The temperature of an ideal gas is directly...Ch. 18 - If the pressure of an ideal monatomic gas is...Ch. 18 - In deriving the ideal-gas equation from the...Ch. 18 - Imagine a special air filter placed in a window of...Ch. 18 - Prob. 18.18DQCh. 18 - Consider two specimens of ideal gas at the same...Ch. 18 - The temperature of an ideal monatomic gas is...Ch. 18 - Prob. 18.21DQCh. 18 - (a) If you apply the same amount of heat to 1.00...Ch. 18 - Prob. 18.23DQCh. 18 - In a gas that contains N molecules, is it accurate...Ch. 18 - The atmosphere of the planet Mars is 95.3% carbon...Ch. 18 - Prob. 18.26DQCh. 18 - Ice is slippery to walk on, and especially...Ch. 18 - Hydrothermal vents are openings in the ocean floor...Ch. 18 - The dark areas on the moons surface are called...Ch. 18 - In addition to the normal cooking directions...Ch. 18 - A 20.0-L tank contains 4.86 104 kg of helium at...Ch. 18 - Helium gas with a volume of 3.20 L, under a...Ch. 18 - A cylindrical tank has a tight-fitting piston that...Ch. 18 - A 3.00-L lank contains air at 3.00 atm and 20.0C....Ch. 18 - Planetary Atmospheres. (a) Calculate the density...Ch. 18 - You have several identical balloons. You...Ch. 18 - A Jaguar XK8 convertible has an eight-cylinder...Ch. 18 - A welder using a tank of volume 0.0750 m3 fills it...Ch. 18 - A large cylindrical tank contains 0.750 m3 of...Ch. 18 - An empty cylindrical canister 1.50 m long and 90.0...Ch. 18 - The gas inside a balloon will always have a...Ch. 18 - An ideal gas has a density of 1.33 106 g/cm3 at...Ch. 18 - If a certain amount of ideal gas occupies a volume...Ch. 18 - A diver observes a bubble of air rising from the...Ch. 18 - A metal tank with volume 3.10 L will burst if the...Ch. 18 - Three moles of an ideal gas are in a rigid cubical...Ch. 18 - With the assumptions of Example 18.4 (Section...Ch. 18 - With the assumption that the air temperature is a...Ch. 18 - (a) Calculate the mass of nitrogen present in a...Ch. 18 - At an altitude of 11,000 m (a typical cruising...Ch. 18 - Prob. 18.21ECh. 18 - Prob. 18.22ECh. 18 - Modern vacuum pumps make it easy to attain...Ch. 18 - The Lagoon Nebula (Fig. E18.24) is a cloud of...Ch. 18 - In a gas at standard conditions, what is the...Ch. 18 - How Close Together Are Gas Molecules? Consider an...Ch. 18 - (a) What is the total translational kinetic energy...Ch. 18 - A flask contains a mixture of neon (Ne), krypton...Ch. 18 - We have two equal-size boxes, A and B. Each box...Ch. 18 - A container with volume 1.64 L is initially...Ch. 18 - Prob. 18.31ECh. 18 - Martian Climate. The atmosphere of Mars is mostly...Ch. 18 - Prob. 18.33ECh. 18 - Calculate the mean free path of air molecules at...Ch. 18 - At what temperature is the root-mean-square speed...Ch. 18 - Prob. 18.36ECh. 18 - Prob. 18.37ECh. 18 - Perfectly rigid containers each hold n moles of...Ch. 18 - (a) Compute the specific heat at constant volume...Ch. 18 - Prob. 18.40ECh. 18 - Prob. 18.41ECh. 18 - For a gas of nitrogen molecules (N2), what must...Ch. 18 - Prob. 18.43ECh. 18 - Meteorology. The vapor pressure is the pressure of...Ch. 18 - Calculate the volume of 1.00 mol of liquid water...Ch. 18 - A physics lecture room at 1.00 atm and 27.0C has a...Ch. 18 - CP BIO The Effect of Altitude on the Lungs. (a)...Ch. 18 - CP BIO The Bends. If deep-sea divers rise to the...Ch. 18 - CP A hot-air balloon stays aloft because hot air...Ch. 18 - In an evacuated enclosure, a vertical cylindrical...Ch. 18 - A cylinder 1.00 m tall with inside diameter 0.120...Ch. 18 - CP During a test dive in 1939, prior to being...Ch. 18 - Atmosphere or Titan. Titan, the largest satellite...Ch. 18 - Pressure on Venus. At the surface of Venus the...Ch. 18 - An automobile tire has a volume of 0.0150 m3 on a...Ch. 18 - A flask with a volume of 1.50 L, provided with a...Ch. 18 - CP A balloon of volume 750 m3 is to be filled with...Ch. 18 - A vertical cylindrical tank contains 1.80 mol of...Ch. 18 - CP A large tank of water has a hose connected to...Ch. 18 - CP A light, plastic sphere with mass m = 9.00 g...Ch. 18 - Prob. 18.61PCh. 18 - BIO A person at rest inhales 0.50 L of air with...Ch. 18 - You have two identical containers, one containing...Ch. 18 - The size of an oxygen molecule is about 2.0 1010...Ch. 18 - A sealed box contains a monatomic ideal gas. The...Ch. 18 - Helium gas is in a cylinder that has rigid walls....Ch. 18 - You blow up a spherical balloon to a diameter of...Ch. 18 - CP (a) Compute the increase in gravitational...Ch. 18 - Prob. 18.69PCh. 18 - Prob. 18.70PCh. 18 - It is possible to make crystalline solids that are...Ch. 18 - Hydrogen on the Sun. The surface of the sun has a...Ch. 18 - Prob. 18.73PCh. 18 - Planetary Atmospheres. (a) The temperature near...Ch. 18 - Prob. 18.75PCh. 18 - Prob. 18.76PCh. 18 - CALC (a) Explain why in a gas of N molecules, the...Ch. 18 - Prob. 18.78PCh. 18 - CP Oscillations of a Piston. A vertical cylinder...Ch. 18 - Prob. 18.80PCh. 18 - DATA The Dew Point and Clouds. The vapor pressure...Ch. 18 - DATA The statistical quantities average value and...Ch. 18 - CP Dark Nebulae and the Interstellar Medium. The...Ch. 18 - CALC Earths Atmosphere. In t he troposphere, the...Ch. 18 - Prob. 18.85PPCh. 18 - Estimate the ratio of the thermal conductivity of...Ch. 18 - The rate of effusionthat is, leakage of a gas...
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- Estimate the mean free path of a nitrogen molecule in a cylinder nitrogen at 2 atm and a temperature of 17 oC. Take the radius to be roughly equal to 1 x10-10 m. Boltzmann constant 1.38 x10-23 J/K.arrow_forward2(6) Calculate the fundamental vibrational wavenumber (in cm-1) for HI molecule, if its angular vibrational frequency is 4.394×1014 s-1. Calculate the vibrational energy of the molecule in the ground state and the force constant. Assume the mass is the mass of a proton.arrow_forwardA gas phase H19F molecule has a bond length of 91.68 pm and a vibrational force constant,k = 966 N/m. For the v = 0, J = 10 and v = 1, J = 10 rovibrational levels, calculate the period of rotation andvibration. How many times does the molecule rotate during one vibrational period?arrow_forward
- Although an ordinary H2 molecule consists of two identical atoms, this is not the case for the molecule HD, with one atom of deuterium (Le., heavy hydrogen, 2H). Because of its small moment of inertia, the HD molecule has a relatively large value of E: 0.0057 eV. At approximately what temperature would you expect the rotational heat capacity of a gas of HD molecules to "freeze out," that is, to fall significantly below the constant value predicted by the equipartition theorem?arrow_forwardA molecule has states with the following energies: 0, 1ε, 2ε, 3ε, and 4ε, where ε = 1.0 x 10-20 J. Calculate the probability that a molecule is in the ground state (with zero energy) for a collection of molecules in thermal equilibrium at T = 300 K. Provide your answer as a number in normal form to 3 decimal places (in the form X.XXX). It is a good idea to keep 4 decimal places during your calculation, then round to 3 decimal places for your submitted answer. Hint: note that this molecule has a finite number of states so you must take a finite sum, do not use expressions for infinite sums. Also note that your calculations for this problem will be useful for the next two problems, so keep them.arrow_forwardThe v = 0 to v = 1 vibrational transition of the HI molecule occurs at a frequency of 6.69 × 1013 Hz. The same transition for the NO molecule occurs at a frequency of 5.63 × 1013 Hz. Calculate (a) the effective force constant and (b) the amplitude of vibration for each molecule. (c) Explain why the force constant of the NO molecule is so much larger than that of the HI molecule.arrow_forward
- (a) Repeat Exercise 31.2, and convert the energy to joules or calories. (b) If all of this energy is converted to thermal energy in the gas, what is its temperature increase, assuming 50.0 cm3 of ideal gas at 0.250atm pressure? (The small answer is consistent with the fact that the energy is large on a quantum mechanical scale but small on a macroscopic scale.)arrow_forwardThe characteristic energy for KCl is 1.4105eV . (a) Determine for the KC1 molecule, (b) Find the separation distance between the K arid Cl atoms.arrow_forwardTo obtain a more clearly defined picture of the FermiDirac distribution, consider a system of 20 FermiDirac particles sharing 94 units of energy. By drawing diagrams like Figure P10.11, show that there are nine different microstates. Using Equation 10.2, calculate and plot the average number of particles in each energy level from 0 to 14E. Locate the Fermi energy at 0 K on your plot from the fact that electrons at 0 K fill all the levels consecutively up to the Fermi energy. (At 0 K the system no longer has 94 units of energy, but has the minimum amount of 90E.) 1 Microstate8 others? One of the nine equally probable microstates for 20 FD particles with a total energy of 94E.arrow_forward
- As an alternative to Equation 42.1, another useful model for the potential energy of a diatomic molecule is the Morse potential U(r)=B[ea(rr0)1]2 where B, a, and r0 are parameters used to adjust the shape of the potential and its depth. (a) What is the equilibrium separation of the nuclei? (b) What is the depth of the potential well, defined as the difference in energy between the potentials minimum value and its asymptote as r approaches infinity? (c) If is the reduced mass of the system of two nuclei and assuming the potential is nearly parabolic about the well minimum, what is the vibrational frequency of the diatomic molecule in its ground state? (d) What amount of energy needs to be supplied to the ground-state molecule to separate the two nuclei to infinity?arrow_forward(a) In an HCl molecule, take the Cl atom to be the isotope 35Cl. The equilibrium separation of the H and Cl atoms is 0.127 46 nm. The atomic mass of the H atom is 1.007 825 u and that of the 35Cl atom is 34.968 853 u. Calculate the longest wavelength in the rotational spectrum of this molecule. (b) What If? Repeat the calculation in part (a), but take the Cl atom to be the isotope 37Cl, which has atomic mass 36.965 903 u. The equilibrium separation distance is the same as in part (a). (c) Naturally occurring chlorine contains approximately three parts of 35Cl to one part of 37Cl. Because of the two different Cl masses, each line in the microwave rotational spectrum of HCl is split into a doublet as shown in Figure P42.11. Calculate the separation in wavelength between the doublet lines for the longest wavelength.arrow_forwardA molecule has states with the following energies: 0, 1ε, 2ε, 3ε, and 4ε, where ε = 1.0 x 10-20 J. Calculate the average number of molecules in the first excited state (1ε) for a collection of 1000 molecules in thermal equilibrium at T = 300 K. Note that the average number of molecules in a state is just the probability that a molecule is in the state times the number of molecules. Provide your answer as a number in normal form.arrow_forward
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