Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 18, Problem 18.8E
Interpretation Introduction
Interpretation:
The minimum value of
Concept introduction:
Different linearly independent wavefunctions that have same energy are called degenerate. This is expressed in terms of degeneracy. If two functions are having same energy then they are called doubly degenerate and so on. The electronic partition function is represented as,
Where,
•
•
•
•
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
What is the value of the Born exponent for Fr+?
What are the Probability Densities?
Chapter 18 Solutions
Physical Chemistry
Ch. 18 - Prob. 18.1ECh. 18 - Prob. 18.2ECh. 18 - Prob. 18.3ECh. 18 - Prob. 18.4ECh. 18 - The following are the first four electronic energy...Ch. 18 - Prob. 18.6ECh. 18 - Prob. 18.7ECh. 18 - Prob. 18.8ECh. 18 - Prob. 18.9ECh. 18 - Prob. 18.10E
Ch. 18 - Prob. 18.11ECh. 18 - Prob. 18.12ECh. 18 - Prob. 18.13ECh. 18 - Prob. 18.14ECh. 18 - Prob. 18.15ECh. 18 - Prob. 18.16ECh. 18 - Prob. 18.17ECh. 18 - Prob. 18.18ECh. 18 - Prob. 18.19ECh. 18 - Prob. 18.20ECh. 18 - Prob. 18.21ECh. 18 - Prob. 18.22ECh. 18 - Prob. 18.23ECh. 18 - Prob. 18.24ECh. 18 - Prob. 18.25ECh. 18 - Prob. 18.26ECh. 18 - Prob. 18.27ECh. 18 - Prob. 18.28ECh. 18 - Prob. 18.29ECh. 18 - Prob. 18.30ECh. 18 - Prob. 18.31ECh. 18 - Prob. 18.32ECh. 18 - Prob. 18.33ECh. 18 - What are qnuc and qrot for N2(I=1)? See Table 18.3...Ch. 18 - The rovibrational spectrum of acetylene, HCCH,...Ch. 18 - Prob. 18.36ECh. 18 - Prob. 18.37ECh. 18 - Prob. 18.38ECh. 18 - Prob. 18.39ECh. 18 - Prob. 18.40ECh. 18 - Prob. 18.41ECh. 18 - Prob. 18.42ECh. 18 - Use equation 18.44 to show that pV=NkT.Ch. 18 - Prob. 18.44ECh. 18 - Determine E,H,G, and S for CH4 at standard...Ch. 18 - Prob. 18.48ECh. 18 - Prob. 18.49ECh. 18 - Calculate the heat capacity of NO2 at 298K and...Ch. 18 - Prob. 18.51ECh. 18 - In Chapters 17 and 18 we have derived expressions...Ch. 18 - Prob. 18.55ECh. 18 - Prob. 18.56ECh. 18 - Prob. 18.57ECh. 18 - Prob. 18.58ECh. 18 - Prob. 18.59ECh. 18 - Prob. 18.60E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What is the degeneracy of an h subshell? An n subshell?arrow_forwardState the Born-Oppenheimer approximation in words and mathematically, and indicate how the mathematical form is implied by the statement.arrow_forwardEvaluate Lz for 3px, Compare it to the answer in Example 11.25, and explain the difference in the answers.arrow_forward
- In a plot of ||2, the maximum maxima in the plot is/are called the most probable positions. What is/are the most probable positions for a particle-in-a-box when: a n=1 b n=2 c n=3 d Do you see a trend?arrow_forwardWhat is the difference between continuous and discrete spectra?arrow_forwardFor a particle in a state having the wavefunction =2asinxa in the range x=0toa, what is the probability that the particle exists in the following intervals? a x=0to0.02ab x=0.24ato0.26a c x=0.49ato0.51ad x=0.74ato0.76a e x=0.98ato1.00a Plot the probabilities versus x. What does your plot illustrate about the probability?arrow_forward
- The following are sets of rotational quantum numbers (J,MJ,K). Label each indicated transition as either allowed or forbidden. Hint: Remember the rules for allowed values of the various quatum numbers. a (0,0,0)(1,1,0)b (0,0,0)(1,0,0) c (3,2,1)(3,1,1)d (4,4,1)(2,4,1)arrow_forwardThe following are sets of rotational quantum numbers (J,MJ,K). Label each indicated transition as either allowed or forbidden. Hint: Remember the rules for allowed values of the various quantum numbers. a (5,4,0)(3,6,0)b (8,2,2)(9,2,2) c (7,4,2)(7,4,2)d (4,2,5)(3,2,5)arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Engineering StudentsChemistryISBN:9781285199023Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage LearningPhysical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,
- Principles of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Physical Chemistry
Chemistry
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Wadsworth Cengage Learning,
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning