Concept explainers
(a)
Interpretation:
The products of reductive amination of the given compounds are to be predicted.
Concept introduction:
When an
(b)
Interpretation:
The products of reductive amination of the given compounds are to be predicted.
Concept introduction:
When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.
(c)
Interpretation:
The products of reductive amination of the given compounds are to be predicted.
Concept introduction:
When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.
(d)
Interpretation:
The products of reductive amination of the given compounds are to be predicted.
Concept introduction:
When an aldehyde or a ketone is converted to an amine, the process is known as reductive amination. The conversion takes place through the formation of an intermediate known as imine. Reductive amination is also known as reductive alkylation.
Want to see the full answer?
Check out a sample textbook solutionChapter 19 Solutions
ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
- Below is the structure of Clemastine and its functional groups. Which of the following statements regarding Clemastine and its functional groups is NOT true? * Ether Tertiary amines CH CH3 Halogenated aromatic hydrocarbon Aromatic hydrocarbon Aliphatic hydrocarbons Clemastine (Tavist) Aromatic hydrocarbon is lipophilic Halogenated aromatic hydrocarbon is lipophilic. Tertiary amine is hydrophobic. Ether is hydrophilic.arrow_forwardIn condensed structural formulas, the amide group in an amide produced from a carboxylic acid and a secondary amine can be written as -CO-NH-. Write the balanced chemical equation for the hydrolysis of N-ethylethanamide with NaOH. CH, CO-NH CH, CH3 + H2O + NAOH Heat CH3-COOH + Na NH,-CH2-CH3 CH3-CO-NH-CH CH3 + HO+ NaOH Heat → CH3-COO H3o'+ Na NH2-CH2-CH3 CH-CO-NH-CH-CH3 + NAOH Heat → CH CO Na + OHNH-CH2-CH3 Heat CH3-CO-NH-CH2-CH3 + NaOH CH3-COO Na" + NH2-CH2-CH3arrow_forward8 (Chemical Connections 19C) Once it has been opened, and particularly if it has been left open to the air, a bottle of aspirin may develop a vinegar-like odor. Explain how this might happen.arrow_forward
- Draw a structure for the product formed in this reductive amination reaction. Upload a jpg image of your answer showing the full reaction (not just the product). + HN NaBH₂CN, EtOH, pH= 4arrow_forwardBecause amines are basic, they can often accept a proton. Draw the protonated structure of n-propylamine.arrow_forwardExplain why CH3 CH2 CH2NH2 is a Brønsted base. Its water solutions are basic. All substances containing nitrogen atoms are Brønsted bases. This amine is a proton donor. This amine can ассеpt a proton from a proton donor.arrow_forward
- 6. The reaction between aniline and nitrous acid at low temperature yields A) an N-nitroso amine B) a diazonium salt C) a nitrile D) an amine nitrite salt 7. An organic nitrogen compound, X, gives ammonia on warming with dilute aqueous sodium hydroxide, X could be A) ethanamide B) ethylamine C) phenylamine D) amino ethanoic acidarrow_forwardCompare the table below by giving the structure and name of a primary (10), secondary(20), and tertiary(30) amine with molecular formula C3H9N. Primary amines can be prepared from amides by Hoffman's reaction. Write a general equation for the reaction and give reagents with reaction conditions for this reaction.arrow_forwardReductive amination of carbonyl compounds produces the same kinds of products as does the reaction of amines and alkyl halides True or Falsearrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning