(a)
To show: The Gabriel synthesis to prepare benzylamine.
Interpretation: The Gabriel synthesis to prepare benzylamine is to be shown.
Concept introduction: The Gabriel synthesis is used for the preparation of primary
(b)
To show: The Gabriel synthesis to prepare hexan-
Interpretation: The Gabriel synthesis to prepare hexan-
Concept introduction: The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis
(c)
To show: The Gabriel synthesis to prepare
Interpretation: The Gabriel synthesis to prepare
Concept introduction: The Gabriel synthesis is used for the preparation of primary amines. It is also called Gabriel phthalimide synthesis. In this synthesis
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Chapter 19 Solutions
ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
- Give each of the following amines an IUPAC name. a. b. c.arrow_forward19. Which of the following molecules contain an amide? H2N-CHC-OH ČH3 a. c. NH2 NH2 b. H2N H2N-CHC-N-CHC-OH d. CHз CH3arrow_forwardClassify each of the following amines as a primary, secondary, or tertiary amine. a. CH3-CH2-CH-CH2-CH3 17-12 NH2 CH3 b. CH3-C-CH3 NH2 c. CH3-N-CH3 CH3 d. CH,—CH—NH-CH—СH2 CH3 CH3arrow_forward
- Assign a common name to each of the following amines. 17-16 a. CH3-CH-CH3 NH2 b. H2N-CH2-CH,-CH2-CH; c. CH3-CH2-Ņ-CH,-CH3 ČH,-CH3 d. CH3-CH2-CH2–NH-CH-CH3 ČH3arrow_forwardWhat is the name of the product formed as a result of the reaction between benzylamine and ethylacrylate (ethylpropenoate)? A. N-benzylpropenamideB. N-phenylpropanamideC. N-phenylpropenamideD. Ethyl-3-aminobenzylpropanoateE. N-Ethyl-N-benzylpropanamidearrow_forwardReductive amination of carbonyl compounds produces the same kinds of products as does the reaction of amines and alkyl halides True or Falsearrow_forward
- Arrange the compounds in order of decreasing basicity A. ethylamine B. 2-aminoethanol C. 3-amino-1-propanolarrow_forwardThe hydrogen on nitrogen atom can be lost (the molecule will behave as an acid) in which of the following cases? O a. Phenylamine derivatives. O b. Primary aliphatic amine c. Secondary aromatic amine O d. Primary aromatic amine O e. Amidearrow_forwardDefine the simplest method to synthesize an amine ?arrow_forward
- 3. Give the pharmacological property of the following alkaloids. Where do they naturally occur? a. morphine b. quinine c. berberine 4. What are the chemical tests used in identifying alkaloids?arrow_forwardVI. What ammonium salt is formed when each amine is treated with HCI? Draw the structure of the resulting salt. a. -NH2 b. -CH,NHCH3arrow_forward6. The reaction between aniline and nitrous acid at low temperature yields A) an N-nitroso amine B) a diazonium salt C) a nitrile D) an amine nitrite salt 7. An organic nitrogen compound, X, gives ammonia on warming with dilute aqueous sodium hydroxide, X could be A) ethanamide B) ethylamine C) phenylamine D) amino ethanoic acidarrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningMacroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks ColeIntroduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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