(a)
Interpretation:
The
Concept introduction:
Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.
(b)
Interpretation:
The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.
Concept introduction:
Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.
(c)
Interpretation:
The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.
Concept introduction:
Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.
(d)
Interpretation:
The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.
Concept introduction:
Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.
(e)
Interpretation:
The amines which can be resolved into enantiomers are to be identified and the reason for the interconversion of the enantiomers takes place or not is to be explained.
Concept introduction:
Enantiomers of a compound are the stereoisomers which are non-super imposable mirror images. A carbon atom bonded to four different groups is known as a chiral carbon. A compound which has a chiral carbon can be resolved into enantiomers.
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ORGANIC CHEMISTRY MASTERINGCHEM ACCESS
- The compounds below can undergo reduction to form a primary amine EXCEPT for what compound? A. NO₂ B. CEN C. NH₂ D. H "N E. Xo -CENarrow_forwardN-Methylpyrrolidine has a boiling point of 81 °C, and piperidine has a boiling point of 106 °C. Tetrahydropyran has a boiling point of 88 °C, and cyclopentanone has a boiling point of 141 °C. These two isomershave a boiling point difference of 53 °C. Explain why the two oxygen-containing isomers have a much larger boilingpoint difference than the two amine isomersarrow_forward1. What is the product of the reaction? 1) LAH 2) Hо* но OH а. b. OH с. HO. HO. d. 2. Which amine is expected to be least soluble in HzO? `NH2 а. c. N. b. d. ZIarrow_forward
- 83. Aliphatic amides 1. are prepared by heating the corresponding aliphatic armmonium carboxylate salt 2. will lost a-CO- group when treated wilth bromate(i) in an alkali 3. can be coverled into the corresponding acid by reacting with NANO HCI. 84. Uren (HN),CO) 1. is an amide because it contains the -C-NH, group 2. has a structure that contains the peptide link 3. reacts with NANO /HCI to give methanoic acidarrow_forwardWhich type of amine is (s)-methamphetamine? a) a primary aliphatic amine b) a primary aromatic amine c) a secondary aliphatic amine d) a secondary aromatic aminearrow_forward6. The reaction between aniline and nitrous acid at low temperature yields A) an N-nitroso amine B) a diazonium salt C) a nitrile D) an amine nitrite salt 7. An organic nitrogen compound, X, gives ammonia on warming with dilute aqueous sodium hydroxide, X could be A) ethanamide B) ethylamine C) phenylamine D) amino ethanoic acidarrow_forward
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- Which type of amine is phentermine? a) a primary aliphatic amine b) a primary aromatic amine c) a tertiary aliphatic amine d) a tertiary aromatic aminearrow_forwardWhich one of the following is a tertiary amine? а. cyclohexylamine b. N,N-dimethylaniline С. N-ethyl-1-propanamine d. 3-pentanaminearrow_forwardexplain the solubility behavior of each representatives amine in water a. aniline b. diethylamine c. N,N-diethylanilinearrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningOrganic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning