EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 2, Problem 2.39AP
Interpretation Introduction
Interpretation:
The reason as to why the bond length and bond angle for compound
Concept introduction:
Newman projection is a way of representing the groups attached to carbon atoms in the
The energy of the conformers varies with change in their dihedral angle. The plot of this variation is known as potential energy curve.
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b) i) Draw the different structural isomers of the 6-membered ring compound
[GAAIBNPAS]H6 in which there are alternating Group 13 and 15 elements.
ii) The isomers containing both B-N and AI-N bonding are the most stable.
Explain why this is the case.
ii) How would you expect the structure and reactivity of the heterocycles
[GAAIBNPAS]H6 to compare with borazine?
iv) While borazine exists as a planar ring compound, the [GAAIBNPAS]H6 ring
compounds dimerize. Explain these observations.
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Compound A (C5H8) readily reacts with bromine (Br2) at room temperature to discharge the purple colour of bromine and form Compound B (C5H8Br2).
When Compound A is treated with H2 in the presence of a transition metal catalyst, it is converted to compound C (C5H10).
When treated with HCl, compound A is converted to compound D (C5H9Cl). B, Cand D are saturated compounds.
Given this information, propose structural formulas for compounds A, B, C, and D.
Compound B contains one chiral carbon atom and reacts with concentrated H2SO4 to yield compounds and
G (both CSH10) that are positional isomers of each other (neither compound is capable of having geometric
isomers). Provide the structures of these compounds in the boxes below. No IUPAC names are necessary.
F
Chapter 2 Solutions
EBK ORGANIC CHEMISTRY
Ch. 2 - Prob. 2.1PCh. 2 - Prob. 2.2PCh. 2 - Prob. 2.3PCh. 2 - Prob. 2.4PCh. 2 - Prob. 2.5PCh. 2 - Prob. 2.6PCh. 2 - Prob. 2.7PCh. 2 - Prob. 2.8PCh. 2 - Prob. 2.9PCh. 2 - Prob. 2.10P
Ch. 2 - Prob. 2.11PCh. 2 - Prob. 2.12PCh. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20PCh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24PCh. 2 - Prob. 2.25APCh. 2 - Prob. 2.26APCh. 2 - Prob. 2.27APCh. 2 - Prob. 2.28APCh. 2 - Prob. 2.29APCh. 2 - Prob. 2.30APCh. 2 - Prob. 2.31APCh. 2 - Prob. 2.32APCh. 2 - Prob. 2.33APCh. 2 - Prob. 2.34APCh. 2 - Prob. 2.35APCh. 2 - Prob. 2.36APCh. 2 - Prob. 2.37APCh. 2 - Prob. 2.38APCh. 2 - Prob. 2.39APCh. 2 - Prob. 2.40APCh. 2 - Prob. 2.41APCh. 2 - Prob. 2.42APCh. 2 - Prob. 2.43APCh. 2 - Prob. 2.44APCh. 2 - Prob. 2.45APCh. 2 - Prob. 2.46APCh. 2 - Prob. 2.47APCh. 2 - Prob. 2.48APCh. 2 - Prob. 2.49APCh. 2 - Prob. 2.50AP
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