Whether you can reorder the steps in the synthesis in Equation 23-48 to produce m-nitrobenzoic acid instead is to be determined. Concept introduction: The CO 2 H group is a meta directing group, so the oxidation of the alkyl group prior to nitration will direct the NO 2 group meta. In the nitration of benzene ring, the ring would be deactivated enough that Friedel-Crafts alkylation would not occur.

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Answer 1

Question

Chapter 23, Problem 23.14YT

Interpretation Introduction

Interpretation:

Whether you can reorder the steps in the synthesis in Equation 23-48 to produce m-nitrobenzoic acid instead is to be determined.

Concept introduction:

The CO2H group is a meta directing group, so the oxidation of the alkyl group prior to nitration will direct the NO2 group meta. In the nitration of benzene ring, the ring would be deactivated enough that Friedel-Crafts alkylation would not occur.

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Answer 2

Question

Chapter 23, Problem 23.14YT

Interpretation Introduction

Interpretation:

Whether you can reorder the steps in the synthesis in Equation 23-48 to produce m-nitrobenzoic acid instead is to be determined.

Concept introduction:

The CO2H group is a meta directing group, so the oxidation of the alkyl group prior to nitration will direct the NO2 group meta. In the nitration of benzene ring, the ring would be deactivated enough that Friedel-Crafts alkylation would not occur.

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Answer 3

Question

Chapter 23, Problem 23.14YT

Interpretation Introduction

Interpretation:

Whether you can reorder the steps in the synthesis in Equation 23-48 to produce m-nitrobenzoic acid instead is to be determined.

Concept introduction:

The CO2H group is a meta directing group, so the oxidation of the alkyl group prior to nitration will direct the NO2 group meta. In the nitration of benzene ring, the ring would be deactivated enough that Friedel-Crafts alkylation would not occur.

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Answer 4

Question

Chapter 23, Problem 23.14YT

Interpretation Introduction

Interpretation:

Whether you can reorder the steps in the synthesis in Equation 23-48 to produce m-nitrobenzoic acid instead is to be determined.

Concept introduction:

The CO2H group is a meta directing group, so the oxidation of the alkyl group prior to nitration will direct the NO2 group meta. In the nitration of benzene ring, the ring would be deactivated enough that Friedel-Crafts alkylation would not occur.

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Answer 5

Chapter 23, Problem 23.14YT

Interpretation Introduction

Interpretation:

Whether you can reorder the steps in the synthesis in Equation 23-48 to produce m-nitrobenzoic acid instead is to be determined.

Concept introduction:

The CO2H group is a meta directing group, so the oxidation of the alkyl group prior to nitration will direct the NO2 group meta. In the nitration of benzene ring, the ring would be deactivated enough that Friedel-Crafts alkylation would not occur.

Answer 6

Chapter 23, Problem 23.14YT

Interpretation Introduction

Interpretation:

Whether you can reorder the steps in the synthesis in Equation 23-48 to produce m-nitrobenzoic acid instead is to be determined.

Concept introduction:

The CO2H group is a meta directing group, so the oxidation of the alkyl group prior to nitration will direct the NO2 group meta. In the nitration of benzene ring, the ring would be deactivated enough that Friedel-Crafts alkylation would not occur.

Answer 7

Chapter 23, Problem 23.14YT

Interpretation Introduction

Interpretation:

Whether you can reorder the steps in the synthesis in Equation 23-48 to produce m-nitrobenzoic acid instead is to be determined.

Concept introduction:

The CO2H group is a meta directing group, so the oxidation of the alkyl group prior to nitration will direct the NO2 group meta. In the nitration of benzene ring, the ring would be deactivated enough that Friedel-Crafts alkylation would not occur.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains that the steps in Equation 23-48 are best to produce m-nitrobenzoic acid.

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