The additional resonance structures of the Meisenheimer complex in Equation 23-35 are to be drawn, indicating the negative charge on C shared over other atoms. Concept introduction: The lone pair of electrons adjacent to a separate π bond can be moved to get a new resonance structure. The uncharged sp 3 -hybridized C atom cannot be involved in resonance.

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Answer 1

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Chapter 23, Problem 23.11YT

Interpretation Introduction

Interpretation:

The additional resonance structures of the Meisenheimer complex in Equation 23-35 are to be drawn, indicating the negative charge on C shared over other atoms.

Concept introduction:

The lone pair of electrons adjacent to a separate π bond can be moved to get a new resonance structure. The uncharged sp3-hybridized C atom cannot be involved in resonance.

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Problem: The Cp2Rh2[µ-(CF3C=CCF3)](CO)(CNR) complex shown above has a Rh-Rh bond distance of 2.67 Å, strongly indicating a covalent bond between the rhodium atoms. How would you electron count this complex to accommodate a Rh-Rh covalent bond?

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Answer 2

Question

Chapter 23, Problem 23.11YT

Interpretation Introduction

Interpretation:

The additional resonance structures of the Meisenheimer complex in Equation 23-35 are to be drawn, indicating the negative charge on C shared over other atoms.

Concept introduction:

The lone pair of electrons adjacent to a separate π bond can be moved to get a new resonance structure. The uncharged sp3-hybridized C atom cannot be involved in resonance.

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Answer 3

Question

Chapter 23, Problem 23.11YT

Interpretation Introduction

Interpretation:

The additional resonance structures of the Meisenheimer complex in Equation 23-35 are to be drawn, indicating the negative charge on C shared over other atoms.

Concept introduction:

The lone pair of electrons adjacent to a separate π bond can be moved to get a new resonance structure. The uncharged sp3-hybridized C atom cannot be involved in resonance.

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Answer 4

Question

Chapter 23, Problem 23.11YT

Interpretation Introduction

Interpretation:

The additional resonance structures of the Meisenheimer complex in Equation 23-35 are to be drawn, indicating the negative charge on C shared over other atoms.

Concept introduction:

The lone pair of electrons adjacent to a separate π bond can be moved to get a new resonance structure. The uncharged sp3-hybridized C atom cannot be involved in resonance.

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Answer 5

Chapter 23, Problem 23.11YT

Interpretation Introduction

Interpretation:

The additional resonance structures of the Meisenheimer complex in Equation 23-35 are to be drawn, indicating the negative charge on C shared over other atoms.

Concept introduction:

The lone pair of electrons adjacent to a separate π bond can be moved to get a new resonance structure. The uncharged sp3-hybridized C atom cannot be involved in resonance.

Answer 6

Chapter 23, Problem 23.11YT

Interpretation Introduction

Interpretation:

The additional resonance structures of the Meisenheimer complex in Equation 23-35 are to be drawn, indicating the negative charge on C shared over other atoms.

Concept introduction:

The lone pair of electrons adjacent to a separate π bond can be moved to get a new resonance structure. The uncharged sp3-hybridized C atom cannot be involved in resonance.

Answer 7

Chapter 23, Problem 23.11YT

Interpretation Introduction

Interpretation:

The additional resonance structures of the Meisenheimer complex in Equation 23-35 are to be drawn, indicating the negative charge on C shared over other atoms.

Concept introduction:

The lone pair of electrons adjacent to a separate π bond can be moved to get a new resonance structure. The uncharged sp3-hybridized C atom cannot be involved in resonance.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2P Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains that the additional resonance structures of the Meisenheimer complex in Equation 23-35 are drawn, indicating the negative charge on C shared over other atoms.

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Chapter 23 Solutions