(a) Interpretation: The orbital overlap picture of Tryptophan is to be drawn. Concept introduction: In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.

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Answer 1

Question

Chapter 23, Problem 23.26A

Interpretation Introduction

(a)

Interpretation:

The orbital overlap picture of Tryptophan is to be drawn.

Concept introduction:

In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.

Interpretation Introduction

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.

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Students have asked these similar questions

(a) Draw the chemical structure of a generic amino acid,using R for the side chain. (b) When amino acids react toform proteins, do they do so via substitution, addition,or condensation reactions? (c) Draw the bond that linksamino acids together in proteins. What is this called?

As we’ve discussed, a peptide bond is made when amino group of one amino acid combines with the carboxylic acid group of another amino acid (releasing a water molecule in the process). The C-N bond formed in this process is called a peptide bond. Peptide bonds have a few properties that might be unexpected. a) One property is that the molecular geometries around the C and N atom in the peptide bond are generally planar with bond angles of approximately 120 degrees. Provide an explanation for why the peptide bond would have this property, using Lewis structures, VSEPR theory and/or valence bond theory as appropriate.

During the hydrolysis of proteins, some amino acids, such as tryptophan, do not survive the reaction conditions. Other amino acids, such as asparagine and glutamine, are modified. Referring to Table 1-7 (p. 39), which shows the structures of the 20 common amino acids, write the structures of the two amino acids that are formed when asparagine and glutamine decompose in hot, concentrated HCl.

Answer 2

Question

Chapter 23, Problem 23.26A

Interpretation Introduction

(a)

Interpretation:

The orbital overlap picture of Tryptophan is to be drawn.

Concept introduction:

In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.

Interpretation Introduction

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.

Expert Solution & Answer

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Answer 3

Question

Chapter 23, Problem 23.26A

Interpretation Introduction

(a)

Interpretation:

The orbital overlap picture of Tryptophan is to be drawn.

Concept introduction:

In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.

Interpretation Introduction

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 23, Problem 23.26A

Interpretation Introduction

(a)

Interpretation:

The orbital overlap picture of Tryptophan is to be drawn.

Concept introduction:

In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.

Interpretation Introduction

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.

Expert Solution & Answer

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See solution

Answer 5

Chapter 23, Problem 23.26A

Interpretation Introduction

(a)

Interpretation:

The orbital overlap picture of Tryptophan is to be drawn.

Concept introduction:

In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.

Interpretation Introduction

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.

Answer 6

Chapter 23, Problem 23.26A

Interpretation Introduction

(a)

Interpretation:

The orbital overlap picture of Tryptophan is to be drawn.

Concept introduction:

In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.

Answer 7

Chapter 23, Problem 23.26A

Interpretation Introduction

(a)

Interpretation:

The orbital overlap picture of Tryptophan is to be drawn.

Concept introduction:

In chemistry, overlapping of orbital takes place to form bonds between the atoms. At least two orbitals must overlap with each other to form a bond. The examples of orbitals are s, p, d, f orbitals. Sigma bond involves the head to head overlapping of two orbitals; on the other hand, π-bond involves the side to side or lateral overlapping of two orbitals.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Prob. 23.1P Ch. 23 - Prob. 23.2A Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4A Ch. 23 - Prob. 23.5P Ch. 23 - Prob. 23.6A Ch. 23 - Draw a complete electron-dot structure for...Ch. 23 - Limonene is the major component in the oil of...Ch. 23 - Draw an orbital overlap picture for methyl a mine...Ch. 23 - Prob. 23.10A

Solution Summary: The author explains how the orbital overlap picture of Tryptophan is used to explain the aromaticity of the compound.

Concept explainers

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.

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Chapter 23 Solutions

Solution Summary: The author explains how the orbital overlap picture of Tryptophan is used to explain the aromaticity of the compound.

Concept explainers

(b) Interpretation: The aromaticity of tryptophan is to be discussed using orbital overlap diagram. Concept introduction: The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor. Aromatic compounds have (4n+2)π electrons.

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Chapter 23 Solutions

(b)

Interpretation:

The aromaticity of tryptophan is to be discussed using orbital overlap diagram.

Concept introduction:

The aromaticity is the phenomena in which compound has odor. The word aromaticity is derived from the word aroma, means odor.

Aromatic compounds have (4n+2)π electrons.