Concept explainers
(a)
Interpretation:
Nitrogen atom that is a more basic among the two nitrogen atoms present in epibatidine has to be explained.
Concept introduction:
Depending on the number of carbon side chain of the nitrogen, different types of amines can form.
According to the explanations by Lewis, if a species donates an electron pair then it is a Lewis base whereas if a species receives an electron pair, then it is Lewis acid.
Hybridization is the mixing of valence atomic orbitals to get equivalent hybridized orbitals that having similar characteristics and energy.
(b)
Interpretation:
Chiral centers in epibatidine have to be marked.
Concept Introduction:
Amines are the derivatives of ammonia
Depending on the number of carbon side chain of the nitrogen, different types of amines can form.
Chirality: It refers to an atom in a molecule that contains four different substituents.
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Chapter 23 Solutions
Organic Chemistry
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- Compound 1 is an anticoagulant that is extracted from, among other plants, the sweetclover plant, Melilotus Officinalis. However, the compound is moderately toxic and alsofinds use as a rodenticide. Name this compoundarrow_forwardPlace the binders below in descending order of acidity (pi) and justify your choice: CH3CN; (C2H5)2O; PCl3; As(C6H5)3; (C2H5)3Narrow_forwardRank each set of compounds in order of increasing basicity.pyrrole, imidazole, 3-nitropyrrolearrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning