Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material. Concept Introduction: Conversion of aromatic amines to phenol: Aromatic amines converted to arenediazonium salt by reacting with N a N O 2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Question

(a) Draw the structures of the following compounds :(i) 4-Chloropentan-2-one (ii) p-Nitropropiophenone(b) Give tests to distinguish between the following pairs of compounds :(i) Ethanal and Propanal (ii) Phenol and Benzoic acid(iii) Benzaldehyde and Acetophenone

Answer 1

Question

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

(a) Draw the structures of the following compounds :(i) 4-Chloropentan-2-one (ii) p-Nitropropiophenone(b) Give tests to distinguish between the following pairs of compounds :(i) Ethanal and Propanal (ii) Phenol and Benzoic acid(iii) Benzaldehyde and Acetophenone

(a) Arrange the following compounds in an increasing order of their indicated property :(i) Benzoic acid, 4-Nitrobenzoic acid, 3,4-Dinitrobenzoic acid, 4-Methoxybenzoic acid (acid strength)(ii) CH3CH2CH (Br) COOH, CH3CH (Br) CH2COOH,(CH3)2CHCOOH, CH3CH2CH2COOH (acid strength)(b) How would you bring about the following conversions :(i) Propanone to Propene (ii) Benzoic acid to Benzaldehyde(iii) Bromobenzene to 1-phenylethanol

Reaction of p-nitroaniline with sodium nitrite and hydrochloric acid at 0°C, followed by treatment with N,N-diethylaniline.

Answer 2

Question

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Answer 6

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Answer 7

Chapter 23.8, Problem 23.13P

(a)

Interpretation Introduction

Interpretation:

Synthesis of 3-nitrophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Synthesis of 3-bromo nitrobenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Synthesis of 1,3-dihydroxybenzene has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluoroaniline has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Synthesis of 3-fluorophenol has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Conversion of aromatic amines to phenol:

Aromatic amines converted to arenediazonium salt by reacting with NaNO2 in presence of aqueous sulfuric acid which further on heating with water forms a phenol.

Schiemann reaction: It is a method used to introduce fluorine into an aromatic ring. The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl followed by the reaction with NaBF4 or HBF4 that results in the introduction of a fluorine atom in the compound.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Synthesis of 3-hydroxybenzonitrile has to be proposed using 3-nitroaniline as starting material.

Concept Introduction:

Hydrogenation:

Hydrogenation means the addition of hydrogen molecules to the unsaturated compound which makes them saturated hydrocarbon in the presence of catalyst.

Reaction of a primary aromatic amine with sodium nitrite:

The reaction of a primary aromatic amine with sodium nitrite in presence of aqueous HCl gives an arenediazonium salt.

Sandmeyer reaction: It reaction type of organic reaction where the diazonium group in an arenediazonium salt gets replaced by −Cl, −Br or −CN groups on reacting with HCl/CuCl, HBr/CuBr or HCN/CuCN.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 21

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 22

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 23

Trending nowThis is a popular solution!

Answer 24

Trending nowThis is a popular solution!

Answer 25

Trending nowThis is a popular solution!

Answer 26

Trending now

Answer 27

This is a popular solution!

Answer 28

See solution

Check out sample textbook solution

Answer 29

Ch. 23.1 - Prob. 23.1P Ch. 23.2 - Prob. 23.2P Ch. 23.2 - Prob. 23.3P Ch. 23.2 - Prob. 23.4P Ch. 23.5 - Prob. 23.5P Ch. 23.5 - Prob. AQ Ch. 23.5 - What is the hybridization of the nitrogen in...Ch. 23.5 - Prob. CQ Ch. 23.5 - The pKas of the conjugate acids of aniline and...Ch. 23.5 - Prob. EQ

Chapter 23 Solutions