The synthesis of the standard amino acid from the given starting material is to be stated. Concept introduction: The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24, Problem 24.30SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

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By using only amide/Peptide bond forming rxn and a lKylation rxns. Provide all the reaction steps with the reagent needed and conditions with out showing the mechanism for each step to form the product. Note: Use protecting groups like (Boc, Fmoc, and others) H2NNH2+

The reaction of ninhydrin with an -amino acid occurs in several steps (a) The first step is loss of water to give a triketone. Show the mechanism of the reaction and the structure of the triketone.(b) The second step is formation of an imine by reaction of the amino acid with the triketone. Show its structure. (c) The third step is a decarboxylation. Show the structure of the product and the mechanism of the decarboxylation reaction. (d) The fourth step is hydrolysis of an imine to yield an amine and an aldehyde. Show the structures of both products. (e) The final step is formation of the purple anion. Show the mechanism of the reaction

(a) Isoleucine has been prepared by the following sequence of reactions. Give the structure of compounds A through D isolated as intermediates in this synthesis.(b) An analogous procedure has been used to prepare phenylalanine. What alkyl halide would you choose as the starting material for this synthesis?

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24, Problem 24.30SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24, Problem 24.30SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 24, Problem 24.30SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Expert Solution & Answer

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Answer 5

Chapter 24, Problem 24.30SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Answer 6

Chapter 24, Problem 24.30SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Answer 7

Chapter 24, Problem 24.30SP

(a)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The synthesis of the standard amino acid from the given starting material is to be stated.

Concept introduction:

The compounds that contain an amine group and a carboxyl group attached with a side chain usually alkyl or aromatic chains are known as amino acids. These compounds are used as structural units to make proteins. Amino acids are joined together with a peptide bond to form proteins.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 24.2A - Draw three-dimensional representations of the...Ch. 24.2A - Prob. 24.2P Ch. 24.2B - The herbicide glyphosate (Roundup) kills plants by...Ch. 24.4 - Draw the structure of the predominant form of a....Ch. 24.4 - Draw the resonance forms of a protonated guanidino...Ch. 24.4 - Although tryptophan contains a heterocyclic amine,...Ch. 24.4 - Prob. 24.7P Ch. 24.4 - Prob. 24.8P Ch. 24.5A - Show how the following amino acids might be formed...Ch. 24.5B - Prob. 24.10P

Solution Summary: The author explains that the synthesis of the standard amino acid from the given starting material is to be stated.

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