EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
10th Edition
ISBN: 9781259636875
Author: Carey
Publisher: MCGRAW HILL BOOK COMPANY
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Chapter 24.18, Problem 24P
Interpretation Introduction

Interpretation:

The hexose that gives the same aldaric acid on oxidation as given by D-glucose is to be identified.

Concept introduction:

The oxidation of both groups CH2OH and CHO of aldoses to carboxylic group forms an aldaric acid.

As both the groups are COOH in aldaric acid, the numbering of carbon can start from either of COOH group.

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Another hexose gives the same aldaric acid on oxidation as does d-glucose. Which one?
Provide an explanation for the fact that α-D-mannose is more stable thanβ-D-mannose, whereas the opposite is true for glucose.
Which compound are both Aldose and hexose?
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