GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.
11th Edition
ISBN: 9780134566030
Author: Petrucci
Publisher: PEARSON
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Question
Chapter 27, Problem 63IAE
Interpretation Introduction
Interpretation:
Whether
Concept introduction:
Alcohols can be oxidized to give
Primary alcohols upon oxidation give aldehyde and secondary alcohol give ketones.
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Potassium permanganate and potassium dichromate are very similar in their oxidizing abilities, however there are differences. If I want to convert 4-hexen-1-ol into 4-hexenoic acid, which would be the appropriate oxidizing agent to use? Explain your answer using equations that show the two different products that would form via the two different oxidizing agents.
2.) Draw 1 isomer of the compounds in item no. 3, and state the type of isomerism.
Example: 2-hydroxy-pentanal
OH
Structure:
Isomer:
OH
Type of isomerism: Functional Isomerism
3.) Predict the product of the following chemical reactions and state where the product (waste) should the
waste should be disposed:
Example:
OH
1. NaBH, ethanol
2. HO
CH,CH,CH,CH
CH;CH,CH,CH
H
Butanal
1-Butanol
Waste: G704 (Non-halogenated organic solvents)
1. NaBH,, ethanol
a.) Cyclohexanecarbaldehyde 2. H,O"
b.) Sodium Flouride + 3-iodo-3-methylpentane
(hint: substitution or elimination?)
c.) Benzoic acid + Phenol
РСС
d.) 3-pentanol
H>CrO4
e.) Cyclohexylmethanol
1. Explain the following
- why stearic acid has higher melting point than decanoic acid.
- why benzoic acid has higher melting point than stearic acid.
- why salicylic acid has higher melting point than benzoic acid.
- why octane has a higher melting point than isooctane.
- why 2,2,3,3-tetramethylbutane has the highest melting point among the three isomers of C8H18.
Chapter 27 Solutions
GENERAL CHEMISTRY(LL)-W/MASTERINGCHEM.
Ch. 27 - Describe what is meant by each of the following...Ch. 27 - Prob. 2ECh. 27 - Prob. 3ECh. 27 - Prob. 4ECh. 27 - Prob. 5ECh. 27 - Prob. 6ECh. 27 - Prob. 7ECh. 27 - Prob. 8ECh. 27 - Answer the following questions for this SN2...Ch. 27 - Answer the following questions for this SN1...
Ch. 27 - Substitution and Elimination Reactions Answer the...Ch. 27 - Prob. 12ECh. 27 - Prob. 13ECh. 27 - Prob. 14ECh. 27 - Prob. 15ECh. 27 - Substitution and Elimination Reactions Molecule...Ch. 27 - Prob. 17ECh. 27 - Prob. 18ECh. 27 - Prob. 19ECh. 27 - Prob. 20ECh. 27 - Prob. 21ECh. 27 - Prob. 22ECh. 27 - Prob. 23ECh. 27 - Substitution and Elimination Reactions (R) — 2 —...Ch. 27 - Prob. 25ECh. 27 - Prob. 26ECh. 27 - Prob. 27ECh. 27 - Prob. 28ECh. 27 - Prob. 29ECh. 27 - Alcohols and Alkenes Predict the product(s) of the...Ch. 27 - Prob. 31ECh. 27 - Alcohols and Alkenes Give the structure of the...Ch. 27 - Alcohols and Alkenes Give the major product that...Ch. 27 - Prob. 34ECh. 27 - Prob. 35ECh. 27 - Prob. 36ECh. 27 - Prob. 37ECh. 27 - Prob. 38ECh. 27 - Prob. 39ECh. 27 - Prob. 40ECh. 27 - Prob. 41ECh. 27 - Prob. 42ECh. 27 - Reactions of Alkanes (a) Write the initiation,...Ch. 27 - Reactions of Alkanes Write the initiation,...Ch. 27 - Prob. 45ECh. 27 - Polymerization Reactions Explain why Dacron is...Ch. 27 - Prob. 47ECh. 27 - Prob. 48ECh. 27 - Prob. 49ECh. 27 - Prob. 50ECh. 27 - Prob. 51ECh. 27 - Prob. 52ECh. 27 - Prob. 53ECh. 27 - Prob. 54ECh. 27 - Prob. 55IAECh. 27 - Prob. 56IAECh. 27 - Prob. 57IAECh. 27 - Prob. 58IAECh. 27 - Prob. 59IAECh. 27 - Prob. 60IAECh. 27 - Prob. 61IAECh. 27 - Prob. 62IAECh. 27 - Prob. 63IAECh. 27 - Prob. 64IAECh. 27 - Prob. 65IAECh. 27 - Prob. 66IAECh. 27 - Prob. 67IAECh. 27 - Prob. 68IAECh. 27 - Prob. 69IAECh. 27 - Prob. 70IAECh. 27 - Prob. 71IAECh. 27 - Prob. 72IAECh. 27 - Prob. 73IAECh. 27 - Prob. 74IAECh. 27 - Prob. 75IAECh. 27 - Prob. 76IAECh. 27 - Prob. 77IAECh. 27 - The reduction of aldehydes and ketones with a...Ch. 27 - Explain the important distinctions between each...Ch. 27 - Prob. 80SAECh. 27 - Prob. 81SAECh. 27 - Prob. 82SAECh. 27 - Prob. 83SAECh. 27 - Prob. 84SAECh. 27 - What is the major organic product obtained in the...Ch. 27 - Prob. 86SAE
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