Interpretation:
The number of the different monochloro derivative of
Concept introduction:
The free radical substitution reaction is the type of reaction that occurs by the free radical mechanism, free radical is formed during the reaction.
The chlorination of alkane is the radical substitution reaction. There are three steps are involved in the
The expression to calculate the mono chlorination product is as follows:
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EBK GENERAL CHEMISTRY
- 5. Consider the synthesis of 2-butanone from butyne: Hg2+ CH3CH,-C=C–H CH3CH, Ĉ -CH3 H3o* (i) Draw the structure of the compound D. (ii) Compound D isomerizes to form 2-butanone. What is this isomeric process called? (iii) Use the mechanism to show the conversion of compound D to 2-butanone.arrow_forward7.44 Give the structures of two different alkyl bromides both of which yield the indicated alkene as the exclusive product of E2 elimination. (а) СH;CH—CH, (b) (CH3)2С—СH2 (c) BRCH=CB12 CH3 (d) CH3arrow_forward5) Limonene is a compound found in orange oil and lemon oil with molecular formula C₁0H16- When limonene is treated with 1 equivalent of mCPBA, the product is limonene oxide as depicted below. When limonene is treated with excess ozone (03) and then with dimethylsulfide (Me₂S), one of the organic products of the reaction is formaldehyde. Of the structures below, which correspond to the structure of limonene and/or the structure of the other major organic product when limonene is reacted with O3 and Me₂S? Please select any and all that apply. A) 'Н H B) ? H 1) 03 (XS) 2) Me₂S (xs) ? limonene, C10H16 D) mCPBA (1 equiv) E) limonene oxide None of the abovearrow_forward
- G.152.arrow_forwardRings + Unsaturation --- Hydrogenation If compound A C51H81BrN5O3P3 is hydrogenated to give compound B C51H101BrN5O3P3. How many rings does compound A have? Assume that P has a valency of 5. Would the answer be 4 rings? Formula -> unsat + rings = 1+C +N/2 - H/2 - X/2arrow_forwardGive the major organic product(s) for each of the following reactions:arrow_forward
- Alloocimene is a hydrocarbon found in turpentine. It has the molecular formula C₁0H16 and a UV absorption maximum at 290 nm. On hydrogenation with a palladium catalyst, 2,6-dimethyloctane is obtained. Ozonolysis of alloocimene, followed by treatment with zinc and acetic acid, produces the following four fragments: || CH3C-CH i O || || CH3CCH3 HC-CH Propose a structure for alloocimene. O || CH3CHarrow_forwardCompound X, C,4H12Br2, is optically inactive. On treatment with strong base, X gives hydrocarbon Y, C14H10: Compound Y absorbs 2 equivalents of hydrogen when reduced over a palladium catalyst to give z (C14H14) and reacts with ozone to give one product, benzoic acid (C,Hg02). Draw the structure of compound Z. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Ignore alkene stereochemistry. • If more than one structure fits the description, draw them all. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate structures with + signs from the drop-down menu. ChemDoodlearrow_forwardCompound A, C9H₁6 reacts with 1 molar equivalent(s) of hydrogen upon catalytic hydrogenation. A undergoes reaction with ozone, followed by Zn treatment, to give: CHỊCHỊCH CH3CCH₂CH₂CH₂CH₂CH₂CCH3 || Propose a structure for A.arrow_forward
- Compound A has the formula C8H8. It reacts rapidly with KMN04 to give CO2 and a carboxylic acid, B (C7H602), but reacts with only 1 molar equivalent of H2 on catalytic hydrogenation over a palladium catalyst. On hydrogenation under conditions that reduce aromatic rings, 4, equivalents of H2 are taken up and hydrocarbon C (C8H16) is produced. What are the structures of A, B, and C. .CO.H COH A A B C OH A CO2H A B QUESTION 6arrow_forwardAn alkene having the molecular formula C11H20 is treated sequentially with ozone (O3) and zinc/acetic acid to give the product/s shown. CH;CH2ČCH,CH3 Draw a structural formula for the alkene. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. In cases where there is more than one answer, just draw one. C opy aste ChemDoodlearrow_forwardCompound A, C₂H16 reacts with 1 molar equivalent(s) of hydrogen on catalytic hydrogenation. A undergoes reaction with ozone, followed by Zn treatment, to give: O CH3 O || CH3CCH₂CCH₂CCH3 CH3 Compound A Propose a structure for A. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one.arrow_forward
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