Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
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Chapter 3, Problem 3.14P
Consider the series
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Chapter 3 Solutions
Inorganic Chemistry
Ch. 3.1 - Use electron-dot diagrams and formal charges to...Ch. 3.2 - Predict the structures of the following ions....Ch. 3.2 - Prob. 3.3ECh. 3.2 - Which molecule has the smallest bond angle in each...Ch. 3.2 - Briefly account for the following observations: a....Ch. 3.2 - Does this approach work for different steric...Ch. 3 - The dimethyldithiocarbamate ion, [S2CN( CH 3 )2]-...Ch. 3 - Several resonance structures are possible for each...Ch. 3 - Draw the resonance structures for the...Ch. 3 - Three isomers having the formula N2CO are known:...
Ch. 3 - Show the possible resonance structures for nitrous...Ch. 3 - Nitric acid, which exists as HNO3 molecules in the...Ch. 3 - L. C. Allen has suggested that a more meaningful...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Explain the trends in bond angles and bond lengths...Ch. 3 - Select from each set the molecule or ¡on having...Ch. 3 - a. Compare the structures of the azide ion, N3 ,...Ch. 3 - Consider the series OCl2,O( CH3)2 , and O( SiH3)2...Ch. 3 - Two ions isoelectronic with carbon suboxide, C3O2...Ch. 3 - Explain the following: a. Ethylene, C2H4 , is a...Ch. 3 - Explain the following: a. PCI5 is a stable...Ch. 3 - X-ray crystal structures of ClOF3 and BrOF3 have...Ch. 3 - Make the following comparisons about the molecules...Ch. 3 - Prob. 3.20PCh. 3 - A solution containing the lO2F2 ion reacts slowly...Ch. 3 - The XeOF3 anion has been reported recently (D. S....Ch. 3 - Predict the structure of l(CF3)Cl2 . Do you expect...Ch. 3 - a. Which has the longer axial PF distance, PF2(...Ch. 3 - Prob. 3.25PCh. 3 - SeCl62,TeCl62 , and CIF6 are all octahedral, but...Ch. 3 - Prob. 3.27PCh. 3 - The thiazyldichloride ion, NSCl2- , is...Ch. 3 - Sketch the most likely structure of PCl3Br2 and...Ch. 3 - a. Are the CF3 groups in PCl3( CF3)2 more likely...Ch. 3 - Of the molecules C1SO2CH3,C1SO2CF3 , and ClSO2CCl3...Ch. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Although the CF distances and the FCF bond angles...Ch. 3 - The Cl...Cl distance in CCl4 is 289 pm, and the...Ch. 3 - The FCF angle in F2CO , shown here, is 109.5°; the...Ch. 3 - Compounds in which hydrogen is the outer atom can...Ch. 3 - For each of the following bonds, indicate which...Ch. 3 - Give Lewis dot structures and shapes for the...Ch. 3 - Give Lewis dot structures and sketch the shapes...Ch. 3 - Which of the molecules in Problem 3.41 are polar?Ch. 3 - Which of the molecules in Problem 3.42 are polar?Ch. 3 - Prob. 3.45PCh. 3 - Prob. 3.46P
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- Aspirin, or acetylsalicylic acid, has the formula C9H8O4 and the skeleton structure (a) Complete the Lewis structure and give the number of bonds and bonds in aspirin. (b) What is the hybridization about the CO2H carbon atom (colored blue)? (c) What is the hybridization about the carbon atom in the benzene-like ring that is bonded to an oxygen atom (colored red)? Also, what is the hybridization of the oxygen atom bonded to this carbon atom?arrow_forwardDraw the Lewis structures and predict the hybridization (sp, sp2, sp3), geometry (linear, trigonal, tetrahedral), and bond angles (180°, 120°, 109.5°) for the central atoms in the following compounds. C and N in C CH3CNarrow_forwardWhat are the bond angles around heteroatoms and non-sp3 hybridised C atoms in C14H23NO ?arrow_forward
- Draw the Lewis Structures for the following molecules and give the hybridization for each carbon atom. a) 2-methyl-1-butanol, CH3CH2CH2(CH3)CH2OH b) Ethyl propanoate, CH3CH2CO2CH2CH3 c) Methyl cyanide (aka acetonitrile), CH3CN d) Isopropyl phenyl ether, (CH3)2CHOC6H5 e) N,N-dimethylpentamide, CH3CH2CH2CH2CON(CH3)2arrow_forwardDraw a line-bond structure for propene, CH3CH=CH2. Indicate the hybridization of the orbitals on each carbon, and predict the value of each bond angle.arrow_forwardExplain the structure of benzene (C6H6) in detail using a ubiquitous electron model (the theory of atomic electron bonding) and the theory of molecular orbital function theoryarrow_forward
- What is the ground state electron configuration for Be+2? What is the bond order for Be+2?arrow_forwardDraw the Lewis structures and predict the hybridization (sp, sp2, sp3), geometry (linear, trigonal, tetrahedral) and bond angles (180°, 120°, 109.5°) for the central atoms in the following compounds. a. C and N in CH3CN b. C in CH3CHCHCH3arrow_forwardWhat are the angles at atom C(5)?arrow_forward
- Draw the Lewis structures and predict the hybridization (sp, sp2, sp3), geometry (linear, trigonal, tetrahedral) and bond angles (180°, 120°, 109.5°) for the central atoms in the following compounds. a. N in NH3 d. C and N in CH3CHNH b. O in CH2O e. C and N in CH3CN c. C in CH3CHCHCH3arrow_forwardFor the following descriptions of molecules, draw the Lewis structure (showing all atoms, lone pairs, formal changes) of the molecule and show all bond angles (assuming ideal VSEPR angles) 1) An organic compound with the molecular formula H3CNO2. C is sp2 hybridized, N is sp3 hybridized, one O is sp2 hybridized, while the second O is sp3 hybridized.arrow_forwardFor the following descriptions of molecules, draw the Lewis structure (showing all atoms, lone pairs, formal changes) of the molecule and show all bond angles (assuming ideal VSEPR angles) 2) An organic compound with molecular formula H2CNO+. Both C and O are sp hybridized while N is sp3 hybridized.arrow_forward
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