EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 4, Problem 4.2P
Interpretation Introduction
Interpretation:
Among the given
Concept introduction:
The stereoisomers of the double bond are cis-trans and E-Z isomers. These configurations of the alkenes arise from the arrangement of groups on both sides of the group respective to each other. For the alkene to be a stereocenter two groups on both side of the double bond must be different from each other.
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Which of the following alkenes can exist as cis-trans isomers? Write their structures.
(a) CH2=CHCH2CH3
(c) CH2=C(CH3)2
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(d) CH3CH2CH=CHCI
Write structural formulas for compounds that meet the following descriptions:(a) An alkene, C6H12, that cannot have cis–trans isomersand whose longest chain is 5 carbons long(b) An alkene with a chemical formula of C10H12 that hascis–trans isomers and contains a benzene ring.
Which of the following cycloalkanes are capable of geometric (cis-trans) isomerism?Draw the cis and trans isomers.(a) 3-ethyl-1,1-dimethylcyclohexane (b) 1-ethyl-3-methylcycloheptane(c) 1-ethyl-3-methylcyclopentane (d) 1-cyclopropyl-2-methylcyclohexane
Chapter 4 Solutions
EBK ORGANIC CHEMISTRY
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - Prob. 4.3PCh. 4 - Prob. 4.4PCh. 4 - Prob. 4.5PCh. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Prob. 4.8PCh. 4 - Prob. 4.9PCh. 4 - Prob. 4.10P
Ch. 4 - Prob. 4.11PCh. 4 - Prob. 4.12PCh. 4 - Prob. 4.13PCh. 4 - Prob. 4.14PCh. 4 - Prob. 4.15PCh. 4 - Prob. 4.16PCh. 4 - Prob. 4.17PCh. 4 - Prob. 4.18PCh. 4 - Prob. 4.19PCh. 4 - Prob. 4.20PCh. 4 - Prob. 4.21PCh. 4 - Prob. 4.22PCh. 4 - Prob. 4.23PCh. 4 - Prob. 4.24PCh. 4 - Prob. 4.25PCh. 4 - Prob. 4.26PCh. 4 - Prob. 4.27PCh. 4 - Prob. 4.28PCh. 4 - Prob. 4.29PCh. 4 - Prob. 4.30PCh. 4 - Prob. 4.31PCh. 4 - Prob. 4.32PCh. 4 - Prob. 4.33PCh. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Prob. 4.39PCh. 4 - Prob. 4.40APCh. 4 - Prob. 4.41APCh. 4 - Prob. 4.42APCh. 4 - Prob. 4.43APCh. 4 - Prob. 4.44APCh. 4 - Prob. 4.45APCh. 4 - Prob. 4.46APCh. 4 - Prob. 4.47APCh. 4 - Prob. 4.48APCh. 4 - Prob. 4.49APCh. 4 - Prob. 4.50APCh. 4 - Prob. 4.51APCh. 4 - Prob. 4.52APCh. 4 - Prob. 4.53APCh. 4 - Prob. 4.54APCh. 4 - Prob. 4.55APCh. 4 - Prob. 4.56APCh. 4 - Prob. 4.57APCh. 4 - Prob. 4.58APCh. 4 - Prob. 4.59APCh. 4 - Prob. 4.60APCh. 4 - Prob. 4.61APCh. 4 - Prob. 4.62APCh. 4 - Prob. 4.63APCh. 4 - Prob. 4.64APCh. 4 - Prob. 4.65APCh. 4 - Prob. 4.66APCh. 4 - Prob. 4.67APCh. 4 - Prob. 4.68APCh. 4 - Prob. 4.69APCh. 4 - Prob. 4.70AP
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- Write Lewis structures and describe the molecular geometry at each carbon atom in the following compounds:(a) cis-3-hexene(b) cis-1-chloro-2-bromoethene(c) 2-pentyne(d) trans-6-ethyl-7-methyl-2-octenearrow_forwardTRUE OR FALSE (a) Both ethylene and acetylene are planar molecules. (b) An alkene in which each carbon of the double bond has two different groups bonded to it will show cis-trans isomerism. (c) Cis-trans isomers have the same molecular formula but a different connectivity of their atoms. (d) Cis-2-butene and trans -2-butene can be interconverted by rotation about the carbon–carbon double bond. (e) Cis-trans isomerism is possible only among appropriately substituted alkenes. (f) Both 2-hexene and 3-hexene can exist as pairs of cis-trans isomers. (g) Cyclohexene can exist as a pair of cis-trans isomers. (h) 1-Chloropropene can exist as a pair of cis-trans isomers.arrow_forward(b) NABH, CH3 COCH,CH3 CH3CH2OH (c)arrow_forward
- 2,3-Dibromoprop-1-ene (C3H4Br2) has four H atoms. Suppose that any of these H atoms can be replaced by a Cl atom to yield a molecule with the formula C3H3Br,Cl. (a) Identify two H atoms where this substitution would yield constitutional isomers of C3H3Br,CI; (b) enantiomers of C3H3Br,Cl; (c) diastereomers of C3H3Br,Cl. H нн H Br Br 2,3-Dibromoprop-1-enearrow_forward(a) Write the IUPAC names of the following compounds :(i) CH3CO(CH2)4CH3 (ii) Ph — CH = CH — CHO(b) Describe the following conversions in not more than two steps :(i) Ethanol to 3-Hydroxybutanal (ii) Benzoic acid to m-Nitrobenzyl alcohol(iii) Propanone to Propenearrow_forwardName and draw a structural formula for the major product of each alkene addition reaction: CH S (a) CH₂C=CH₂ + HI →→→→ (b) CH 3 + HClarrow_forward
- Give the IUPAC name of the following compounds: (a) HạC CH3 (D) CH3 H2C=CHCHCH3 CH3CH,CH=CCH,CH3 CH3 (c) CH3 (d) CH3CHCH,CH3 CH,CH=CHCHCH=CHCHCH, CH,CH,CH,CH=CHCHCH,CH,arrow_forwardWrite the reagent or draw structures of the starting material or organic product(s) in the following reactions. If more than one product is formed, identify the major product where possible. (a) (b) HO OH OH H2SO4 ? Cl₂ ? FeCl3arrow_forwardName or write the condensed structural formula for the fol- lowing compounds: (a) trans-2-pentene (b) 2,5-dimethyl-4-0octene (c) CH3 CH;CH2 CH,ĊHCH,CH3 Н `H (d) Br Br (e) CH-CHЗ НС—ССH-CСНЗ ČH3arrow_forward
- Classify each of the following reactions as an addition, elimination, substitution, or rearrangement: (a) CH3Br + KOH → CH3OH + KBr(b) CH3CH2Br → H2C=CH2 + HBr(c) H2C=CH2 + H2 → CH3CH3arrow_forwardFor each of the compounds below, state its systematic name, its functional group(s), and whether or not it is chi- ral. CH3 O С—ОН CH-CНCHC—О NH (a) Ć (b) CH-CH-CH3CHСНЗ CH;CH,CH3 (c) (d)arrow_forward(a) Draw the condensed structural formulas for the cis andtrans isomers of 2-pentene. (b) Can cyclopentene exhibitcis–trans isomerism? Explain. (c) Does 1-pentyne haveenantiomers? Explain.arrow_forward
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