University Physics with Modern Physics (14th Edition)
14th Edition
ISBN: 9780321973610
Author: Hugh D. Young, Roger A. Freedman
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Question
Chapter 42, Problem 42.9DQ
To determine
In what ways do atoms in a diatomic molecule behave as though they were held together by a spring and in ways is this a poor description of the interaction between the atoms.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
What is the minimum energy required to go from one vibrational state to the next higher vibrational state for a molecule whose vibrations are modeled by a harmonic oscillator?
However, the molecule we can encounter everyday continuously vibrates and interact with the surrounding causing its bond vector to vary slightly. According to a new spectroscopy analysis, the adjacent bond vectors was found to be
A = 0.82i + 0.99j + 0.84k
B = 1.09i + -1.01j + -0.97k
What is the angle (in degrees) between the bonds based on this new data?
When are the rotational degrees of freedom of a diatomic molecule expected to contribute R to the molar constant volume heat capacity? When will a vibrational degree of freedom contribute R to the molar heat capacity?
Chapter 42 Solutions
University Physics with Modern Physics (14th Edition)
Ch. 42.1 - If electrons obeyed the exclusion principle but...Ch. 42.2 - Prob. 42.2TYUCh. 42.3 - Prob. 42.3TYUCh. 42.4 - One type of thermometer works by measuring the...Ch. 42.5 - Prob. 42.5TYUCh. 42.6 - Prob. 42.6TYUCh. 42.7 - Suppose a negative charge is placed on the gate of...Ch. 42 - Van der Waals bonds occur in many molecules, but...Ch. 42 - Prob. 42.2DQCh. 42 - The H2+ molecule consists of two hydrogen nuclei...
Ch. 42 - The moment of inertia for an axis through the...Ch. 42 - Prob. 42.5DQCh. 42 - Prob. 42.6DQCh. 42 - Prob. 42.7DQCh. 42 - The air you are breathing contains primarily...Ch. 42 - Prob. 42.9DQCh. 42 - Prob. 42.10DQCh. 42 - What factors determine whether a material is a...Ch. 42 - Prob. 42.12DQCh. 42 - Prob. 42.13DQCh. 42 - Prob. 42.14DQCh. 42 - Prob. 42.15DQCh. 42 - Prob. 42.16DQCh. 42 - Prob. 42.17DQCh. 42 - Prob. 42.18DQCh. 42 - Prob. 42.19DQCh. 42 - Prob. 42.20DQCh. 42 - Prob. 42.21DQCh. 42 - Prob. 42.22DQCh. 42 - Prob. 42.23DQCh. 42 - Prob. 42.24DQCh. 42 - If the energy of the H2 covalent bond is 4.48 eV,...Ch. 42 - An Ionic Bond, (a) Calculate the electric...Ch. 42 - Prob. 42.3ECh. 42 - Prob. 42.4ECh. 42 - Prob. 42.5ECh. 42 - Prob. 42.6ECh. 42 - Prob. 42.7ECh. 42 - Two atoms of cesium (Cs) can form a Cs2 molecule....Ch. 42 - Prob. 42.9ECh. 42 - Prob. 42.10ECh. 42 - A lithium atom has mass 1.17 1026 kg, and a...Ch. 42 - Prob. 42.12ECh. 42 - When a hypothetical diatomic molecule having atoms...Ch. 42 - The vibrational and rotational energies of the CO...Ch. 42 - Prob. 42.15ECh. 42 - Prob. 42.16ECh. 42 - Prob. 42.17ECh. 42 - Prob. 42.18ECh. 42 - Prob. 42.19ECh. 42 - Prob. 42.20ECh. 42 - Prob. 42.21ECh. 42 - Prob. 42.22ECh. 42 - Prob. 42.23ECh. 42 - Prob. 42.24ECh. 42 - Prob. 42.25ECh. 42 - Prob. 42.26ECh. 42 - Prob. 42.27ECh. 42 - Prob. 42.28ECh. 42 - Prob. 42.29ECh. 42 - Prob. 42.30ECh. 42 - Prob. 42.31ECh. 42 - Prob. 42.32ECh. 42 - Prob. 42.33PCh. 42 - Prob. 42.34PCh. 42 - Prob. 42.35PCh. 42 - The binding energy of a potassium chloride...Ch. 42 - (a) For the sodium chloride molecule (NaCl)...Ch. 42 - Prob. 42.38PCh. 42 - Prob. 42.39PCh. 42 - Prob. 42.40PCh. 42 - Prob. 42.41PCh. 42 - Prob. 42.42PCh. 42 - Prob. 42.43PCh. 42 - Prob. 42.44PCh. 42 - Prob. 42.45PCh. 42 - Prob. 42.46PCh. 42 - Prob. 42.47PCh. 42 - Prob. 42.48PCh. 42 - Prob. 42.49PCh. 42 - Prob. 42.50PCh. 42 - Prob. 42.51PCh. 42 - Prob. 42.52PCh. 42 - Prob. 42.53CPCh. 42 - Prob. 42.54CPCh. 42 - Prob. 42.55CPCh. 42 - Prob. 42.56PPCh. 42 - Prob. 42.57PPCh. 42 - Prob. 42.58PP
Knowledge Booster
Similar questions
- Compare the effective force constant for the CO molecule deduced here with that of an ordinary laboratory spring that stretches 0.5 m when a 1.0 kg mass is suspended from it.arrow_forwardThe intensities of spectroscopic transitions between the vibrational states of a molecule are proportional to the square of the integral ∫ψv′xψvdx over all space. Use the relations between Hermite polynomials given in Table 7E.1 to show that the only permitted transitions are those for which v′ = v ± 1 and evaluate the integral in these cases.arrow_forwardFind the amplitude of the ground-state vibrations of the CO molecule. What percentage of the bond length is this? Assume the molecule vibrates like a harmonic oscillator.arrow_forward
- Would you expect superconductivity from a "glass" with no or little crystal structure? If not, why not?arrow_forwardWhy do very similar gases, such as HCl and DCl, give bands at quite different vibrational frequencies?arrow_forwardIs it reasonable to expect superconductivity in a "glass," a material with almost no crystalline structure? Why or why not, if that's the case?arrow_forward
- 2(6) Calculate the fundamental vibrational wavenumber (in cm-1) for HI molecule, if its angular vibrational frequency is 4.394×1014 s-1. Calculate the vibrational energy of the molecule in the ground state and the force constant. Assume the mass is the mass of a proton.arrow_forwardThe fundamental frequency is 2230 cm−1 for the molecule 1H127I. If the H atom is replacedwith D (an isotope of H atom with mass 2, i.e. 2H), calculate the fundamental frequency assumingthat the force constant stays the same. Repeat the calculation if the diatomic molecule underconsideration is 1H37Cl (fundamental frequency = 2886 cm−1). Explain your observations.arrow_forwardCheck Your Understanding What does the energy separation between absorption lines in a rotational spectrum of a diatomic molecule tell you?arrow_forward
- The v = 0 to v = 1 vibrational transition of the HI molecule occurs at a frequency of 6.69 × 1013 Hz. The same transition for the NO molecule occurs at a frequency of 5.63 × 1013 Hz. Calculate (a) the effective force constant and (b) the amplitude of vibration for each molecule. (c) Explain why the force constant of the NO molecule is so much larger than that of the HI molecule.arrow_forwardExperimentally it appears that many polyatomic molecules' vibrational degrees of freedom can contribute to some extent to their energy at room temperature. Would you expect that fact to increase or decrease their heat capacity from the value R? Explain.arrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
Modern PhysicsPhysicsISBN:9781111794378Author:Raymond A. Serway, Clement J. Moses, Curt A. MoyerPublisher:Cengage Learning
Glencoe Physics: Principles and Problems, Student...PhysicsISBN:9780078807213Author:Paul W. ZitzewitzPublisher:Glencoe/McGraw-Hill
Physics for Scientists and Engineers with Modern ...PhysicsISBN:9781337553292Author:Raymond A. Serway, John W. JewettPublisher:Cengage Learning
University Physics Volume 3PhysicsISBN:9781938168185Author:William Moebs, Jeff SannyPublisher:OpenStax
Modern Physics
Physics
ISBN:9781111794378
Author:Raymond A. Serway, Clement J. Moses, Curt A. Moyer
Publisher:Cengage Learning
Glencoe Physics: Principles and Problems, Student...
Physics
ISBN:9780078807213
Author:Paul W. Zitzewitz
Publisher:Glencoe/McGraw-Hill
Physics for Scientists and Engineers with Modern ...
Physics
ISBN:9781337553292
Author:Raymond A. Serway, John W. Jewett
Publisher:Cengage Learning
University Physics Volume 3
Physics
ISBN:9781938168185
Author:William Moebs, Jeff Sanny
Publisher:OpenStax