(a)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(b)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(c)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(d)
To determine: The stronger nucleophile among the given pairs of nucleophiles used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(e)
To determine: The stronger nucleophile among the given pairs of nucleophiles used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(f)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(g)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(h)
To determine: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Interpretation: The stronger nucleophile among the given pairs of nucleophiles that is used in the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
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Chapter 6 Solutions
Organic Chemistry (9th Edition)
- From each pair, select the stronger nucleophile. Q.)Cl- or I- in DMSOarrow_forwardSelect which molecule is the better nucleophile in the following pair: a). Br− or Cl− in H2O b). CH3O− or CH3OH in H2O c). HO− or HS− in H2O d). I− or Br− in H2Oarrow_forwardFrom each pair, select the stronger nucleophile. Q.) CH3OCH3 or CH3SCH3arrow_forward
- Which reacts faster in an E2 elimination, cis-or-trans1-bromo-3-tert-butylcyclohexanearrow_forwardWould you expect acetate ion CH3CO2 to be a better nucleophile in an SN2 reaction with an alkyl halide carried out in methanol or in dimethyl sulfoxide?arrow_forwardIdentify the stronger nucleophile in each pair. a.NH3, −NH2 b.CH3NH2, CH3OH c.CH3CO2−, CH3CH2O−arrow_forward
- Identify the stronger nucleophile in each pair. a. NH3,−NH2 b. CH3NH2, CH3OH c. CH3CO2−, CH3CH2O−arrow_forwardHow does changing the alkyl halide from CH3CH2Br to (CH3)2CHBr affect the rate of an E2 reaction?arrow_forwardConsider the following alkyl halides: - may react with NaI to give JKL? - an alkyl iodide that will give SN1 and E1 product? - has the highest boiling point? - most likely to give retention and inversion products in SN1 reaction? - most likely to give rearrangement product in SN1?arrow_forward
- From each pair, select the stronger nucleophile. Q.)Cl2 or I2 in methanolarrow_forwardRank the nucleophiles in each group in order of increasing nucleophilicity.a. -OH, -NH2, H2Ob. -OH, Br-, F- (polar aprotic solvent)c. H2O, -OH, CH3CO2-arrow_forwardWhen drawing organic chemistry mechanisms with NaOCH3, do we automatically dissociate it into Na+ and OCH3-, making it easier to go through SN2 and/or E2 reactions? Does NaOCH3 dissociate, and is this why it is a strong nucleophile?arrow_forward
- EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENTOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning