Concept explainers
(a)
To determine: The member among the given pair of compounds that react faster by the
Interpretation: The member among the given pair of compounds that react faster by the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any
The nucleophilic reaction contains only a substrate as a reactant not a nucleophile which means a unimolecular nucleophilic reaction is termed as
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(b)
To determine: The member among the given pair of compounds that react faster by the
Interpretation: The member among the given pair of compounds that react faster by the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains only a substrate as a reactant not a nucleophile which means a unimolecular nucleophilic reaction is termed as
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(c)
To determine: The member among the given pair of compounds that react faster by the
Interpretation: The member among the given pair of compounds that react faster by the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains only a substrate as a reactant not a nucleophile which means a unimolecular nucleophilic reaction is termed as
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(d)
To determine: The member among the given pair of compounds that react faster by the
Interpretation: The member among the given pair of compounds that react faster by the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains only a substrate as a reactant not a nucleophile which means a unimolecular nucleophilic reaction is termed as
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactant which means a bimolecular nucleophilic reaction is termed as
(e)
To determine: The member among the given pair of compounds that react faster by the
Interpretation: The member among the given pair of compounds that react faster by the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains only a substrate as a reactant not a nucleophile which means a unimolecular nucleophilic reaction is termed as
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
(f)
To determine: The member among the given pair of compounds that react faster by the
Interpretation: The member among the given pair of compounds that react faster by the
Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. There are two types of substitution reaction.
The nucleophilic reaction contains only a substrate as a reactant not a nucleophile which means a unimolecular nucleophilic reaction is termed as
The nucleophilic reaction contains a substrate as well as a nucleophile as the reactants which mean a bimolecular nucleophilic reaction is termed as
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Chapter 6 Solutions
Organic Chemistry (9th Edition)
- How does doubling [RX] affect the rate of an E1 reaction?arrow_forwardOn a single graph, draw the reaction coordinate diagram for the addition of one equivalent of HBr to 2-methyl-1,3-pentadiene and for the addition of one equivalent of HBr to 2-methyl-1,4-pentadiene. Which reaction is faster?arrow_forwardWhy is the mechanism shown in Figure 28 not plausible? * A- The reagent does not have a good leaving group. B- Water is too weak a base for the reaction to occur. C- The structure of the haloalkane prevents the nucleophile from coming close to the alpha carbon atom. D- None of these statements are correct. E- All these statements are correct.arrow_forward
- The SN1 reaction is a two-step reaction, and the first step of this reaction is the formation of a carbocation intermediate. Draw the carbocation intermediates that form from the alkyl chlorides in tubes 8 and 15. 2. Again, use tubes 8 and 15 to answer the following question. In general, the more stable carbocation forms faster. Given this, which carbocation is more stable, or do they have the same stability?arrow_forwardcan you please arrange 1 to 6 alkyl halids from most reactive to least reactive for SN1 and SN2 reaction which alkyl halides will be most reactive and least reactive in the SN2 and SN2 reaction reaction? 1-chlorobutane, 2-chlorobutane, Allyl chloride, 2-chloro-2-methylpropane, 1-chloro-2-methylpropane, 2-bromobutanearrow_forwardWhich reacts faster in an E2 elimination, cis-or-trans1-bromo-3-tert-butylcyclohexanearrow_forward
- Fill in the reagent above/below the arrow of the Gg reactionarrow_forwardChoose the reagent(s) that would be most likely to complete this reactionarrow_forwardFor SN1 Explain the order in which 1o (primary) alkyl halides reacted (fastest to slowest) and explain why. The 1o primary alkyl halides are: (see picture below) 1-chlorobutane 1-bromobutane 1-chloro-2butene benzylchloridearrow_forward
- Say the type of reaction (SN1, SN2, E1 or E2) and detail the mechanism: 4-bromo-2-ethyl-2-pentene + methanolarrow_forwardAssume that 2-chloropropane reacts with CN− in an SN2 reaction. Use the JSME editor () to draw the structure of the substitution product of the reaction. The guide on how to draw your structure can be found here Important Note: When drawing the structures in the JME editor please adhere to the following formats: 1. If the nucleophile is OH−, DO NOT manually add the "H" to the final product 2. If the nucleophile is CN−, be sure to include the appropriate bonding between the C and N in the final productarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning