Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 7.6, Problem 4P
- a. Predict the relative bond lengths of the three carbon–oxygen bonds in the carbonate ion (
- b. What would you expect the charge to be on each oxygen?
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Chapter 7 Solutions
Essential Organic Chemistry, Global Edition
Ch. 7.4 - Prob. 1PCh. 7.5 - Prob. 3PCh. 7.6 - a. Predict the relative bond lengths of the three...Ch. 7.6 - Prob. 5PCh. 7.6 - Prob. 6PCh. 7.7 - Prob. 7PCh. 7.7 - Prob. 8PCh. 7.7 - Prob. 9PCh. 7.7 - Prob. 10PCh. 7.8 - Which member of each pair is the stronger acid? a....
Ch. 7.8 - Which member of each pair is the stronger base? a....Ch. 7.9 - Prob. 13PCh. 7.9 - Which species in each of the following pairs is...Ch. 7.9 - Prob. 16PCh. 7.11 - Prob. 18PCh. 7.11 - Prob. 19PCh. 7.11 - Prob. 20PCh. 7.11 - Prob. 21PCh. 7.11 - Prob. 22PCh. 7.12 - Prob. 23PCh. 7.12 - Prob. 24PCh. 7.15 - Prob. 25PCh. 7.15 - Which of the following are aromatic? A...Ch. 7.17 - Prob. 29PCh. 7.17 - Prob. 30PCh. 7 - Prob. 31PCh. 7 - Prob. 32PCh. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - Which of the compounds in each of the following...Ch. 7 - Prob. 39PCh. 7 - Prob. 40PCh. 7 - Prob. 41PCh. 7 - Prob. 42PCh. 7 - Prob. 43PCh. 7 - Prob. 44PCh. 7 - Prob. 45PCh. 7 - Which species in each of the pairs in Problem 45...Ch. 7 - Rank the following anions in order from most basic...Ch. 7 - a. Which oxygen atom has the greater electron...Ch. 7 - Prob. 49PCh. 7 - Which compound is the strongest base?Ch. 7 - Prob. 51PCh. 7 - Prob. 52PCh. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - a. Which dienophile in each pair is more reactive...Ch. 7 - Prob. 57PCh. 7 - Draw the product of each of the following...Ch. 7 - Prob. 59PCh. 7 - Prob. 60PCh. 7 - Prob. 61PCh. 7 - a. In what direction is the dipole moment in...Ch. 7 - Propose a mechanism for each of the following...Ch. 7 - Prob. 1PCh. 7 - Prob. 2PCh. 7 - Prob. 3PCh. 7 - Prob. 4PCh. 7 - Prob. 5PCh. 7 - Prob. 6PCh. 7 - Prob. 7PCh. 7 - Prob. 8PCh. 7 - Prob. 9PCh. 7 - Prob. 10PCh. 7 - Prob. 11PCh. 7 - Prob. 12P
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- Use the observed bond lengths to answer each question. (a) Why is bond [1] longer than bond [2] (143 pm versus 136 pm)? (b) Why are bonds [3] and [4] equal in length (127 pm), and shorter than bond [2]?arrow_forwardA. What is the electron-pair geometry for P in PO(OH)3?_____________ There are _____lone pair(s) around the central atom, so the geometry of PO(OH)3 is ________________. B. What is the electron-pair geometry for Se in SeOF2?_____________ There are __________lone pair(s) around the central atom, so the geometry of SeOF2 is _________________.arrow_forwardLight of appropriate wavelength can break chemical bonds. Light having λ < 240 nm can dissociate gaseous O2. It requires light with λ < 819 nm to dissociate gaseous H2O2 to 2 OH. Assume that all of the photon energy is used solely for these dissociations. (a) Calculate the energy required to dissociate (i) O2 and (ii) H2O2. (b) Consider the results of part (a). How well do they correlate with the Lewis structures of O2 and H2O2? Explain your answer.arrow_forward
- Explain why CF4 and Xef4 are nonpolar compounds (have no net dipole moments) while SF4 is polar (has a net dipo le moment). Is CO2 polar? What about COS?arrow_forwardThe compound oxygen difluoride is quite reactive, giving oxygen and HF when treated with water: OF2(g) + H2O(g) O2(g) + 2 HF(g) rH = 318 kl/mol-rxn Using bond dissociation enthalpies, calculate the bond dissociation enthalpy of the OF bond in OF2.arrow_forwardWhat is the connection between bond order, bond length, and bond energy? Use ethane (C2H6), ethylene (C2H4), and acetylene (C2H2) as examples.arrow_forward
- Compare the nitrogen-nitrogen bond in hydrazine, H2NNH2, with that in laughing gas, N2O. In which molecule is the nitrogen-nitrogen bond shorter? In which is the bond stronger?arrow_forwardMolecules in space: (a) In addition to molecules such as CO, HCl, H2O, and NH3, glycolaldehyde has been detected in outer space. Is the molecule polar? (b) Where do the positive and negative charges lie in the molecule? (c) One molecule found in the 1995 Hale-Bopp comet is HC3N. Suggest a structure for this molecule.arrow_forwardAcrylamide, H2C=CHCONH2, is a known neurotoxin and possible carcinogen. It was a shock to all consumers of potato chips and french fries a few years ago when it was found to occur in those products. (a) Sketch the molecular structure of acrylamide and identify all bond angles. (b) Indicate which carbon-carbon bond is the stronger of the two. (c) Is the molecule polar or nonpolar? (d) The amount of acrylamide found in potato chips is 1.7 mg/kg. If a serving of potato chips is 28 g, how many moles of acrylamide are you consuming?arrow_forward
- Following is a structural formula of benzene, C6H6, which we study in Chapter 21. (a) Using VSEPR, predict each HCC and CCC bond angle in benzene. (b) State the hybridization of each carbon in benzene. (c) Predict the shape of a benzene molecule. (d) Draw important resonance contributing structures.arrow_forwardCompare the carbon-oxygen bond lengths in the formate ion (HCO2), in methanol (CH3OH), and in the carbonate ion (CO32). In which species is the carbon-oxygen bond predicted to be longest? In which is it predicted to be shortest? Explain briefly.arrow_forwardThe chemistry of the nitrite ion and HNO2: (a) Two resonance structures are possible for NO2. Draw these structures, and then find the formal charge on each atom in each resonance structure. (b) In forming the acid HNO2 an H+ ion attaches to the O atom and not the N atom of NO2. Explain why you would predict this result. (c) Two resonance structures are possible for HNO2. Draw these structures, and then find the formal charge on each atom in each resonance structure. Is either of these structures strongly preferred over the other?arrow_forward
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