a) Interpretation: The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene is to be given. Concept introduction: The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in an alkene . The resulting product has the hydroxyl group on the less highly substituted carbon. To give: The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

Question

Propose the structures for hydrocarbons (and give the organic reaction) that give the following products on oxidative cleavage with KMnO 4 or O 3 .

Answer 1

Question

Chapter 8.5, Problem 9P

Interpretation Introduction

a)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in an alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of the compound is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of the compound shown.

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Propose the structures for hydrocarbons (and give the organic reaction) that give the following products on oxidative cleavage with KMnO 4 or O 3 .

Propose the structures for hydrocarbons (and give the organic reaction) that give the following products on oxidative cleavage with KMnO 4 or O 3 . EXPLAIN

What products would you expect from reaction of the following alkenes with NBS? If more than one product is formed, show the structures of all.

Answer 2

Question

Chapter 8.5, Problem 9P

Interpretation Introduction

a)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in an alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of the compound is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of the compound shown.

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Answer 3

Question

Chapter 8.5, Problem 9P

Interpretation Introduction

a)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in an alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of the compound is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of the compound shown.

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Answer 4

Question

Chapter 8.5, Problem 9P

Interpretation Introduction

a)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in an alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of the compound is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of the compound shown.

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Answer 5

Chapter 8.5, Problem 9P

Interpretation Introduction

a)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in an alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

Interpretation Introduction

b)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of the compound is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of the compound shown.

Answer 6

Chapter 8.5, Problem 9P

Interpretation Introduction

a)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in an alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

Answer 7

Chapter 8.5, Problem 9P

Interpretation Introduction

a)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in an alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

Answer 8

Interpretation Introduction

b)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of the compound is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of the compound shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

The structure of the product obtained by the hydroboration-oxidation of the compound is to be given.

Concept introduction:

The hydroboration reaction takes place with syn stereochemistry and results in a non-Markovnikov addition of water to the double bond in the alkene. The resulting product has the hydroxyl group on the less highly substituted carbon.

To give:

The structure of the product obtained by the hydroboration-oxidation of the compound shown.

Answer 10

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Ch. 8.1 - Prob. 1P Ch. 8.1 - How many alkene products, including E,Z isomers,...Ch. 8.2 - Prob. 3P Ch. 8.2 - Addition of HCl to 1, 2-dimethylcyclohexene yields...Ch. 8.3 - Prob. 5P Ch. 8.3 - Prob. 6P Ch. 8.4 - Prob. 7P Ch. 8.4 - From what alkenes might the following alcohols...Ch. 8.5 - Prob. 9P Ch. 8.5 - What alkenes might be used to prepare the...

Solution Summary: The author explains the structure of the product obtained by the hydroboration-oxidation of 2-methyl-2-pentene.

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