EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 9.2, Problem 20E

(a)

Interpretation Introduction

Interpretation: Considering the mono-chlorination of heptane using ABCN (1) and sulfuryl chloride, the structures and names of the possible mono-chlorination products that could be produced, needs to be written.

Concept Introduction: Heptane, being a main component of gasoline, has a chemical formula of C7H16 , and is a straight chain alkane.

(b)

Interpretation Introduction

Interpretation: Considering the mono-chlorination of heptane using ABCN (1) and sulfuryl chloride, the center(s) of chirality, if any, that are present in the isomers derived in Part a, needs to be circled.

Concept Introduction: When an atom is bonded to four other groups, such that the group is held in space with this atom becoming the stereocenter, and the mirror image of the bond is non-superimposable, then this atom is called chiral center or chirality center.

(c)

Interpretation Introduction

Interpretation: The structure of each sample needs to be determined using the 1H and 13C NMR spectroscopic data.

Concept Introduction: Stereoscopic imaging is used to view and understand three dimensional images and record the same, such that the viewer will also be able to see and understand the depth of the image.

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