EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 9.2, Problem 18E
Interpretation Introduction

Interpretation: Thermodynamically favored geometry of the given azo compounds needs to be drawn.

Concept introduction:The presence of double bond between two N atoms as RN=NR where R can be alkyl, aryl, cycloalkyl, or cycloarylgroups results in the formation of azo compounds. The group N=N is said to be azo group.

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Please write down the resulting products. How can I know which of the two substituents already present is more strongly conducting in the case of double-substituted benzene? Is generally ortho preferred to para? In the example of OH and NH2 both otho,para conducting. So are there three possible products?
Thoroughly describe what is meant when a compound is considered aromatic. In your answer, provide examples and be sure to discuss how Huckel's Rule applies, and what it means to be anti-aromatic versus non-aromatic. When providing specific examples to demonstrate the requirements that you list, describe the delocalized pi electrons and sp2 hybridization. Lastly, why is benzene so special compared to alkenes like cyclohexene....both are 6-carbon atom cycles so are they chemically similar or not really similar at all?
I am slightly confused on the naming of ethers. How come for chloromethoxymethane, it is not methoxychloride? Isn't chloride more complex than the alkyl group, so it should be placed at the root? Or is it not placed at the root because chloride is not an alkyl group at all?
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