The characteristics of a molecule to act as a good initiator needs to be explained. Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction .

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Answer 1

Question

Chapter 9.2, Problem 17E

(a)

Interpretation Introduction

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

(b)

Interpretation Introduction

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

(c)

Interpretation Introduction

Interpretation: For the given radical initiators, the bond homolysis needs to be shown using the curved arrow when they are heated or irradiated.

Benzoyl peroxide 2,2'-Azobis [2−methylproanenitrile]

Concept Introduction: In the bond dissociation, the movement of electrons always takes place from negative to positive charge. Thus, the direction of the curved arrow is also from negative to the positive charge.

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Answer 2

Question

Chapter 9.2, Problem 17E

(a)

Interpretation Introduction

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

(b)

Interpretation Introduction

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

(c)

Interpretation Introduction

Interpretation: For the given radical initiators, the bond homolysis needs to be shown using the curved arrow when they are heated or irradiated.

Benzoyl peroxide 2,2'-Azobis [2−methylproanenitrile]

Concept Introduction: In the bond dissociation, the movement of electrons always takes place from negative to positive charge. Thus, the direction of the curved arrow is also from negative to the positive charge.

Expert Solution & Answer

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Answer 3

Question

Chapter 9.2, Problem 17E

(a)

Interpretation Introduction

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

(b)

Interpretation Introduction

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

(c)

Interpretation Introduction

Interpretation: For the given radical initiators, the bond homolysis needs to be shown using the curved arrow when they are heated or irradiated.

Benzoyl peroxide 2,2'-Azobis [2−methylproanenitrile]

Concept Introduction: In the bond dissociation, the movement of electrons always takes place from negative to positive charge. Thus, the direction of the curved arrow is also from negative to the positive charge.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 9.2, Problem 17E

(a)

Interpretation Introduction

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

(b)

Interpretation Introduction

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

(c)

Interpretation Introduction

Interpretation: For the given radical initiators, the bond homolysis needs to be shown using the curved arrow when they are heated or irradiated.

Benzoyl peroxide 2,2'-Azobis [2−methylproanenitrile]

Concept Introduction: In the bond dissociation, the movement of electrons always takes place from negative to positive charge. Thus, the direction of the curved arrow is also from negative to the positive charge.

Expert Solution & Answer

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Answer 5

Chapter 9.2, Problem 17E

(a)

Interpretation Introduction

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

(b)

Interpretation Introduction

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

(c)

Interpretation Introduction

Interpretation: For the given radical initiators, the bond homolysis needs to be shown using the curved arrow when they are heated or irradiated.

Benzoyl peroxide 2,2'-Azobis [2−methylproanenitrile]

Concept Introduction: In the bond dissociation, the movement of electrons always takes place from negative to positive charge. Thus, the direction of the curved arrow is also from negative to the positive charge.

Answer 6

Chapter 9.2, Problem 17E

(a)

Interpretation Introduction

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

Answer 7

Chapter 9.2, Problem 17E

(a)

Interpretation Introduction

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

Answer 10

(c)

Interpretation Introduction

Interpretation: For the given radical initiators, the bond homolysis needs to be shown using the curved arrow when they are heated or irradiated.

Benzoyl peroxide 2,2'-Azobis [2−methylproanenitrile]

Concept Introduction: In the bond dissociation, the movement of electrons always takes place from negative to positive charge. Thus, the direction of the curved arrow is also from negative to the positive charge.

Answer 11

(c)

Interpretation Introduction

Interpretation: For the given radical initiators, the bond homolysis needs to be shown using the curved arrow when they are heated or irradiated.

Benzoyl peroxide 2,2'-Azobis [2−methylproanenitrile]

Concept Introduction: In the bond dissociation, the movement of electrons always takes place from negative to positive charge. Thus, the direction of the curved arrow is also from negative to the positive charge.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 9.2 - Prob. 1E Ch. 9.2 - Prob. 2E Ch. 9.2 - Prob. 3E Ch. 9.2 - Prob. 4E Ch. 9.2 - Prob. 5E Ch. 9.2 - Prob. 6E Ch. 9.2 - Prob. 7E Ch. 9.2 - Prob. 8E Ch. 9.2 - Prob. 9E Ch. 9.2 - Prob. 10E

The characteristics of a molecule to act as a good initiator needs to be explained. Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction .

Solution Summary: The author explains the characteristics of a good initiator molecule and the reason for its unnecessary use.

Concept explainers

Videos

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

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Chapter 9 Solutions

The characteristics of a molecule to act as a good initiator needs to be explained. Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction .

Solution Summary: The author explains the characteristics of a good initiator molecule and the reason for its unnecessary use.

Concept explainers

Videos

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained. Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained. Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.

Want to see the full answer?

Chapter 9 Solutions

Interpretation: The characteristics of a molecule to act as a good initiator needs to be explained.

Concept Introduction: The initiator is used in the initiation step and it is used to start a chemical reaction.

Interpretation: The reason for the unnecessary use of stoichiometric amount of the initiator needs to be explained.

Concept Introduction: Only a catalytic amount of initiator is required for initiation of reaction, further to which there is no role for the initiator in the chemical reaction.