Bichem Jessica quiz 1

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The University of Oklahoma *

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3653

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Chemistry

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9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 1/18 Week 1 Practice Quiz F22 Started: Sep 20 at 7:52pm Quiz Instructions 1 pts Question 1 The statement is not true The statement is true Many textbooks use J and kJ, but many biochemists are stubborn and use cal and kcal; accordingly, to convert between J and cal, the following conversion factor (to four significant figures) is used: 1 cal = 4.184 J. 1 pts Question 2 The statement is not true The statement is true The value of the gas constant (in terms of cal/K mol) is, to four significant figures, 1.987 cal/K mol. 1 pts Question 3 The statement is not true Nearly all thermodynamics problems require the Absolute (or Kelvin) scale for temperature; accordingly, to convert from °C to K, the following conversion factor (to three significant figures) is used: K = °C + 273.
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 2/18 The statement is true 1 pts Question 4 nonspontaneous only endothermic and spontaneous exothermic and spontaneous exothermic only exothermic and nonspontaneous endothermic and nonspontaneous endothermic only spontaneous only A certain reaction at 25 °C has ΔH = +3.54 kJ/mol and ΔS = 129 J/mol K. Which of the following is an accurate description of this reaction? 1 pts Question 5 exothermic only nonspontaneous only spontaneous only endothermic and nonspontaneous endothermic only exothermic and spontaneous A certain reaction at 25 °C has ΔH = −3.54 kJ/mol and ΔS = −29 J/mol K. Which of the following is an accurate description of this reaction?
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 3/18 endothermic and spontaneous exothermic and nonspontaneous 1 pts Question 6 The reaction will be spontaneous (i.e., thermodynamically favorable) at temperatures less than 25 °C. The reaction will be spontaneous (i.e., thermodynamically favorable) at any temperature. The reaction will be spontaneous (i.e., thermodynamically favorable) at temperatures greater than 25 °C. The reaction will not be spontaneous (i.e., thermodynamically favorable) at any temperature. None of the other choices is true. A reaction carried out at 25 °C is noted to have ΔH = +32.5 kJ/mol and ΔS = 109 J/mol K. Which of the following statements accurately describes the above reaction? 1 pts Question 7 The statement is true The statement is not true If 4.184 J of thermal energy are added to 1 g of water, then the temperature of the water will increase 1 degree Celsius. 1 pts Question 8
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9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 4/18 8.88 5.12 8.18 3.06 4.34 What is the pH of a 0.10 M solution of a weak acid (HA) that has a p K of 5.12? a 1 pts Question 9 2.5 3.5 1.5 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 5.5 6.5 4.5 A 0.2 M solution of a weak acid HA dissociates such that 99.6% of the weak acid remains intact (i.e., remains as HA). What is the p K of the weak acid? a 1 pts Question 10 A 0.2 M solution of a weak acid HA dissociates such that 99.4% of the weak acid remains intact (i.e., remains as HA). What is the pH of the solution?
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 5/18 3.5 −0.03 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 2.9 2.2 0.7 1.9 1 pts Question 11 8.50 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 5.50 11.25 9.05 4.95 2.75 A 0.2 M solution of a weak base A is made. To a limited extent, the A reacts with H O to form some OH and some of the corresponding weak acid HA. If the weak acid has a p K of 9.2, what will be the pH of the solution? Hint: recall how p K , p K , and p K are related. - - 2 a a b W 1 pts Question 12
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 6/18 10.9 11.9 5.5 2.1 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 3.1 8.5 A 0.2 M solution of a weak base A reacts with H O such that at equilibrium 99.6% of the compound remains in the A form. Given this information, what is the pH of this solution? - 2 1 pts Question 13 7.8 6.2 10.9 3.1 5.5 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 8.5 A 0.2 M solution of a weak base A reacts with H O such that at equilibrium 99.6% of the compound remains in the A form. Given this information, what is the p K of the conjugate acid HA? - 2 a
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9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 7/18 1 pts Question 14 The statement is true The statement is false Propionic acid (CH CH COOH) has a p K of 4.87 and thus a 0.1 M solution of propionic acid/sodium propionate at pH 5.87 would be an effective buffer against the addition of 0.1 M NaOH because pH 5.87 is within the “±1 of the p K ” buffering range. 3 2 a a 1 pts Question 15 The statement is false The statement is true Propionic acid (CH CH COOH) has a p K of 4.87 and thus a 0.1 M solution of propionic acid/sodium propionate at pH 5.87 would be an effective buffer against the addition of 0.1 M HCl. 3 2 a 1 pts Question 16 The statement is false The statement is true Propylaminium ion (CH CH CH NH ) has a p K of 10.71 and thus a 0.1 M solution of propylaminium ion/propylamine at pH 11.71 would be an effective buffer against the addition of 0.1 M NaOH because pH 11.71 is within the “±1 of the p K ” buffering range. 3 2 2 3 + a a
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 8/18 1 pts Question 17 The statement is true The statement is false Propylaminium ion (CH CH CH NH ) has a p K of 10.71 and thus a 0.1 M solution of propylaminium ion/propylamine at pH 11.71 would be an effective buffer against the addition of 0.1 M HCl. 3 2 2 3 + a 1 pts Question 18 2.15 9.78 7.20 12.35 4.68 You have 100. mL of a 0.10 M solution of phosphoric acid (H PO ). The p K s of this polyprotic acid are 2.15, 7.20, and 12.35. What will be the pH of this solution when 50.0 mL of 0.10 M KOH is added with stirring such that equilibrium is attained? 3 4 a 1 pts Question 19 12.35 2.15 You have 100. mL of a 0.10 M solution of phosphoric acid (H PO ). The p K s of this polyprotic acid are 2.15, 7.20, and 12.35. What will be the pH of this solution when 100.0 mL of 0.10 M KOH is added with stirring such that equilibrium is attained? 3 4 a
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 9/18 4.68 7.20 9.78 1 pts Question 20 essentially all H PO essentially all HPO none of the other answers is correct essentially all H PO essentially all PO 50:50 H PO and HPO 50:50 HPO and PO 50:50 H PO and H PO Consider the titration curve of phosphate (PO ) ion. When 1.5 equivalents of H have been added to a solution of phosphate ion, what species predominates? 4 3− + 2 4 4 2− 3 4 4 3− 2 4 4 2− 4 2− 4 3− 3 4 2 4 1 pts Question 21 The molecule shown below is S -adenosylmethionine, an important cofactor that is involved in methyl group transfers. The –NH group of S -adenosylmethionine is a/an _________________ functional group. 2
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9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 10/18 alkyl halide ketone amine (amino) alcohol acyl halide (acid halide) alkane aldehyde amide nitrile ester ether carboxylic acid 1 pts Question 22 The molecule shown below is S -adenosylmethionine, an important cofactor that is involved in methyl group transfers. The right-most carbon of S -adenosylmethionine (as depicted below) is part of a/an _________________ functional group.
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 11/18 amide alcohol aldehyde carboxylic acid (ionized form) amine (amino) alkane acyl halide (acid halide) ether ketone alkyl halide nitrile ester 1 pts Question 23 The molecule shown below is the dipeptide alanyltyrosine. The dashed box indicates what type of functional group?
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 12/18 aldehyde ether ketone amine (amino) alkane nitrile carboxylic acid amide alkyl halide alcohol ester acyl halide (acid halide) 1 pts Question 24 The molecule shown below is trimyristin, a type of triacylglycerol that is abundant in nutmeg. The dashed boxes indicate what type functional group?
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9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 13/18 thiol amide amine (amino) nitrile alkyl halide ether aldehyde ester carboxylic acid alkane alcohol acyl halide (acid halide) ketone 1 pts Question 25 ether alkane The molecule shown below is sucralose, which goes by the trade name Splenda. Sucralose is used as an artificial sweetener. The chlorines in sucralose are each part of what type of functional group?
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 14/18 amide alkyl halide carboxylic acid aldehyde ketone alcohol thiol nitrile acyl halide (acid halide) amine (amino) ester 1 pts Question 26 ethylene glycol glycerol choline propanol trihydroxy propane The structure shown below is that of _____________.
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 15/18 1 pts Question 27 trihydroxy propane propanol ethanolamine choline glycerol ethylene glycol inorganic phosphate The structure shown below is that of _____________. 1 pts Question 28 ethanolamine glycerol inorganic phosphate choline trihydroxy propane ethylene glycol The structure shown below is that of _____________.
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9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 16/18 propanol 1 pts Question 29 ethanolamine glycerol choline ethylene glycol propanol inorganic phosphate trihydroxy propane The structure shown below is that of _____________. 1 pts Question 30 The compound shown below is called acetyl-coenzyme A (acetyl-CoA). Acetyl-CoA is an important cofactor that you will meet when you study metabolism. The right-most carbon of this compound (as depicted below) is part of what type of functional group?
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 17/18 nitrile ester thioester alcohol thiol amide acyl halide (acid halide) aldehyde carboxylic acid amine (amino) ketone alkane alkyl halide ether 1 pts Question 31 A 0.20 M solution of a weak acid HA dissociates such that 99.4% of the weak acid remains intact (i.e., remains as HA). To the nearest hundredths, what is the pH of the solution? 1 pts Question 32
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 18/18 Quiz saved at 7:52pm A 0.19 M solution of a weak acid HA dissociates such that 99.2% of the weak acid remains intact (i.e., remains as HA). What is the p K of the weak acid? Enter your answer to the nearest hundredths. a 1 pts Question 33 If the concentration of glucose inside an E. coli cell is 5.2 mM, how many glucose molecules are in the cell? Assume an E. coli cell to be a cylinder 2.0 micrometers long and 0.8 micrometers in diameter. Enter your answer to the nearest ones (e.g., 508.9 would be entered as 509). Hint: a concentration given in mM means mmol/L; however, we are given the length and diameter of an E. coli cell in m. If we can convert the volume in terms of m to cm , then we can use the relationship that 1 cm = 1 mL, and then the relationship that 1 mL = 0.001 L. Be careful, because volume conversions can be tricky. Consider a cube that is 1 cm in volume. What would be the volume of this cube in m ? To answer this, consider the relationship between cm and m, and recall that there are 10 m per cm. 3 3 3 3 3 4 Submit Quiz
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