Bichem Jessica quiz 1
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The University of Oklahoma *
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Course
3653
Subject
Chemistry
Date
Apr 3, 2024
Type
Pages
18
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Week 1 Practice Quiz F22
Started: Sep 20 at 7:52pm
Quiz Instructions
1 pts
Question 1
The statement is not true
The statement is true
Many textbooks use J and kJ, but many biochemists are stubborn and use cal and
kcal; accordingly, to convert between J and cal, the following conversion factor (to
four significant figures) is used: 1 cal = 4.184 J.
1 pts
Question 2
The statement is not true
The statement is true
The value of the gas constant (in terms of cal/K
⋅
mol) is, to four significant figures,
1.987 cal/K
⋅
mol.
1 pts
Question 3
The statement is not true
Nearly all thermodynamics problems require the Absolute (or Kelvin) scale for
temperature; accordingly, to convert from °C to K, the following conversion factor (to
three significant figures) is used: K = °C + 273.
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The statement is true
1 pts
Question 4
nonspontaneous only
endothermic and spontaneous
exothermic and spontaneous
exothermic only
exothermic and nonspontaneous
endothermic and nonspontaneous
endothermic only
spontaneous only
A certain reaction at 25 °C has ΔH = +3.54 kJ/mol and ΔS = 129 J/mol
⋅
K. Which of
the following is an accurate description of this reaction?
1 pts
Question 5
exothermic only
nonspontaneous only
spontaneous only
endothermic and nonspontaneous
endothermic only
exothermic and spontaneous
A certain reaction at 25 °C has ΔH = −3.54 kJ/mol and ΔS = −29 J/mol
⋅
K. Which of
the following is an accurate description of this reaction?
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endothermic and spontaneous
exothermic and nonspontaneous
1 pts
Question 6
The reaction will be spontaneous (i.e., thermodynamically favorable) at temperatures less
than 25 °C.
The reaction will be spontaneous (i.e., thermodynamically favorable) at any temperature.
The reaction will be spontaneous (i.e., thermodynamically favorable) at temperatures greater
than 25 °C.
The reaction will not be spontaneous (i.e., thermodynamically favorable) at any temperature.
None of the other choices is true.
A reaction carried out at 25 °C is noted to have ΔH = +32.5 kJ/mol and ΔS = 109
J/mol
⋅
K. Which of the following statements accurately describes the above reaction?
1 pts
Question 7
The statement is true
The statement is not true
If 4.184 J of thermal energy are added to 1 g of water, then the temperature of the
water will increase 1 degree Celsius.
1 pts
Question 8
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Quiz: Week 1 Practice Quiz F22
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4/18
8.88
5.12
8.18
3.06
4.34
What is the pH of a 0.10 M solution of a weak acid (HA) that has a p
K
of 5.12?
a
1 pts
Question 9
2.5
3.5
1.5
none of the other choices is reasonably close (i.e., within ±5% of the correct answer)
5.5
6.5
4.5
A 0.2 M solution of a weak acid HA dissociates such that 99.6% of the weak acid
remains intact (i.e., remains as HA). What is the p
K
of the weak acid?
a
1 pts
Question 10
A 0.2 M solution of a weak acid HA dissociates such that 99.4% of the weak acid
remains intact (i.e., remains as HA). What is the pH of the solution?
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3.5
−0.03
none of the other choices is reasonably close (i.e., within ±5% of the correct answer)
2.9
2.2
0.7
1.9
1 pts
Question 11
8.50
none of the other choices is reasonably close (i.e., within ±5% of the correct answer)
5.50
11.25
9.05
4.95
2.75
A 0.2 M solution of a weak base A
is made. To a limited extent, the A
reacts with
H
O to form some OH
and some of the corresponding weak acid HA. If the weak
acid has a p
K
of 9.2, what will be the pH of the solution? Hint: recall how p
K
, p
K
,
and p
K
are related.
- - 2
− a
a
b
W 1 pts
Question 12
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10.9
11.9
5.5
2.1
none of the other choices is reasonably close (i.e., within ±5% of the correct answer)
3.1
8.5
A 0.2 M solution of a weak base A reacts with H
O such that at equilibrium 99.6% of
the compound remains in the A
form. Given this information, what is the pH of this
solution?
-
2
−
1 pts
Question 13
7.8
6.2
10.9
3.1
5.5
none of the other choices is reasonably close (i.e., within ±5% of the correct answer)
8.5
A 0.2 M solution of a weak base A reacts with H
O such that at equilibrium 99.6% of
the compound remains in the A
form. Given this information, what is the p
K
of the
conjugate acid HA?
-
2
−
a
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1 pts
Question 14
The statement is true
The statement is false
Propionic acid (CH
CH
COOH) has a p
K
of 4.87 and thus a 0.1 M solution of
propionic acid/sodium propionate at pH 5.87 would be an effective buffer against the
addition of 0.1 M NaOH because pH 5.87 is within the “±1 of the p
K
” buffering range.
3
2
a
a
1 pts
Question 15
The statement is false
The statement is true
Propionic acid (CH
CH
COOH) has a p
K
of 4.87 and thus a 0.1 M solution of
propionic acid/sodium propionate at pH 5.87 would be an effective buffer against the
addition of 0.1 M HCl.
3
2
a
1 pts
Question 16
The statement is false
The statement is true
Propylaminium ion (CH
CH
CH
NH
) has a p
K
of 10.71 and thus a 0.1 M solution
of propylaminium ion/propylamine at pH 11.71 would be an effective buffer against the
addition of 0.1 M NaOH because pH 11.71 is within the “±1 of the p
K
” buffering
range.
3
2
2
3
+
a
a
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1 pts
Question 17
The statement is true
The statement is false
Propylaminium ion (CH
CH
CH
NH
) has a p
K
of 10.71 and thus a 0.1 M solution
of propylaminium ion/propylamine at pH 11.71 would be an effective buffer against the
addition of 0.1 M HCl.
3
2
2
3
+
a
1 pts
Question 18
2.15
9.78
7.20
12.35
4.68
You have 100. mL of a 0.10 M solution of phosphoric acid (H
PO
). The p
K
s of this
polyprotic acid are 2.15, 7.20, and 12.35. What will be the pH of this solution when
50.0 mL of 0.10 M KOH is added with stirring such that equilibrium is attained?
3
4
a
1 pts
Question 19
12.35
2.15
You have 100. mL of a 0.10 M solution of phosphoric acid (H
PO
). The p
K
s of this
polyprotic acid are 2.15, 7.20, and 12.35. What will be the pH of this solution when
100.0 mL of 0.10 M KOH is added with stirring such that equilibrium is attained?
3
4
a
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4.68
7.20
9.78
1 pts
Question 20
essentially all H
PO
essentially all HPO
none of the other answers is correct
essentially all H
PO
essentially all PO
50:50 H
PO
and HPO
50:50 HPO
and PO
50:50 H
PO
and H
PO
Consider the titration curve of phosphate (PO
) ion. When 1.5 equivalents of H
have been added to a solution of phosphate ion, what species predominates?
4
3−
+
2
4
−
4
2−
3
4
4
3−
2
4
−
4
2−
4
2−
4
3−
3
4
2
4
−
1 pts
Question 21
The molecule shown below is S
-adenosylmethionine, an important cofactor that is
involved in methyl group transfers. The –NH
group of S
-adenosylmethionine is a/an
_________________ functional group. 2
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alkyl halide
ketone
amine (amino)
alcohol
acyl halide (acid halide)
alkane
aldehyde
amide
nitrile
ester
ether
carboxylic acid
1 pts
Question 22
The molecule shown below is S
-adenosylmethionine, an important cofactor that is
involved in methyl group transfers. The right-most carbon of S
-adenosylmethionine
(as depicted below) is part of a/an _________________ functional group.
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amide
alcohol
aldehyde
carboxylic acid (ionized form)
amine (amino)
alkane
acyl halide (acid halide)
ether
ketone
alkyl halide
nitrile
ester
1 pts
Question 23
The molecule shown below is the dipeptide alanyltyrosine. The dashed box indicates
what type of functional group?
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aldehyde
ether
ketone
amine (amino)
alkane
nitrile
carboxylic acid
amide
alkyl halide
alcohol
ester
acyl halide (acid halide)
1 pts
Question 24
The molecule shown below is trimyristin, a type of triacylglycerol that is abundant in
nutmeg. The dashed boxes indicate what type functional group?
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thiol
amide
amine (amino)
nitrile
alkyl halide
ether
aldehyde
ester
carboxylic acid
alkane
alcohol
acyl halide (acid halide)
ketone
1 pts
Question 25
ether
alkane
The molecule shown below is sucralose, which goes by the trade name Splenda.
Sucralose is used as an artificial sweetener. The chlorines in sucralose are each part
of what type of functional group?
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amide
alkyl halide
carboxylic acid
aldehyde
ketone
alcohol
thiol
nitrile
acyl halide (acid halide)
amine (amino)
ester
1 pts
Question 26
ethylene glycol
glycerol
choline
propanol
trihydroxy propane
The structure shown below is that of _____________.
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1 pts
Question 27
trihydroxy propane
propanol
ethanolamine
choline
glycerol
ethylene glycol
inorganic phosphate
The structure shown below is that of _____________. 1 pts
Question 28
ethanolamine
glycerol
inorganic phosphate
choline
trihydroxy propane
ethylene glycol
The structure shown below is that of _____________.
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propanol
1 pts
Question 29
ethanolamine
glycerol
choline
ethylene glycol
propanol
inorganic phosphate
trihydroxy propane
The structure shown below is that of _____________. 1 pts
Question 30
The compound shown below is called acetyl-coenzyme A (acetyl-CoA). Acetyl-CoA is
an important cofactor that you will meet when you study metabolism. The right-most
carbon of this compound (as depicted below) is part of what type of functional group?
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nitrile
ester
thioester
alcohol
thiol
amide
acyl halide (acid halide)
aldehyde
carboxylic acid
amine (amino)
ketone
alkane
alkyl halide
ether
1 pts
Question 31
A 0.20 M solution of a weak acid HA dissociates such that 99.4% of the weak acid
remains intact (i.e., remains as HA). To the nearest hundredths, what is the pH of the
solution? 1 pts
Question 32
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Quiz saved at 7:52pm
A 0.19 M solution of a weak acid HA dissociates such that 99.2% of the weak acid
remains intact (i.e., remains as HA). What is the p
K
of the weak acid? Enter your
answer to the nearest hundredths. a
1 pts
Question 33
If the concentration of glucose inside an E. coli cell is 5.2 mM, how many glucose
molecules are in the cell? Assume an E. coli cell to be a cylinder 2.0 micrometers
long and 0.8 micrometers in diameter. Enter your answer to the nearest ones (e.g.,
508.9 would be entered as 509). Hint: a concentration given in mM means mmol/L;
however, we are given the length and diameter of an E. coli cell in m. If we can
convert the volume in terms of m
to cm
, then we can use the relationship that 1
cm
= 1 mL, and then the relationship that 1 mL = 0.001 L. Be careful, because
volume conversions can be tricky. Consider a cube that is 1 cm
in volume. What
would be the volume of this cube in m
? To answer this, consider the relationship
between cm and m, and recall that there are 10
m per cm.
3
3
3
3
3
4
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