Bichem Jessica quiz 1

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The University of Oklahoma *

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3653

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Chemistry

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Apr 3, 2024

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pdf

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18

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9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 1/18 Week 1 Practice Quiz F22 Started: Sep 20 at 7:52pm Quiz Instructions 1 pts Question 1 The statement is not true The statement is true Many textbooks use J and kJ, but many biochemists are stubborn and use cal and kcal; accordingly, to convert between J and cal, the following conversion factor (to four significant figures) is used: 1 cal = 4.184 J. 1 pts Question 2 The statement is not true The statement is true The value of the gas constant (in terms of cal/K mol) is, to four significant figures, 1.987 cal/K mol. 1 pts Question 3 The statement is not true Nearly all thermodynamics problems require the Absolute (or Kelvin) scale for temperature; accordingly, to convert from °C to K, the following conversion factor (to three significant figures) is used: K = °C + 273.
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 2/18 The statement is true 1 pts Question 4 nonspontaneous only endothermic and spontaneous exothermic and spontaneous exothermic only exothermic and nonspontaneous endothermic and nonspontaneous endothermic only spontaneous only A certain reaction at 25 °C has ΔH = +3.54 kJ/mol and ΔS = 129 J/mol K. Which of the following is an accurate description of this reaction? 1 pts Question 5 exothermic only nonspontaneous only spontaneous only endothermic and nonspontaneous endothermic only exothermic and spontaneous A certain reaction at 25 °C has ΔH = −3.54 kJ/mol and ΔS = −29 J/mol K. Which of the following is an accurate description of this reaction?
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 3/18 endothermic and spontaneous exothermic and nonspontaneous 1 pts Question 6 The reaction will be spontaneous (i.e., thermodynamically favorable) at temperatures less than 25 °C. The reaction will be spontaneous (i.e., thermodynamically favorable) at any temperature. The reaction will be spontaneous (i.e., thermodynamically favorable) at temperatures greater than 25 °C. The reaction will not be spontaneous (i.e., thermodynamically favorable) at any temperature. None of the other choices is true. A reaction carried out at 25 °C is noted to have ΔH = +32.5 kJ/mol and ΔS = 109 J/mol K. Which of the following statements accurately describes the above reaction? 1 pts Question 7 The statement is true The statement is not true If 4.184 J of thermal energy are added to 1 g of water, then the temperature of the water will increase 1 degree Celsius. 1 pts Question 8
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 4/18 8.88 5.12 8.18 3.06 4.34 What is the pH of a 0.10 M solution of a weak acid (HA) that has a p K of 5.12? a 1 pts Question 9 2.5 3.5 1.5 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 5.5 6.5 4.5 A 0.2 M solution of a weak acid HA dissociates such that 99.6% of the weak acid remains intact (i.e., remains as HA). What is the p K of the weak acid? a 1 pts Question 10 A 0.2 M solution of a weak acid HA dissociates such that 99.4% of the weak acid remains intact (i.e., remains as HA). What is the pH of the solution?
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 5/18 3.5 −0.03 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 2.9 2.2 0.7 1.9 1 pts Question 11 8.50 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 5.50 11.25 9.05 4.95 2.75 A 0.2 M solution of a weak base A is made. To a limited extent, the A reacts with H O to form some OH and some of the corresponding weak acid HA. If the weak acid has a p K of 9.2, what will be the pH of the solution? Hint: recall how p K , p K , and p K are related. - - 2 a a b W 1 pts Question 12
9/20/22, 7:52 PM Quiz: Week 1 Practice Quiz F22 https://canvas.ou.edu/courses/249882/quizzes/352356/take 6/18 10.9 11.9 5.5 2.1 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 3.1 8.5 A 0.2 M solution of a weak base A reacts with H O such that at equilibrium 99.6% of the compound remains in the A form. Given this information, what is the pH of this solution? - 2 1 pts Question 13 7.8 6.2 10.9 3.1 5.5 none of the other choices is reasonably close (i.e., within ±5% of the correct answer) 8.5 A 0.2 M solution of a weak base A reacts with H O such that at equilibrium 99.6% of the compound remains in the A form. Given this information, what is the p K of the conjugate acid HA? - 2 a
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