An open tubular column with a diameter of 215 µm and a stationary phase thickness on the inner wall of 0.51 pm passes unretained solute through in 79 s. A particular solute has a retention time of 467 s. What is the distribution constant for this solute? Kp = What fraction of time does this solute spend in the stationary phase? ts ttotal
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- the dimensionless Henry's law constant for trichloroethylene at 25 degrees Celcius is 0.4. A sealed glass vial is prepared that has an air volume of 4ml overlying an aqueous volume of 36ml. TCE is added to the aqueous phase so that initially it has an aqueous-phase concentration of 100 ppb. After the system equilibrates, what will be the concentration (in units of microgram per liter) of TCE in the aqueous phaseThe standard addition method is used to analyze a sample of a river water for mercury. Solution A is made by pipetting 5.00 mL of undiluted sample in to a 10 mL volumetric flask and filling to the mark with DI water. Solution B is made by pipetting 5.00 mL of undiluted sample and 3.00 mL of 15.0 ppb of Hg standard into same 10.0 mL volumetric flask and filling to the mark with DI. Solution A and B are analyzed using atomic absorption spectroscopy and give a percent transmittance values of 56 % and 33 % respectively (not blank corrected). A blank has a transmittance of 96%. What is the corrected absorbance of both solution A and B? A. Solution A: 0.123 Solution B: 0.463 B. Solution A: 0.463 Solution B: 0.234 C. Solution A: 0.123 Solution B: 0.234 D. Solution A: 0.234 Solution B: 0.463The distribution coefficient, KD (C water/C ether), between ether and water for aspirin at room temperature is 0.30. What weight of aspirin would be extracted by a single extraction with 300 mL of water from a solution of with a concentration of 0.67 M? Calculate the weight of aspirin which would be removed by three extractions with 100 mL portions of water. Compare the weight of solute extracted in single extraction process with the triple extraction process. Take note: The volume of the solution is 100ml
- Pls do fast within 5 minutes and i will give like for sure Solution must be in typed form To plan a liquid–liquid extraction we need to know the solute’s distribution ratio between the two phases. One approach is to carry out the extraction on a solution that contains a known amount of solute. After the extraction, we isolate the organic phase and allow it to evaporate, leaving behind the solute. In one such experiment, 1.235 g of a solute with a molar mass of 117.3 g/mol is dissolved in 10.00 mL of water. After extracting with 5.00 mL of toluene, 0.889 g of the solute is recovered in the organic phase. If we extract 20.00 mL of an aqueous solution that contains the solute using 10.00 mL of toluene, what is the extraction efficiency?The partial molar volumes of acetone and chloroform, in a solution in which the molar fraction of chloroform is 0.4693, are 74.166 cm3mol-1 and 80.235 cm3 mol-1, respectively. What is the volume of 1,000 kg of this solution? Data: M.M. (acetone) = 58.08 gmol-1; M.M. (chloroform) = 119.07 gmol-1.A solution is prepared by dissolving 40.00 g of MgCl2 (f.w. = 95.211 g mol–1), a non-volatile solute, in enough water (m.w. = 18.02 g mol–1) to result in exactly 2 L of solution at 25 °C. Assume the density of the solution is that of pure water (dsolution = 1.000 g mL–1). The ebullioscopic constant (Kb) for water is 0.513 °C m–1. The cryoscopic constant (Kf) for water is 1.86 °C m–1. The vapor pressure of pure water is 0.0313 atm. Determine the freezing point of the solution.
- A solution is prepared by dissolving 40.00 g of MgCl2 (f.w. = 95.211 g mol–1), a non-volatile solute, in enough water (m.w. = 18.02 g mol–1) to result in exactly 2 L of solution at 25 °C. Assume the density of the solution is that of pure water (dsolution = 1.000 g mL–1). The ebullioscopic constant (Kb) for water is 0.513 °C m–1. The cryoscopic constant (Kf) for water is 1.86 °C m–1. The vapor pressure of pure water is 0.0313 atm. Determine the osmotic pressure in atm.At 30°C, pure benze has a vapor pressure of 121.8 mmHg. Dissolving 15.0g of a non-volatile solute, R, in 250g of benzene produced a solution having a vapor pressure of 120.2 mmHg. Determine the approximate MW of solute R.A solution of common salt in water is prepared by adding 50kg of salt to 200kg of water tomake a liquid density of 1250kg/m3. Calculate the concentration of salt in this solution as a: i) Weight(w/w)fraction (Ans: weight fraction 20%)
- At a certain temperature, the solubility of zinc(I) chromate is (7.6x10^-5) M. What is the Ksp? Report your answer to 2 sig figs. Note: Your answer is assumed to be reduced to the highest power possibleSolid Na2S is slowly added to a solution of 1.0 x 10-3 M Cr3+ (with no change in volume). At what [S2-] will Cr2S3 start to ppt? For Cr2S3, Ksp = 1.0 x 10-20Although other solvents are available, dichloromethane(CH₂Cl₂) is still often used to “decaffeinate” drinks because thesolubility of caffeine in CH₂Cl₂ is 8.35 times that in water.(a) A 100.0-mL sample of cola containing 10.0 mg of caffeine is extracted with 60.0 mL of CH₂Cl₂. What mass of caffeine re-mains in the aqueous phase? (b) A second identical cola sampleis extracted with two successive 30.0-mL portions of CH₂Cl₂.What mass of caffeine remains in the aqueous phase after each extraction? (c) Which approach extracts more caffeine?