Concept explainers
(a)
To determine: The important resonance forms for the given compound; the major and minor contributors in the resonating structures; if they have the same energy and any important missing resonance form.
Interpretation: The important resonance forms for the given compound are to be stated; the major and minor contributors in the resonating structures are to be indicated; whether they have same energy is to be stated and any important missing resonating form is to be stated.
Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs.
The major contributors are those resonating structures in which almost all the atoms have filled octet.
The minor contributors are those resonating structures in which atoms do not have complete octet and electronegative atom carries positive charge and vice-versa.
(b)
To determine: The important resonance forms for the given compound; the major and minor contributors in the resonating structures; if they have the same energy and any important missing resonance form.
Interpretation: The important resonance forms for the given compound are to be stated; the major and minor contributors in the resonating structures are to be indicated; whether they have same energy is to be stated and any important missing resonating form is to be stated.
Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs.
The major contributors are those resonating structures in which almost all the atoms have filled octet.
The minor contributors are those resonating structures in which atoms do not have complete octet and electronegative atom carries positive charge and vice-versa.
(c)
To determine: The important resonance forms for the given compound; the major and minor contributors in the resonating structures; if they have the same energy and any important missing resonance form.
Interpretation: The important resonance forms for the given compound are to be stated; the major and minor contributors in the resonating structures are to be indicated; whether they have same energy is to be stated and any important missing resonating form is to be stated.
Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs.
The major contributors are those resonating structures in which almost all the atoms have filled octet.
The minor contributors are those resonating structures in which atoms do not have complete octet and electronegative atom carries positive charge and vice-versa.
(d)
To determine: The important resonance forms for the given compound; the major and minor contributors in the resonating structures; if they have the same energy and any important missing resonance form.
Interpretation: The important resonance forms for the given compound are to be stated; the major and minor contributors in the resonating structures are to be indicated; whether they have same energy is to be stated and any important missing resonating form is to be stated.
Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs.
The major contributors are those resonating structures in which almost all the atoms have filled octet.
The minor contributors are those resonating structures in which atoms do not have complete octet and electronegative atom carries positive charge and vice-versa.
(e)
To determine: The important resonance forms for the given compound; the major and minor contributors in the resonating structures; if they have the same energy and any important missing resonance form.
Interpretation: The important resonance forms for the given compound are to be stated; the major and minor contributors in the resonating structures are to be indicated; whether they have same energy is to be stated and any important missing resonating form is to be stated.
Concept introduction: Resonance is the process in which a molecule gets different structures to define its bonding within the molecule. Such molecules cannot be represented in single Lewis structures. Resonating structures of such molecules are called contributing structures. In the process of resonance shifting of lone pairs occur with the bonds and other lone pairs.
The major contributors are those resonating structures in which almost all the atoms have filled octet.
The minor contributors are those resonating structures in which atoms do not have complete octet and electronegative atom carries positive charge and vice-versa.
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Chapter 1 Solutions
Organic Chemistry (9th Edition)
- If possible, draw additional resonance contributors for the structure below. Include appropriate curved arrows showing how one contributor is converted to the next. If you believe there is a major resonance structure, circle it. (Hint: You should start by filling in lone pairs of electrons that have not been depicted. And you may find it useful to draw in implicit Hs.)..arrow_forwardDraw all significant resonance structures for the following molecules. For each, circle the most significant resonance contributor..arrow_forwardFuran, shown below, exhibit resonance stabilization. Which of the following is an INVALID resonance structure of furan?arrow_forward
- The molecule shown has an unusually stable anion. In the box below please draw all the resonance structures that show the delocalization fo the anion that is generated when a proton is removed. Provide an explanation for this unusual stability.arrow_forward1. Add nonbonding electron pairs to each atom where it is implied by the line-angle drawings shown below. 2. Use the curved arrow formalism to generate four additional, valid resonance structures for each compound. 3. Rank your resonance structures in order of increasing contribution to the overall nature of the molecule.arrow_forwardLabel the major and minor resonance structures below. Concisely explain why the structure you labeled as major is the major contributor to the overall structure of the compound.arrow_forward
- Draw all possible resonance structures (contributors) for the following compound. Which resonance structure contributes most to the resonance hybrid? Why?arrow_forwarddraw the resonance for the following structures?arrow_forwardPlease guide me on how to draw the best resonance structure, thank you.arrow_forward
- Draw three major resonance contributors for the molecule shown in the box. Partiallycompleted skeletal structures are provided as a time-saver; simply add double bonds and formalcharges where appropriate. Do not generate any additional charges.arrow_forwardWhat are all the possible resonance structures (contributors) for the compound below? Please draw them.arrow_forwardDraw resonance contributors for the following species. Do not include structures that are so unstable that their contributions to the resonance hybrid would be negligible. Indicate which are major contributors and which are minor contributors to the resonance hybrid. b. Do any of the species have resonance contributors that all contribute equally to the resonance hybrid?arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning