EBK ORGANIC CHEMISTRY
12th Edition
ISBN: 9781119233664
Author: Snyder
Publisher: VST
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Chapter 10, Problem 41P
Hydrogen peroxide and ferrous sulfate react to produce hydroxyl radical (HO·), as reported in 1894 by. English chemist H.J. H. Fenton. When tert-butyl alcohol is treated with HO· generated this way, it affords a crystalline reaction produa X, mp 92 °C, which has these spectral properties:
MS: heaviest mass peak is at m/z 131
IR: 3620, 3350 (broad), 2980, 2940, 1385, 1370 cm−1
Draw the structure of X and write a mechanism for its formation.
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File Details
4CH003/UM1: Fundamentals of...
Introduction
NaBH4
OH
C=0
H
benzophenone
diphenylmethanol
Ketones are readily reduced to secondary alcohols by reaction with sodium
borohydride. The aim of this experiment is to determine the time required to
effect
the complete conversion
of the ketone, benzophenone to
diphenylmethanol at room temperature. This investigation may be achieved
by isolating and analyzing the reaction product after different reduction times.
Infrared spectroscopy affords a convenient method of analysis; by comparing
the IR spectrum of the crude reaction product at different time intervals one
would expect to see the intensity of the hydroxyl absorption peak increase
relative to that of the original carbonyl peak. From this you can deduce the
optimum time for the reduction process at room temperature.
Procedure
Note the "reduction time" that the demonstrator assigns to your group.
Different groups will be assigned different times, eithert = 2.5 minutes,…
Answer Q25, 26, 27
Chapter 10 Solutions
EBK ORGANIC CHEMISTRY
Ch. 10 - Prob. 1PPCh. 10 - Prob. 2PPCh. 10 - Practice Problem 10.3 How would the molecular ion...Ch. 10 - Prob. 4PPCh. 10 - Prob. 5PPCh. 10 - Prob. 6PPCh. 10 - Practice Problem 10.7 Chlorination reactions of...Ch. 10 - Prob. 8PPCh. 10 - Prob. 9PPCh. 10 - Prob. 10PP
Ch. 10 - Prob. 11PPCh. 10 - Practice Problem 10.12 Benzylic radicals, due to...Ch. 10 - Prob. 13PPCh. 10 - Practice Problem 10.14 Show how the following...Ch. 10 - Prob. 15PPCh. 10 - Prob. 16PPCh. 10 - Prob. 17PPCh. 10 - Prob. 18PCh. 10 - Explain the relative distribution of produces...Ch. 10 - 10.20 Which of the following compounds can be...Ch. 10 - Prob. 21PCh. 10 - Prob. 22PCh. 10 - Prob. 23PCh. 10 - Prob. 24PCh. 10 - 10.25 List in order of decreasing stability all of...Ch. 10 - Prob. 26PCh. 10 - Prob. 27PCh. 10 - Prob. 28PCh. 10 - Starting with the compound or compounds indicated...Ch. 10 - Prob. 30PCh. 10 - 10.31 Synthesize each of the following compounds...Ch. 10 - Synthesize each of die following compounds by...Ch. 10 - Prob. 33PCh. 10 - Prob. 34PCh. 10 - Prob. 36PCh. 10 - The halogen atom of an alkyl halide can be...Ch. 10 - Prob. 38PCh. 10 - Prob. 39PCh. 10 - Write a mechanism for the following reaction.Ch. 10 - 10.41 Hydrogen peroxide and ferrous sulfate react...Ch. 10 - Prob. 42PCh. 10 - If one were to try to draw the simplest Lewis...Ch. 10 - Prob. 1LGPCh. 10 - 2. (a) Propose a synthesis of 2-methoxypropene...
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