EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
12th Edition
ISBN: 9781119233664
Author: Snyder
Publisher: VST
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Chapter 10, Problem 28P
Interpretation Introduction

Interpretation:

The radical chain mechanism of the Hunsdiecker reaction is to be represented.

Concept introduction:

The Hunsdiecker reaction is an organic reaction in which silver salts of carboxylic acid are added to a halogen in order to produce an organic halide. This reaction is also known as Hunsdiecker–Borodin reaction. The reaction of Hunsdiecker is as follows:

EBK ORGANIC CHEMISTRY, Chapter 10, Problem 28P

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b) Explain in detail what characteristics of the alkyl halide influence whether a mechanism will be SN1 or SN2. c) Explain in detail what characteristics of a nucleophile influence whether a reaction will be SN1 or SN2.
Explain why quinuclidine is a much more reactive nucleophile thantriethylamine, even though both compounds have N atoms surroundedby three R groups.
The reaction is a nucleophilic substitution, A is OH- and B is an alkyl bromide. Give the reaction mechanism and explain your reasoning.
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