Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 15, Problem 3DQ
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Chemical Principles
Ch. 15 - Prob. 1DQCh. 15 - Prob. 2DQCh. 15 - a graph of [A] versus time for zero-, first-, and...Ch. 15 - Prob. 4DQCh. 15 - Prob. 5DQCh. 15 - Prob. 6DQCh. 15 - Prob. 7DQCh. 15 - Prob. 8DQCh. 15 - Provide a conceptual rationale for the differences...Ch. 15 - Prob. 10E
Ch. 15 - Consider the general reaction aA+bBcC and the...Ch. 15 - Prob. 12ECh. 15 - Prob. 13ECh. 15 - Prob. 14ECh. 15 - Prob. 15ECh. 15 - The hydroxyl radical (OH) is an important...Ch. 15 - Prob. 17ECh. 15 - The reaction 2NO(g)+Cl2(g)2NOCl(g) was studied at...Ch. 15 - Prob. 19ECh. 15 - The following data were obtained for the gas-phase...Ch. 15 - Prob. 21ECh. 15 - Prob. 22ECh. 15 - Prob. 23ECh. 15 - Prob. 24ECh. 15 - Prob. 25ECh. 15 - Prob. 26ECh. 15 - Prob. 27ECh. 15 - Prob. 28ECh. 15 - If the half-life for a reaction is 20. seconds,...Ch. 15 - A certain reaction has the following general form:...Ch. 15 - Prob. 31ECh. 15 - Prob. 32ECh. 15 - The decomposition of hydrogen peroxide was studied...Ch. 15 - Prob. 34ECh. 15 - Prob. 35ECh. 15 - Prob. 36ECh. 15 - At 500K in the presence of a copper surface,...Ch. 15 - Experimental data for the reaction A2B+C have been...Ch. 15 - The reaction NO(g)+O3(g)NO2(g)+O2(g) was studied...Ch. 15 - Determine the forms of the integrated and the...Ch. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 43ECh. 15 - Prob. 44ECh. 15 - Prob. 45ECh. 15 - Prob. 46ECh. 15 - Prob. 47ECh. 15 - Prob. 48ECh. 15 - Prob. 49ECh. 15 - Prob. 50ECh. 15 - Prob. 51ECh. 15 - Prob. 52ECh. 15 - Prob. 53ECh. 15 - Prob. 54ECh. 15 - Prob. 55ECh. 15 - Define each of the following. elementary step...Ch. 15 - Define what is meant by unimolecular and...Ch. 15 - What two requirements must be met to call a...Ch. 15 - Prob. 59ECh. 15 - Prob. 60ECh. 15 - A proposed mechanism for a reaction is...Ch. 15 - Is the mechanism NO+Cl2k1NOCl2NOCl2+NOk22NOCl...Ch. 15 - The reaction 2NO(g)+O2(g)2NO2(g) exhibits the rate...Ch. 15 - Prob. 64ECh. 15 - The reaction...Ch. 15 - Prob. 66ECh. 15 - Prob. 67ECh. 15 - Prob. 68ECh. 15 - The following mechanism is proposed for the...Ch. 15 - The following mechanism has been proposed to...Ch. 15 - Consider the hypothetical reaction BE+F which is...Ch. 15 - How is the rate of a reaction affected by each of...Ch. 15 - The central idea of the collision model is that...Ch. 15 - Prob. 74ECh. 15 - Prob. 75ECh. 15 - Consider the following potential energy plots Rank...Ch. 15 - Prob. 77ECh. 15 - Prob. 78ECh. 15 - Prob. 79ECh. 15 - Prob. 80ECh. 15 - Prob. 81ECh. 15 - Chemists commonly use a rule of thumb that an...Ch. 15 - Prob. 83ECh. 15 - Prob. 84ECh. 15 - Prob. 85ECh. 15 - Prob. 86ECh. 15 - For the following reaction profiles, indicate the...Ch. 15 - Prob. 88ECh. 15 - Prob. 89ECh. 15 - Prob. 90ECh. 15 - Prob. 91ECh. 15 - Prob. 92ECh. 15 - The decomposition of NH3 to N2 and H2 was studied...Ch. 15 - One pathway for the destruction of ozone in the...Ch. 15 - Prob. 95ECh. 15 - Prob. 96ECh. 15 - Prob. 97ECh. 15 - Prob. 98ECh. 15 - Prob. 99ECh. 15 - Prob. 100AECh. 15 - Prob. 101AECh. 15 - Prob. 102AECh. 15 - Prob. 103AECh. 15 - Prob. 104AECh. 15 - Prob. 105AECh. 15 - Prob. 106AECh. 15 - Prob. 107AECh. 15 - Prob. 108AECh. 15 - Prob. 109AECh. 15 - The decomposition of NO2(g) occurs by the...Ch. 15 - Prob. 111AECh. 15 - Prob. 112AECh. 15 - Prob. 113AECh. 15 - Prob. 114AECh. 15 - Prob. 115AECh. 15 - Prob. 116AECh. 15 - The compound NO2Cl is thought to decompose to NO2...Ch. 15 - Prob. 118AECh. 15 - Prob. 119AECh. 15 - Prob. 120AECh. 15 - Prob. 121AECh. 15 - Prob. 122AECh. 15 - Prob. 123AECh. 15 - Prob. 124AECh. 15 - Prob. 125AECh. 15 - Prob. 126AECh. 15 - Consider the following reaction: CH3X+YCH3Y+X At...Ch. 15 - The following data were collected in two studies...Ch. 15 - Prob. 129CPCh. 15 - For the reaction 2A+Bproducts afriend proposes the...Ch. 15 - Consider the hypothetical reaction A+B+2C2D+3E In...Ch. 15 - A reaction represented by the equation...Ch. 15 - Prob. 133CPCh. 15 - You are studying the kinetics of the reaction...Ch. 15 - Prob. 135CPCh. 15 - Prob. 136MP
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- Consider the first-order decomposition reaction A+BCwhere A (circles) decomposes to B (triangles) and C (squares). Given the following boxes representing the reaction at t=2 minutes, fill in the boxes with products at the indicated time. Estimate the half-life of the reaction.arrow_forwardConsider the hypothetical first-order reaction 2A(g)X(g)+12Y(g)At a certain temperature, the half-life of the reaction is 19.0 min. A 1.00-L flask contains A with a partial pressure of 622 mm Hg. If the temperature is kept constant, what are the partial pressures of A, X, and Y after 42 minutes?arrow_forwardAs with any drug, aspirin (acetylsalicylic acid) must remain in the bloodstream long enough to be effective. Assume that the removal of aspirin from the bloodstream into the urine is a lirst-order reaction, with a half-life of about 3 hours. The instructions on an aspirin bottle say to take 1 or 2 tablets every 4 hours. If a person takes 2 aspirin tablets, how much aspirin remains in the bloodstream when it is time for the second dose? (A standard tablet contains 325 mg of aspirin.)arrow_forward
- Derive an expression for the half-life of a a third order reaction;b a reaction whose order is =1; c a reaction whose order is 12. In these last two cases, examples are rare but known.arrow_forwardCyclobutane can decompose to form ethylene: The cyclobutane concentration can be measured as a function of time by mass spectrometry (a graph is nearby). Write an expression for the rate of reaction in terms of a changing concentration. Calculate the average rate of reaction between 10. and 30. s. Calculate the instantaneous rate of reaction after 20. s. Calculate the initial rate of reaction. Calculate the instantaneous rate of formation of ethylene 40. s after the start of the reaction.arrow_forwardThe hydrolysis of the sugar sucrose to the sugars glucose and fructose, C12H22O11+H2OC6H12O6+C6H12O6 follows a first-order rate equation for the disappearance of sucrose: Rate =k[C12H22O11] (The products of the reaction, glucose and fructose, have the same molecular formulas but differ in the arrangement of the atoms in their molecules.) (a) In neutral solution, k=2.11011s1 at 27 C and 8.51011s1 at 37 C. Determine the activation energy, the frequency factor, and the rate constant for this equation at 47 C (assuming the kinetics remain consistent with the Arrhenius equation at this temperature). (b) When a solution of sucrose with an initial concentration of 0.150 M reaches equilibrium, the concentration of sucrose is 1.65107M . How long will it take the solution to reach equilibrium at 27 C in the absence of a catalyst? Because the concentration of sucrose at equilibrium is so low, assume that the reaction is irreversible. (c) Why does assuming that the reaction is irreversible simplify the calculation in pan (b)?arrow_forward
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